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1.
Oil-weathering processes in ice-free subarctic and Arctic waters include spreading, evaporation, dissolution, dispersion of whole-oil droplets into the water column, photochemical oxidation, water-in-oil emulsification, microbial degradation, adsorption onto suspended particulate material, ingestion by organisms, sinking, and sedimentation. While many of these processes also are important factors in ice-covered waters, the various forms of sea ice (depending on the active state of ice growth, extent of coverage and/or decay) impart drastic, if not controlling, changes to the rates and relative importance of different oil-weathering mechanisms. Flow-through seawater wave-tank experiments in a cold room at −35°C and studies in the Chukchi Sea in late winter provide data on oil fate and effects for a variety of potential oil spill scenarios in the Arctic. Time-series chemical weathering data are presented for Prudhoe Bay crude oil released under and encapsulated in growing first-year columnar ice through spring breakup. 相似文献
2.
In this paper, we formulate a finite-element procedure for approximating the coupled fluid and mechanics in Biot’s consolidation
model of poroelasticity. We approximate the flow variables by a mixed finite-element space and the displacement by a family
of discontinuous Galerkin methods. Theoretical convergence error estimates are derived and, in particular, are shown to be
independent of the constrained specific storage coefficient, c
o
. This suggests that our proposed algorithm is a potentially effective way to combat locking, or the nonphysical pressure
oscillations, which sometimes arise in numerical algorithms for poroelasticity. 相似文献
3.
4.
Carbon isotope fractionation in wood during carbonization 总被引:1,自引:0,他引:1
A significant uncertainty exists as to whether δ13C values in charcoal meaningfully represent the stable isotopic content of the original material, with studies suggesting variable responses to both natural and laboratory heating. An extensive study was undertaken using fully homogenised samples of wood taken from Eucalyptus spp., Quercus robur and Pinus radiata. The results demonstrate that the duration of heating had no tangible effect on the final composition of the charred material, with the δ13C and carbon content of wood fixed after 30 min of heating. Furthermore, all three wood types become progressively depleted in 13C with increasing temperature. The results demonstrate that even at temperatures commonly reached in natural fires (<450 °C) isotopic fractionation of up to 1.3‰ can take place indicating that the absolute values obtained from charcoal extracted for paleoenvironmental reconstruction must be interpreted with caution. 相似文献
5.
Multicollinearity and correlation among local regression coefficients in geographically weighted regression 总被引:5,自引:3,他引:5
Present methodological research on geographically weighted regression (GWR) focuses primarily on extensions of the basic GWR model, while ignoring well-established diagnostics tests commonly used in standard global regression analysis. This paper investigates multicollinearity issues surrounding the local GWR coefficients at a single location and the overall correlation between GWR coefficients associated with two different exogenous variables. Results indicate that the local regression coefficients are potentially collinear even if the underlying exogenous variables in the data generating process are uncorrelated. Based on these findings, applied GWR research should practice caution in substantively interpreting the spatial patterns of local GWR coefficients. An empirical disease-mapping example is used to motivate the GWR multicollinearity problem. Controlled experiments are performed to systematically explore coefficient dependency issues in GWR. These experiments specify global models that use eigenvectors from a spatial link matrix as exogenous variables.This study was supported by grant number 1 R1 CA95982-01, Geographic-Based Research in Cancer Control and Epidermiology, from the National Cancer Institute. The author thank the anonymous reviewers and the editor for their helpful comments. 相似文献
6.
Experimental Melting of Cordierite Gneiss and the Petrogenesis of Syntranscurrent Peraluminous Granites in Southern Brazil 总被引:8,自引:1,他引:8
KOESTER EDINEI; PAWLEY ALISON R.; FERNANDES LUIS A. D.; PORCHER CARLA C.; SOLIANI ENIO JR 《Journal of Petrology》2002,43(8):1595-1616
To understand the petrogenesis of peraluminous granites syntectonicto the Dorsal de Canguçu Transcurrent Shear Zone in theSul-rio-grandense Shield, Brazil, melting experiments were performedon one of the potential protoliths, a cordierite-bearing semi-peliticmetasedimentary gneiss (PE-1). Experiments were conducted atpressures of 5, 10 and 15 kbar, at temperatures of 700900°C,and under fluid-absent and 5% H2O-present conditions. The experimentsshow that fluid-absent melting begins at near-solidus conditions,around 700°C, promoted by participation of retrogressivephengitic muscovite in the reaction Mus + Kf ± Qz = melt± FeTi oxide ± Als, producing a very smallamount of melt (<9%) with widely ranging composition. Allhypersolidus experiments (>800°C) produced S-type graniticmelts promoted by participation of biotite or cordierite inthe reactions Bio + Pl + Crd + Qz = Px + FeTi oxide +melt at 5 kbar, and Bio + Pl + Crd ± Qz = Grt + Als ±Kf + melt at 10 and 15 kbar, both producing a high amount ofmelt (1063% by volume). The melt compositions obtainedat 900°C and 15 kbar under fluid-absent conditions, promotedby biotite or cordierite breakdown, are similar to the syntectonicgranites. However, it is unlikely that the granites were formedat this pressure (corresponding to a depth of melting of 相似文献
7.
From geometry to dynamics of microstructure: using boundary lengths to quantify boundary misorientations and anisotropy 总被引:1,自引:0,他引:1
John Wheeler Z. Jiang D. J. Prior J. Tullis M. R. Drury P. W. Trimby 《Tectonophysics》2003,376(1-2):19-35
The microstructure of a quartzite experimentally deformed and partially recrystallised at 900 °C, 1.2 GPa confining pressure and strain rate 10−6/s was investigated using orientation contrast and electron backscatter diffraction (EBSD). Boundaries between misoriented domains (grains or subgrains) were determined by image analysis of orientation contrast images. In each domain, EBSD measurements gave the complete quartz lattice orientation and enabled calculation of misorientation angles across every domain boundary. Results are analysed in terms of the boundary density, which for any range of misorientations is the boundary length for that range divided by image area. This allows a more direct comparison of misorientation statistics between different parts of a sample than does a treatment in terms of boundary number.The strain in the quartzite sample is heterogeneous. A 100×150 μm low-strain partially recrystallised subarea C was compared with a high-strain completely recrystallised subarea E. The density of high-angle (>10°) boundaries in E is roughly double that in C, reflecting the greater degree of recrystallisation. Low-angle boundaries in C and E are produced by subgrain rotation. In the low-angle range 0–10° boundary densities in both C and E show an exponential decrease with increasing misorientation. The densities scale with exp(−θ/λ) where λ is approximately 2° in C and 1° in E; in other words, E has a comparative dearth of boundaries in the 8–10° range. We explain this dearth in terms of mobile high-angle boundaries sweeping through and consuming low-angle boundaries as the latter increase misorientation through time. In E, the density of high-angle boundaries is larger than in C, so this sweeping would have been more efficient and could explain the relative paucity of 8–10° boundaries.The boundary density can be generalised to a directional property that gives the degree of anisotropy of the boundary network and its preferred orientation. Despite the imposed strain, the analysed samples show that boundaries are not, on average, strongly aligned. This is a function of the strong sinuosity of high-angle boundaries, caused by grain boundary migration. Low-angle boundaries might be expected, on average, to be aligned in relation to imposed strain but this is not found.Boundary densities and their generalisation in terms of directional properties provide objective measures of microstructure. In this study the patterns they show are interpreted in terms of combined subgrain rotation and migration recrystallisation, but it may be that other microstructural processes give distinctive patterns when analysed in this fashion. 相似文献
8.
WESTON BLAKE JR 《Geografiska Annaler: Series A, Physical Geography》2005,87(1):175-192
ABSTRACT. Crusts of white carbonate precipitate occur commonly on the upper surfaces of glacially sculptured Precambrian granites and gneisses in east-central Ellesmere Island. Radiocarbon dating of 21 such carbonate precipitates, from elevations between 50 m and 1050 m a.s.l., has yielded only Holocene ages. Two samples from Ellesmere Island, plus one from Inglefield Land, Greenland, have calibrated ages over 5000 years, the rest are younger. The formation of these deposits, mainly calcite and characterized by unusually heavy δ13 C ratios (+3.36 to +15.18‰), has apparently been aided in some cases by the presence of bacteria, and some crusts seem to have developed where Ca-bearing minerals are more prevalent. In the case of Bache Peninsula and Cape Herschel, where the carbonate crusts are particularly abundant, the presence of calcareous till may have played a role as well. The carbonate crusts may be related to the presence of small, thin carapace ice caps, when such features formed at lower elevations than those at which they exist today. The more extensive cover of ice and snow is postulated to have existed during the latter, cooler part of the Holocene, especially during the period from 2500 to 100 years ago, deduced as a period of low melt from ice core studies on the Agassiz Ice Cap, 200 km to the north. The existence of carapace ice caps at lower elevations also agrees with the radiocarbon evidence for outlet glacier advances during the last 2000 years on both east and west margins of the Prince of Wales Icefield. Alternatively, the white carbonate crusts may be, to a large degree, the result of weathering processes. In either case they provide minimum ages for the exposed, ice-sculptured rock surfaces on which they occur. 相似文献
9.
Coral mortality may result in macroalgal proliferation or a phase shift into an alga-dominated state. Subtidal, high-latitude western Indian Ocean coral communities at Sodwana Bay on the KwaZulu-Natal coast, South Africa, have experienced some mortality because of warm-water anomalies, storms and other causes, but the response of the macroalgae is unknown. We investigated the abundance and diversity of benthic algae on different hard natural substrata (dead digitate, brain and plate corals and beach rock) on Two-Mile Reef, Sodwana Bay. We also compared algal communities colonising ceramic, marble and pretreated ceramic tiles placed on the reef for six months. We identified 95 algae (14 Chlorophyta, 11 Phaeophyceae, 69 Rhodophyta and one cyanobacterium). Assemblages on natural and artificial substrata were dominated by the brown alga Lobophora variegata (Lamouroux) Womersley ex Oliveira and non-geniculate corallines (Rhodophyta, Corallinaceae). Cluster and ordination analyses revealed that the algae showed no affinity for particular substrata, whether natural or artificial. Algal cover was occasionally higher on rougher tiles and crustose corallines were significantly more abundant on marble than ceramic tiles. Two-Mile Reef had 23.1% dead and 48.4% live scleractinian coral cover, where dead corals were colonised indiscriminately by many small algal species, but there was no evidence of algal proliferation. The results provide a baseline for monitoring this high-latitude reef system. 相似文献
10.
We perform a convergence analysis of the fixed stress split iterative scheme for the Biot system modeling coupled flow and deformation in anisotropic poroelastic media with tensor Biot parameter. The fixed stress split iterative scheme solves the flow subproblem with all components of the stress tensor frozen using a multipoint flux mixed finite element method, followed by the poromechanics subproblem using a conforming Galerkin method in every coupling iteration at each time step. The coupling iterations are repeated until convergence and Backward Euler is employed for time marching. The convergence analysis is based on studying the equations satisfied by the difference of iterates to show that the fixed stress split iterative scheme for anisotropic poroelasticity with Biot tensor is contractive. We also demonstrate that the scheme is numerically convergent using the classical Mandel’s problem solution for transverse isotropy. 相似文献