Hydrogeochemical investigations and groundwater provinces of the Friuli Venezia Giulia Plain aquifers,northeastern Italy   总被引：2，自引：0，他引：2  

Franco Cucchi  Giuliana Franceschini  Luca Zini 《Environmental Geology》2008,55(5):985-999

Water resources are a key factor, particularly for the planning of the sustainable regional development of agriculture, as well as for socio-economic development in general. A hydrochemical investigation was conducted in the Friuli Venezia Giulia aquifer systems to identify groundwater evolution, recharge and extent of pollution. Temperature, pH, electric conductivity, total dissolved solids, alkalinity, total hardness, SAR, Ca²⁺, Na⁺, K⁺, Mg²⁺, Cl⁻, SO₄ ²⁻, NO₃ ⁻, HCO₃ ⁻ _, water quality and type, saturation indexes and the environmental stable isotope δ¹⁸O were determined in 149 sampling stations. The pattern of geochemical and oxygen stable isotope variations suggests that the sub-surface groundwater (from phreatic and shallow confined aquifers) is being recharged by modern precipitations and local river infiltrations. Four hydrogeological provinces have been recognised and mapped in the Friuli Venezia Giulia Plain having similar geochemical signatures. These provinces have different degrees of vulnerability to contamination. The deep confined groundwater samples are significantly less impacted by surface activities; and it appears that these important water resources have very low recharge rates and would, therefore, be severely impacted by overabstraction.  相似文献   

Contribution of the SISCam Web-based GIS to the seismotectonic study of Campania (Southern Apennines): an example of application to the Sannio-area     

Rosa Nappi  Giuliana Alessio  Giovanni Bronzino  Carlo Terranova  Giuseppe Vilardo 《Natural Hazards》2008,45(1):73-85

In this article the implementation and potential of the Seismotectonic Information System of the Campania Region (SISCam) are described, in particular an application of this Web-based GIS system to the seismotectonic analysis of the Sannio area (Southern Apennines) is performed. WEB-GIS technologies greatly contribute to both the environmental monitoring and the disaster management of areas affected by high natural risks. Specifically the SISCam system has been developed with the aim of providing easy access and fast diffusion, through Internet technology, of the most significant geological, geophysical, and territorial data relative to the Campania Region. The Sannio area has been selected as our application example because it is among the most active seismic regions in Italy. This portion of the Southern Apennines which was hit by the June 5, 1688 strong earthquake (M _W = 6.7, CPTI 1999) and by some low- and moderate-energy seismic sequences (1990–1992, 1997), is characterized by a complex inherited tectonic setting and low-tectonic deformation rates that hide the seismogenic sources position. Since this case study turned out to be complicated, the use of the SIScam WEB-GIS has become indispensable because it allowed us to visualize, integrate and analyze all the data available, in order to obtain an accurate and direct picture of the seismotectonic setting of the area. Moreover, a different approach of data analysis was necessary, due to the lack of up-to-date neotectonic and structural data; therefore, the operation of this GIS system enabled us to process and generate some original informative layers, through image analysis, such as new structural lineaments represented on a map of the potential active faults of the area, which has been the final result of our application, as a contribution to new knowledge about the local seismic risk parameters.  相似文献   

Holocene climate variability in Sicily from a discontinuous stalagmite record and the Mesolithic to Neolithic transition   总被引：2，自引：0，他引：2  

Silvia Frisia  Andrea Borsato  Augusto Mangini  Christoph Sptl  Giuliana Madonia  Ugo Sauro 《Quaternary Research》2006,66(3):388-400

Fabric and stable isotopic composition of a Holocene stalagmite (CR1) from a cave in northern Sicily record changes in paleorainfall in the early Holocene. High δ¹³C stable isotope values in the calcite deposited from ca. 8500 to ca. 7500 yr ago are interpreted as reflecting periods of high rainfall. The wet phase was interrupted by two periods of multi-century duration characterized by relatively cool and dry winters centered at ca. 8200 and ca. 7500 yr ago, highlighted by low δ¹³C and δ¹⁸O values. A high variability of δ¹³C values is recorded from ca. 7500 to ca. 6500 yr ago and indicates that the transition from a pluvial early Holocene to the present-day climate conditions was punctuated by decadal-scale periods of relatively dry winters. In northern Sicily, the traditional elements of the Neolithic appear at ca. 7700 yr ago. It is possible that changes in rainfall influenced the passage from hunter-gathering to farming and sheep-herding economies.  相似文献   

Estimation of gas-hydrate concentration and free-gas saturation at the Norwegian-Svalbard continental margin     

José M. Carcione  Davide Gei  Giuliana Rossi  Gianni Madrussani 《Geophysical Prospecting》2005,53(6):803-810

We estimate the concentration of gas hydrate and free gas at an area located to the north of the Knipovich Ridge (western Svalbard margin). The method is based on P-wave velocities computed by reflection tomography applied to multicomponent ocean-bottom seismometer data. The tomographic velocity field is fitted to theoretical velocities obtained from a poro-elastic model based on a Biot-type approach (the interaction between the rock frame, gas hydrate and fluid is modelled from first physical principles). We obtain average hydrate concentrations of 7% and maximum free-gas saturations of 0.4% and 9%, depending on the saturation model.  相似文献   

Pollution monitoring with meiofauna,using the ratio of nematodes to copepods     

D.G. Raffaelli  C.F. Mason 《Marine pollution bulletin》1981,12(5):158-163

The ratio of nematodes to copepods was calculated for meiofauna samples from 17 beaches and additional values for intertidal and sublittoral sites were obtained from the literature. Intertidal ratios increased with decreasing particle size, but ratios from polluted sites were always extremely high. Sublittoral ratios increased with depth. It is suggested that this ratio has potential for monitoring organic pollution of sandy beaches.  相似文献   

Occurrence of antifouling paint booster biocides in selected harbors and marinas inside the Gulf of Napoli: a preliminary survey     

Di Landa G  Ansanelli G  Ciccoli R  Cremisini C 《Marine pollution bulletin》2006,52(11):1541-1546

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Arsenite sequestration at the surface of nano-Fe(OH)₂, ferrous-carbonate hydroxide, and green-rust after bioreduction of arsenic-sorbed lepidocrocite by Shewanella putrefaciens     

Georges Ona-Nguema  Guillaume Morin  Yuheng Wang  Farid Juillot  Giuliana Aquilanti  Christian Ruby  François Guyot  Gordon E. Brown Jr. 《Geochimica et cosmochimica acta》2009,73(5):1359-1446

X-ray Absorption Fine Structure (XAFS) spectroscopy was used in combination with high resolution transmission electron microscopy (HRTEM), electron energy loss spectroscopy (EELS), X-ray energy dispersive spectroscopy (XEDS), X-ray powder diffraction, and Mössbauer spectroscopy to obtain detailed information on arsenic and iron speciation in the products of anaerobic reduction of pure and As(V)- or As(III)-adsorbed lepidocrocite (γ-FeOOH) by Shewanella putrefaciens ATCC 12099. We found that this strain of S. putrefaciens is capable of using Fe(III) in lepidocrocite and As(V) in solution or adsorbed on lepidocrocite surfaces as electron acceptors. Bioreduction of lepidocrocite in the absence of arsenic resulted in the formation of hydroxycarbonate green rust 1 [Fe^II₄Fe^III₂(OH)₁₂CO₃: GR1(CO₃)], which completely converted into ferrous-carbonate hydroxide (Fe^II₂(OH)₂CO₃: FCH) over nine months. This study thus provides the first evidence of bacterial reduction of stoichiometric GR1(CO₃) into FCH. Bioreduction of As(III)-adsorbed lepidocrocite also led to the formation of GR1(CO₃) prior to formation of FCH, but the presence of As(III) slows down this transformation, leading to the co-occurrence of both phases after 22-month of aging. At the end of this experiment, As(III) was found to be adsorbed on the surfaces of GR1(CO₃) and FCH. After five months, bioreduction of As(V)-bearing lepidocrocite led directly to the formation of FCH in association with nanometer-sized particles of a minor As-rich Fe(OH)₂ phase, with no evidence for green rust formation. In this five-month experiment, As(V) was fully converted to As(III), which was dominantly sorbed at the surface of the Fe(OH)₂ nanoparticles as oligomers binding to the edges of Fe(OH)₆ octahedra at the edges of the octahedral layers of Fe(OH)₂. These multinuclear As(III) surface complexes are characterized by As-As pairs at a distance of 3.32 ± 0.02 Å and by As-Fe pairs at a distance of 3.50 ± 0.02 Å and represent a new type of As(III) surface complex. Chemical analyses show that the majority of As(III) produced in the experiments with As present is associated with iron-bearing hydroxycarbonate or hydroxide solids, reinforcing the idea that, at least under some circumstances, bacterial reduction can promote As(III) sequestration instead of mobilizing it into solution.  相似文献   

A Snapshot of the Sun Near Solar Minimum: The Whole Heliosphere Interval     

Barbara J. Thompson  Sarah E. Gibson  Peter C. Schroeder  David F. Webb  Charles N. Arge  Mario M. Bisi  Giuliana de Toma  Barbara A. Emery  Antoinette B. Galvin  Deborah A. Haber  Bernard V. Jackson  Elizabeth A. Jensen  Robert J. Leamon  Jiuhou Lei  Periasamy K. Manoharan  M. Leila Mays  Patrick S. McIntosh  Gordon J. D. Petrie  Simon P. Plunkett  Liying Qian  Peter Riley  Steven T. Suess  Munetoshi Tokumaru  Brian T. Welsch  Thomas N. Woods 《Solar physics》2011,274(1-2):29-56

We present an overview of the data and models collected for the Whole Heliosphere Interval, an international campaign to study the three-dimensional solar?Cheliospheric?Cplanetary connected system near solar minimum. The data and models correspond to solar Carrington Rotation 2068 (20 March??C?16 April 2008) extending from below the solar photosphere, through interplanetary space, and down to Earth??s mesosphere. Nearly 200 people participated in aspects of WHI studies, analyzing and interpreting data from nearly 100 instruments and models in order to elucidate the physics of fundamental heliophysical processes. The solar and inner heliospheric data showed structure consistent with the declining phase of the solar cycle. A closely spaced cluster of low-latitude active regions was responsible for an increased level of magnetic activity, while a highly warped current sheet dominated heliospheric structure. The geospace data revealed an unusually high level of activity, driven primarily by the periodic impingement of high-speed streams. The WHI studies traced the solar activity and structure into the heliosphere and geospace, and provided new insight into the nature of the interconnected heliophysical system near solar minimum.  相似文献   

Tracing seafloor methane emissions with benthic foraminifera: Results from the Ana submarine landslide (Eivissa Channel,Western Mediterranean Sea)     

Giuliana Panieri  Angelo Camerlenghi  Isabel Cacho  Cristina Sanchez Cervera  Miquel Canals  Sara Lafuerza  Gemma Herrera 《Marine Geology》2012

The hypothesis that benthic foraminifera are useful proxies of local methane emissions from the seafloor has been verified on sediment core KS16 from the headwall of the Ana submarine landslide in the Eivissa Channel, Western Mediterranean Sea. The core MS312 from a nearby location with no known methane emissions is utilised as control. The core was analysed for biostratigraphy, benthic foraminiferal assemblages, Hyalinea balthica and Uvigerina peregrina carbon and oxygen stable isotope composition, and sedimentary structures. The upper part of the core records post-landslide deglacial and Holocene normal marine hemipelagic sediments with highly abundant benthic foraminifera species that are typical of outer neritic to upper bathyal environment. In this interval, the δ¹³C composition of benthic foraminifera indicates normal marine environment analogous to those found in the control core. Below the sedimentary hiatus caused by the emplacement of the slide, the foraminiferal assemblages are characterised by lower density and higher Shannon Index. Markedly negative δ¹³C shifts in benthic foraminifera are attributed to the release of methane through the seabed. The mean values of the ¹³C anomaly in U. peregrina are ? 0.951 ± 0.208 in the pre-landslide sediments, and ? 0.269 ± 0.152 in post-slide reworked sediments deposited immediately above the hiatus. The δ¹³C anomaly in Hyalinea balthica is ? 2.497 ± 0.080 and ? 2.153 ± 0.087, respectively. To discard the diagenetic effects on the δ¹³C anomaly, which could have been induced by Ca–Mg replacement and authigenic carbonate overgrowth on foraminifera tests, a benthic foraminifera subsample has been treated following an oxidative and reductive cleaning protocol. The cleaning has resulted, only in some cases, in a slight reduction of the anomaly by 0.95% for δ¹³C and < 0.80% for δ¹⁸O. Therefore, the first conclusion is that the diagenetic alteration is minor and it does not alter significantly the overall carbon isotopic anomaly in the core. Consequently, the pre-landslide sediments have been subject to pervasive methane emissions during a time interval of several thousand years. Methane emissions continued during and immediately after the occurrence of Ana Slide at about 61.5 ka. Subsequently, methane emissions decreased and definitely ceased during the last deglaciation and the Holocene.  相似文献   

Implications of nutrient decline in the seagrass ecosystem success     

P.G. Cardoso  S. Leston  M.D. Bordalo  D. Raffaelli 《Marine pollution bulletin》2010,60(4):601-608

The Mondego estuary (Portugal) suffered major changes in environmental quality due to eutrophication, however, in the late 1990s a restoration project was implemented in order to return the system to its original condition. The main goal of this paper is to evaluate the ecosystem response to the restoration measures applied at three different levels: water quality, primary producers and primary consumers.In post-restoration period a clear decline was observed in dissolved inorganic nitrogen which was reflected in the gradual recovery of Zostera noltii and a concomitant decline in green macroalgae.Macrobenthic assemblages responded variably to the recovery process. In the seagrass bed and intermediate area, there was a large increase in total biomass, but in the eutrophic area species diversity increased. Despite improvement in the ecological status of the system, full recovery has not been achieved yet, possible due to hysteresis in the dynamics of this system.  相似文献