Distrubution of Dissolved and Particulate Iron, copper and Manganese in the Shelf waters of the Ross sea (Antarctica)     

Carmela Ianni  Paola Rivaro  Roberto Frache 《Marine Ecology》2002,23(S1):210-219

Abstract. During the austral summer 1997–98, within the framework of the activities of the Climatic Long-term Interaction for the Massbalance in Antarctica (CLIMA) Project of the Italian National Program for Antarctic Research (PNRA) in the Ross Sea, measurements were conducted to focus on the role of dissolved iron, copper and manganese as micronutrients, and on their distribution in suspended particulate matter in different water masses. Sampling was carried out in two selected shelf areas, both important for formation and mixing processes of the water bodies.
Metal data were evaluated together with physical measurements and classical chemical parameters such as oxygen and nutrients.
In both the studied areas, the distribution of dissolved metals along the waste column confirmed their micronutrient behaviour, showing depletion where phytoplanktonic activities occurred.
The trend of particulate metals underlined the scavenging phenomena along the water column and presented an interesting correlation at intermediate depths with the amount and origin of suspended matter.  相似文献   

High-resolution rainfall variability simulated by the WRF RCM: application to eastern France     

Romain Marteau  Yves Richard  Benjamin Pohl  Carmela Chateau Smith  Thierry Castel 《Climate Dynamics》2015,44(3-4):1093-1107

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Hydraulic modeling of flood pulses in the Middle Bussento Karst System (MBSKS), UNESCO Cilento Global Geopark,southern Italy          下载免费PDF全文

Vittorio Bovolin  Albina Cuomo  Domenico Guida 《水文研究》2017,31(3):639-653

Karst systems provide water for domestic and industrial uses and for generating hydropower, but they can also create fluvial hazards, such as upstream back‐flooding and downstream karst flash‐flood events. However, these hazards are difficult to foresee due to the complex recharge‐discharge processes as well as the lack of information on the inside of the system, which has often not been completely surveyed by speleologists or explored by boreholes. To overcome these difficulties, hydro‐chemical data from the monitoring system in the Middle Bussento Karst System (MBSKS), one of the first Experimental Karst Systems in southern Italy, were recorded and previously discussed. Based on shared background in flood karst hydraulic modeling, this paper describes the conceptual premises and rationale of a general‐purpose hydraulic model that is suitable both for the MBSKS and for other Mediterranean, multi‐recharge, mature, conduit‐dominated karst systems. To test the reliability of the model, simulations of time–space behavior and response are performed using natural and artificial flood pulses “as tracers”, considering a “pulse” as a significant variation in water quantity and/or quality. The results of the model explain the interactions between allogenic, autogenic, and anthropogenic recharges from differentiated sources and phreatic conduit systems. These results also clarify the overall response of karst springs at typical time scales of flood pulses. Table acronym name  相似文献   

Numerical SPH analysis of debris flow run-out and related river damming scenarios for a local case study in SW China     

Anika Braun  Sabatino Cuomo  Stefano Petrosino  Xueliang Wang  Luqing Zhang 《Landslides》2018,15(3):535-550

A smoothed particle hydrodynamics (SPH) numerical modeling method implemented for the forward simulation of propagation and deposition of flow-type landslides was combined with different empirical geomorphological index approaches for the assessment of the formation of landslide dams and their possible evolution for a local case study in southwestern China. The SPH model was calibrated with a previously occurred landslide that formed a stable dam impounding the main river, and it enabled the simulation of final landslide volumes, and the spatial distribution of the resulting landslide deposits. At four different sites on the endangered slope, landslides of three different volumes were simulated, respectively. All landslides deposited in the main river, bearing the potential for either stable impoundment of the river and upstream flooding scenarios, or sudden breach of incompletely formed or unstable landslide dams and possible outburst floods downstream. With the empirical indices, none of the cases could be identified as stable formed landslide dam when considering thresholds reported in the literature, showing up the limitations of these indices for particular case studies of small or intermediate landslide volumes and the necessity to adapt thresholds accordingly for particular regions or sites. Using the occurred benchmark landslide as a reference, two cases could be identified where a complete blockage occurs that is more stable than the reference case. The other cases where a complete blockage was simulated can be considered as potential dam-breach scenarios.  相似文献   

Multistage evolution of the European lithospheric mantle: new evidence from Sardinian peridotite xenoliths     

Luigi Beccaluva  Gianluca Bianchini  Massimo Coltorti  William Perkins  Franca Siena  Carmela Vaccaro  Marjorie Wilson 《Contributions to Mineralogy and Petrology》2001,142(3):284-297

Peridotite xenoliths entrained in Plio-Pleistocene alkali basalts from Sardinia represent fragments of the uppermost lithospheric mantle, and are characterised by an anhydrous four-phase mineral assemblage. They range in bulk rock composition from fertile spinel-lherzolites to residual spinel-harzburgites. The Sr-Nd isotope and trace element composition of clinopyroxene mineral separates varies between LREE-depleted samples with ⁸⁷Sr/⁸⁶Sr as low as 0.70262 and ¹⁴³Nd/¹⁴⁴Nd up to 0.51323 and LREE-enriched samples with ⁸⁷Sr/⁸⁶Sr up to 0.70461 and ¹⁴³Nd/¹⁴⁴Nd down to 0.51252. The available data suggest that all the studied peridotite samples suffered variable degrees of partial melting during Pre-Mesozoic times (based on Nd model ages relative to CHUR and DMM). The overprinted enrichment is related to a subsequent metasomatism, induced by fluids rising through the lithosphere that preferentially percolated the originally most depleted domains. Despite the occurrence of orogenic volcanism in the area, preferential enrichment in elements typically associated with slab derived fluids/melts (K, Rb, Sr, Th) relative to LREE has not been detected, and metasomatism seems to be more likely related to the infiltration of highly alkaline basic melts characterised by an EM-like Sr-Nd isotopic composition. Similar ⁸⁷Sr/⁸⁶Sr-¹⁴³Nd/¹⁴⁴Nd compositions, characterised by an EM signature, are observed in anorogenic mafic lavas and peridotite xenoliths from widespread localities within the "European" plate, whereas they have not previously been recorded in peridotite xenoliths and associated alkaline mafic lavas from the stable "African" lithospheric domain.  相似文献   

Eruptive history and petrologic evolution of the Albano multiple maar (Alban Hills, Central Italy)     

Carmela Freda  Mario Gaeta  Daniel B. Karner  Fabrizio Marra  Paul R. Renne  Jacopo Taddeucci  Piergiorgio Scarlato  John N. Christensen  Luigi Dallai 《Bulletin of Volcanology》2006,68(6):567-591

A comprehensive volcanological study of the Albano multiple maar (Alban Hills, Italy) using (i) ⁴⁰Ar/³⁹Ar geochronology of the most complete stratigraphic section and other proximal and distal outcrops and (ii) petrographic observations, phase analyses of major and trace elements, and Sr and O isotopic analyses of the pyroclastic deposits shows that volcanic activity at Albano was strongly discontinuous, with a first eruptive cycle at 69±1 ka producing at least two eruptions, and a second cycle with two peaks at 39±1 and 36±1 ka producing at least four eruptions. Contrary to previous studies, we did not find evidence of magmatic or hydromagmatic eruptions younger than 36±1 ka. The activity of Albano was fed by a new batch of primary magma compositionally different from that of the older activity of the Alban Hills; moreover, the REE and ⁸⁷Sr/⁸⁶Sr data indicate that the Albano magma originated from an enriched metasomatized mantle. According to the modeled liquid line of descent, this magma differentiated under the influence of magma/limestone wall rock interaction. Our detailed eruptive and petrologic reconstruction of the Albano Maar evolution substantiates the dormant state of the Alban Hills Volcanic District. Electronic Supplementary Material Supplementary material is available for this article at Editorial responsibility: J. Donnelly-Nolan An erratum to this article can be found at  相似文献   

Distribution of dissolved labile and particulate iron and copper in Terra Nova Bay polynya (Ross Sea,Antarctica) surface waters in relation to nutrients and phytoplankton growth     

Paola Rivaro  Carmela Ianni  Serena Massolo  M. Luisa Abelmoschi  Cinzia De Vittor  Roberto Frache 《Continental Shelf Research》2011,31(7-8):879-889

The distribution of the dissolved labile and of the particulate Fe and Cu together with dissolved oxygen, nutrients, chlorophyll a and total particulate matter was investigated in the surface waters of Terra Nova Bay polynya in mid-January 2003. The measurements were conducted within the framework of the Italian Climatic Long-term Interactions of the Mass balance in Antarctica (CLIMA) Project activities. The labile dissolved fraction was operationally defined by employing the chelating resin Chelex-100, which retains free and loosely bound trace metal species. The dissolved labile Fe ranges from below the detection limit (0.15 nM) to 3.71 nM, while the dissolved labile Cu from below the detection limit (0.10 nM) to 0.90 nM. The lowest concentrations for both metals were observed at 20 m depth (the shallowest depth for which metals were measured). The concentration of the particulate Fe was about 5 times higher than the dissolved Fe concentration, ranging from 0.56 to 24.83 nM with an average of 6.45 nM. The concentration of the particulate Cu ranged from 0.01 to 0.71 nM with an average of 0.17 nM. The values are in agreement with the previous data collected in the same area. We evaluated the role of the Fe and Cu as biolimiting metals. The N:dissolved labile Fe ratios (18,900–130,666) would or would not allow a complete nitrate removal, on the basis of the N:Fe requirement ratios that we calculated considering the N:P and the C:P ratios estimated for diatoms. This finding partially agrees with the Si:N ratio that we found (2.29). Moreover we considered a possible influence of the dissolved labile Cu on the Fe uptake process.  相似文献   

Stochastic behaviour and scaling laws in geoelectrical signals measured in a seismic area of southern Italy     

Vincenzo Cuomo  Vincenzo Lapenna  Maria Macchiato  Carmine Serio  & Luciano Telesca 《Geophysical Journal International》1999,139(3):889-894

We explore the inner dynamics of daily geoelectrical time series measured in a seismic area of the southern Apennine chain (southern Italy). Autoregressive models and the Higuchi fractal method are applied to extract maximum quantitative information about the time dynamics from these geoelectrical signals. First, the predictability of the geoelectrical measurements is investigated using autoregressive models. The procedure is based on two forecasting approaches: the global and the local autoregressive approximations. The first views the data as a realization of a linear stochastic process, whereas the second considers the data points as a realization of a deterministic process, which may be non-linear. Comparison of the predictive skills of the two techniques allows discrimination between low-dimensional chaos and stochastic dynamics. Our findings suggest that the physical systems governing electrical phenomena are characterized by a very large number of degrees of freedom and can be described only with statistical laws. Second, we investigate the stochastic properties of the same geoelectrical signals, searching for scaling laws in the power spectrum. The spectrum fits a power law P (  f )∝  f  ^−α , with the scaling exponent α a typical fingerprint of fractional Brownian processes. In this analysis we apply the Higuchi method, which gives a linear relationship between the fractal dimension D _Σ and the spectral power law scaling index α : D _Σ=(3− α )/2. This analysis highlights the stochastic nature of geoelectrical signals recorded in this seismic area of southern Italy.  相似文献   

Ostreopsis cf. ovata bloom in the northern Adriatic Sea during summer 2009: ecology, molecular characterization and toxin profile     

Accoroni S  Romagnoli T  Colombo F  Pennesi C  Di Camillo CG  Marini M  Battocchi C  Ciminiello P  Dell'Aversano C  Dello Iacovo E  Fattorusso E  Tartaglione L  Penna A  Totti C 《Marine pollution bulletin》2011,62(11):2512-2519

Intense blooms of the benthic dinoflagellate Ostreopsis cf. ovata have occurred in the northern Adriatic Sea since 2006. These blooms are associated with noxious effects on human health and with the mortality of benthic organisms because of the production of palytoxin-like compounds. The O. cf. ovata bloom and its relationships with nutrient concentrations at two stations on the Conero Riviera (northern Adriatic Sea) were investigated in the summer of 2009. O. cf. ovata developed from August to November, with the highest abundances in September (1.3 × 10⁶ cells g⁻¹ fw corresponding to 63.8 × 10³ cells cm⁻²). The presence of the single O. cf. ovata genotype was confirmed by a PCR assay. Bloom developed when the seawater temperature was decreasing. Nutrient concentrations did not seem to affect bloom dynamics. Toxin analysis performed by high resolution liquid chromatography-mass spectrometry revealed a high total toxin content (up to 75 pg cell⁻¹), including putative palytoxin and all the ovatoxins known so far.  相似文献   

Evaluation of wave impact loads on caisson breakwaters based on joint probability of impact maxima and rise times     

Giovanni Cuomo  Rodolfo Piscopia  William Allsop 《Coastal Engineering》2011

When waves break against seawalls, vertical breakwaters, piers or jetties, they abruptly transfer their momentum into the structure. This energy transfer is always spectacular and perpetually unrepeatable but can also be very violent and affect the stability and the integrity of coastal structures. Over the last 15 years, increasing awareness of wave-impact induced structural failures of maritime structures has emphasised the need for a more complete approach to dynamic responses, including effects of impulsive loads. At the same time, movement of design standards toward probabilistic approaches requires new statistical tools able to account for uncertainties in the variability of wave loading processes. This paper presents a new approach to the definition of loads for use in performance design of vertical coastal structures subject to breaking wave impacts.  相似文献