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1.
Crystallization of authigenic carbonates in mud volcanoes at Lake Baikal   总被引:1,自引:0,他引:1  
This paper presents data on authigenic siderite first found in surface sediments from mud volcanoes in the Central (K-2) and Southern (Malen’kii) basins of Lake Baikal. Ca is the predominant cation, which substitutes Fe in the crystalline lattice of siderite. The enrichment of the carbonates in the 13C isotope (from +3.3 to +6.8‰ for the Malen’kii volcano and from +17.7 to +21.9‰ for K-2) results from the crystallization of the carbonates during methane generation via the bacterial destruction of organic matter (acetate). The overall depletion of the carbonates in 18O is mainly inherited from the isotopic composition of Baikal water.  相似文献   
2.
Rice paddies as a methane source   总被引:8,自引:0,他引:8  
Rice fields are considered to be among the highest sources of atmospheric methane, an important source of global warming. In order to meet the projected rice needs of the increasing world population, it is estimated that the annual world's rough rice production must increase to 760 million tons (a 65% increase) in the next 30 years. This will increase methane emissions from ricefields if current technologies are kept. Methane emissions from ricefields are affected by climate, water regime, soil properties, and various cultural practices like irrigation and drainage, organic amendments, fertilization, and rice cultivars. Irrigated rice comprises 50% of the world-harvested rice area and contributes 70% to total rice production. Because of assured flooding during the growing period it is the primary source of methane. Rainfed rice emits less methane due to periods of droughts. Upland rice, being never flooded for a significant period of time, is not a significant source of methane. There is great potential to develop no regret mitigation options that are in accordance with increasing rice production.  相似文献   
3.
International Journal of Earth Sciences - Early diagenetic carbonates are rare in Lake Baikal. Siderite (Fe carbonate) concretions in the sediments were discovered only recently. Here, we discuss...  相似文献   
4.
Earthquake observations and microtremor measurements were conducted on a 12-storey steel-reinforced concrete building just after its completion. Marked stiffness deterioration was observed over the following five-year period, during which time several earthquakes were recorded and two additional series of microtremor measurements were made. The large contribution made by non-structural elements (especially the curtain walls that cover all sides of the building) to the apparent stiffness of the entire building was lost during this period. Both ageing effects and stiffness reductions depend greatly on the amplitude of the structural response of this building.  相似文献   
5.
Mitigating Agricultural Emissions of Methane   总被引:7,自引:0,他引:7  
Agricultural crop and animal production systems are important sources and sinks for atmospheric methane (CH4). The major CH4 sources from this sector are ruminant animals, flooded rice fields, animal waste and biomass burning which total about one third of all global emissions. This paper discusses the factors that influence CH4 production and emission from these sources and the aerobic soil sink for atmospheric CH4 and assesses the magnitude of each source. Potential methods of mitigating CH4 emissions from the major sources could lead to improved crop and animal productivity. The global impact of using the mitigation options suggested could potentially decrease agricultural CH4 emissions by about 30%.  相似文献   
6.
We investigated the molecular composition (methane, ethane, and propane) and stable isotope composition (methane and ethane) of hydrate-bound gas in sediments of Lake Baikal. Hydrate-bearing sediment cores were retrieved from eight gas seep sites, located in the southern and central Baikal basins. Empirical classification of the methane stable isotopes (δ13C and δD) for all the seep sites indicated the dominant microbial origin of methane via methyl-type fermentation; however, a mixture of thermogenic and microbial gases resulted in relatively high methane δ13C signatures at two sites where ethane δ13C indicated a typical thermogenic origin. At one of the sites in the southern Baikal basin, we found gas hydrates of enclathrated microbial ethane in which 13C and deuterium were both highly depleted (mean δ13C and δD of –61.6‰ V-PDB and –285.4‰ V-SMOW, respectively). To the best of our knowledge, this is the first report of C2 δ13C–δD classification for hydrate-bound gas in either freshwater or marine environments.  相似文献   
7.
Tadao  Nishiyama  Aiko  Tominaga  Hiroshi  Isobe 《Island Arc》2007,16(1):16-27
Abstract We carried out hydrothermal experiments in the system dolomite‐quartz‐H2O to track the temporal change in reaction rates of simultaneous reactions during the development of reaction zones. Two types of configurations for the starting materials were prepared: dolomite single crystals + quartz powder + water and quartz single crystals + dolomite powder + water, both sealed separately in gold capsules. Runs at 0.1GPa and 600°C with cold seal pressure vessels gave the following results. (i) In short duration (45–71 h) runs metastable layer sequences involving wollastonite and talc occur in the reaction zone, whereas they disappear in longer duration (168–336 h) runs. (ii) The layer sequence of the reaction zones in short duration runs differs from place to place on the dolomite crystal even in the same run. (iii) The diversity of layer sequences in the short duration runs merges into a unique layer sequence in the longer duration runs. (iv) The reaction zone develops locally on the dolomite crystal, but no reaction zone was observed on the quartz crystal in any of the runs. The lines of evidence (i)–(iii) show that the system evolves from an initial transient‐ to a steady‐state and that the kinetic effect is important in the development of reaction zones. A steady diffusion model for the unique layer sequence Qtz/Di/Fo + Cal/Dol + Cal/Dol shows that the Dol + Cal layer cannot be formed by diffusion‐controlled process and that the stability of the layer sequence Qtz/Di/Fo + Cal/Dol depends not only on L‐ratios (a = /LCaOCaO and b = /LMgOMgO) but also on the relative rate P = (−2ξ1ξ2)/(–ξ1 − 2ξ2) of competing reactions: Dol + 2Qtz = Di + 2CO2 (ξ1) and 2Dol + Qtz = Fo + 2Cal + 2CO2 (ξ2). For smaller P the stability field will shift to higher values of a and b. The steady diffusion model also shows that the apparent‐non‐reactivity on the quartz surface can be attributed to void formation in a large volume fraction in the diopside layer.  相似文献   
8.
As a possible design of a future geoneutrino detector, a KamLAND-type, monolithic, liquid scintillator detector with a thicker veto and a method for particle identification to reject neutron and 9Li background from cosmic-ray muon spallation is considered. Assuming such a detector, the possibility for geoneutrino observation at a depth of around 300 meters of water equivalent is investigated.  相似文献   
9.
Spinifex-like textured metaperidotites from the Higo Metamorphic Rocks (HMR), west-central Kyushu, Japan, may be formed by high-pressure dehydration of antigorite, and may indicate deep subduction of serpentinite reaching a pressure–temperature condition of 1.6 GPa and 740–750 °C. Three rock types have been identified based on mineral assemblage and rock texture: Type I (L) consisting of medium-grained (1–5 cm long) olivine + enstatite + chromite ±tremolite with secondary talc and anthophyllite that occurs in low-grade metamorphic rocks of the biotite zone, Type I (H) of coarse-grained (up to 10 cm long) olivine + enstatite (with clinoenstatite lamella) + chromite ±tremolite with secondary talc that occurs in high-grade metamorphic rocks of the garnet-cordierite zone, and Type II composed of Al-spinel + chlorite + olivine + apatite + ilmenite with minor sodic gedrite in the garnet-cordierite zone together with Type I (H). Olivines in all rock types are mostly serpentinized during exhumation. The chromite-olivine thermometer gives 560–690 °C for Type I (L) rocks, and the spinel-olivine thermometer gives 610–740 °C for Type II rocks. The peak metamorphic pressure will be higher than 1.6 GPa based on the location of the experimentally determined invariant point (P = 1.6 GPa and T = 670 °C) of antigorite + forsterite + enstatite + talc + H2O. This estimate is consistent with the occurrence of chlorite in Type II rocks, which is stable up to 890 °C at 2.0 GPa. The spinifex-like textured metaperidotites occur as small bodies in the low P/T type gneisses, implying tectonic juxtaposition of them probably during exhumation of the HMR. Recent findings of medium pressure (0.9–1.2 GPa) granulites and gneisses from the HMR may indicate that the HMR has a deep root into the wedge mantle from which the spinifex-like textured metaperidotites have derived.  相似文献   
10.
Observed potential temperatures and concentrations of dissolved oxygen are analyzed to elucidate their variations during the period from 1958 to 1996 at Stn. P (37°43′ N, 134°43′ E) and from 1965 to 1996 at Stn. H (40°30′ N, 137°40′ E) in the Japan Sea. At Stn. P, increases of the potential temperature for the period are found below 800 m depth with the largest value of 0.16 ± 0.09°C per century at 800 m depth. At Stn. H, the potential temperature increased below 500 m depth. The increase rate has the largest value of 0.50 ± 0.18°C per century at 500 m depth and it is 0.30 ± 0.09°C per century at 800 m depth. The concentrations of dissolved oxygen increased around 800 m depth at Stn. P. At Stn. H, they increased above 800 m depth. On the other hand, they decreased below 1200 m depth at both stations. The layer of the dissolved oxygen minimum has deepened in these decades. These features appearing in the distributions of temperature and dissolved oxygen are successively simulated by a vertical one-dimensional advection-diffusion model including consumption of dissolved oxygen and termination of the deep water supply. These results suggest that the supply of the Japan Sea Proper Water into the deep layer, which is cold and rich in dissolved oxygen, has been decreasing for the last four decades. This revised version was published online in August 2006 with corrections to the Cover Date.  相似文献   
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