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1.
Annually laminated carbonates, known as tufas, commonly develop in limestone areas and typically record seasonal patterns of oxygen- and carbon-isotope compositions. δ18O values are principally controlled by seasonal changes of water temperature, whereas δ13C values are the result of complex reactions among the gaseous, liquid, and solid sources of carbon in the system. We examined the processes that cause the seasonal patterns of δ13C in groundwater systems at three tufa-depositing sites in southwestern Japan by applying model calculations to geochemical data. Underground inorganic carbon species are exchanged with gaseous CO2, which is mainly introduced to the underground hydrological system by natural atmospheric ventilation and by diffusion of soil air. These processes control the seasonal pattern of δ13C, which is low in summer and high in winter. Among the three sites we investigated, we identified two extreme cases of the degree of carbon exchange between liquid and gaseous phases. For the case with high radiocarbon composition (Δ14C) and low pCO2, there was substantial carbon exchange because of a large contribution of atmospheric CO2 and a small water mass. For the other extreme case, which was characterized by low Δ14C and high pCO2, the contribution of atmospheric CO2 was small and the water mass was relatively large. Our results suggest that at two of the three sites water residence time within the soil profile was longer than 1 year. Our results also suggested a short residence time (less than 1 year) of water in the soil profile at the site with the smallest water mass, which is consistent with large seasonal amplitude of the springwater temperature variations. The Δ14C value of tufas is closely related to the hydrological conditions in which they are deposited. If the initial Δ14C value of a tufa-depositing system is stable, 14C-chronology can be used to date paleo-tufas.  相似文献   
2.
Two processes are generally explained as causes of temporal changes in the stoichiometric silicon/nitrogen (Si/N) ratios of sinking particles and of nutrient consumption in the surface water during the spring diatom bloom: (1) physiological changes of diatom under the stress of photosynthesis of diatom and (2) differences of regeneration between silicon and nitrogen. We investigated which process plays an important role in these changes using a one-dimensional ecosystem model that explicitly represents diatom and the other non-silicious phytoplankton. The model was applied to station A7 (41°30′ N, 145°30′ E) in the western North Pacific, where diatom regularly blooms in spring. Model simulations show that the Si/N ratios of the flux exported by the sinking particles at 100 m depth and of nutrient consumptions in the upper 100 m surface water have their maxima at the end of the spring diatom bloom, the values and timings of which are significantly different from each other. Analyses of the model results show that the differences of regeneration between silicon and nitrogen mainly cause the temporal changes of the Si/N ratios. On the other hand, the physiological changes of diatoms under stress can hardly cause these temporal changes, because the effect of the change in the diatom's uptake ratio of silicon to nitrogen is cancelled by that in its sinking rate.  相似文献   
3.
A model based on that of Kishi et al. (2001) has been extended to 15 compartments including silicon and carbon cycles. This model was applied to Station A7 off Hokkaido, Japan, in the Northwestern Pacific. The model successfully simulated the observations of: 1. a spring bloom of diatoms; 2. large seasonal variations of nitrate and silicate concentrations in the surface water; and 3. large inter-annual variations in chlorophyll-a. It also reproduced the observed features of the seasonal variations of carbon dioxide partial pressure (pCO2)—a peak in pCO2 in winter resulting from deep winter convection, a rapid decrease in pCO2 as a result of the spring bloom, and an almost constant pCO2 from summer through fall (when the effect of increasing temperature cancels the effect of biological production). A comparison of cases with and without silicate limitation shows that including silicate limitation in the model results in: 1. decreased production by diatoms during summer; and 2. a transition in the dominant phytoplankton species, from diatoms to other species that do not take up silicate. Both of these phenomena are observed at Station A7, and our results support the hypothesis that they are caused by silicate limitation of diatom growth. This revised version was published online in July 2006 with corrections to the Cover Date.  相似文献   
4.
Mesozoic brackish-water bivalve faunas in Japan diversified in three steps: at the beginning of the Early Jurassic, Early and Late Cretaceous. The Hettangian Niranohama Fauna in northeastern Honshu represents the establishment of a heterodont-dominated brackish-water fauna that persisted until the early Late Cretaceous. No similar composition is known from the Triassic. The infauna consists mostly of non-siphonate and some short-siphonate heterodonts, while the epifauna is represented by diverse pteriomorphian families. In the Early Cretaceous Tetori Group in central Honshu, the long-siphonate heterodonts Tetoria (Corbiculidae) and the semi-infaunal soft-bottom oyster Crassostrea appeared. The evolutionary diversification of the latter, known as the most important element of modern brackish-water faunas, may thus originate at that time. In the early Late Cretaceous (Cenomanian) of the Goshoura and Mifune Groups in west Kyushu, several euryhaline deep-burrowing heterodont families, such as Veneridae and Tellinidae, further diversified in the brackish and marine environments. The Late Cretaceous is characterized by massive shell biolithic beds in which large Crassostrea species are common, a feature common for Cenozoic brackish-water faunas. The long-term changes in the composition of the brackish-water faunas in Japan represents thus an evolutionary record, irrespective of the severe physiological and environmental conditions imposed on the highly conservative nature of the fauna.  相似文献   
5.
6.
The early Cambrian pentamerous microfossil Olivooides/Punctatus in South China, which is characterized by a diagnostic stellate tubular apex, has been well-known for its almost complete development sequence that can be confidently traced from embryos and hatched juveniles, to conical adults. However, its zoological affinity remains highly controversial. Here we describe the internal microanatomic structures of the soft-body inside the peridermal theca of Olivooides multisulcatus Qian, 1977, including interradial pairs of tentacles, adradial and perradial frenula, perradial oral marginal lappets and twins of perradial gastric saccule-like humps as well as a circular velarium with striated coronal muscles. Particularly, one specimen shows bifurcated velarial canals along the bell aperture. Both the components of the soft-body and the external theca (or cyst) are arranged in perfect pentaradial symmetry. These characteristics are more compatible with those of living cubomedusans and co-occurring Cambrian athecate embryonic cubozoans. Concerning the presence of peridermal theca, Olivooides most likely represents an extinct thecate stem-group cubomedusae but devoid of both perradial eyes and specialized pedalia. The well-grown soft body inside the peridermal tube displays a set of mixed features of both polyp and medusa.  相似文献   
7.
The gastropod superfamily Lepetelloidea represents an extremely diverse lineage in terms of their utilization of different deep‐sea organic substrates that include sunken wood, leaves, whale and fish bones, egg cases of sharks and rays, annelid tubes and detrital cephalopod beaks among others. They also inhabit cold seeps and hydrothermal vents, thus presenting an interesting case for the evaluation of such organic substrates as ‘stepping stones’ into these chemosynthetically nourished environments. Here we show the first molecular phylogeny of the Pseudococculinidae, a primarily wood‐dwelling family and the most speciose in Lepetelloidea. Special emphasis is placed on the genus Caymanabyssia, for which the only subfamily Caymanabyssiinae has been established, and a new species Caymanabyssia solis is described herein and compared with previously known taxa in order to reconsider the morphological characteristics of lepetelloids on wood. Bayesian and likelihood trees reconstructed using four‐gene sequences reveal that Pseudococculinidae sensu auctt. is a polyphyletic taxon that is grouped by shared plesiomorphic conditions of characters including the radula, a digestive organ, the morphology of which is often governed strongly by diet and feeding ecology. The newly reinterpreted families Pseudococculinidae and Caymanabyssiidae represent reciprocal sister clades as a basal radiation in Lepetelloidea. Sunken wood might thus have served as an ancestral habitat from which species on other substrates and vent and seep taxa were derived.  相似文献   
8.
9.
Chemical compositions of materials used for new sample holders (vertically aligned carbon nanotubes [VACNTs] and polyimide film), which were developed for the analysis of Hayabusa2‐return samples, were determined by instrumental neutron activation analysis and/or instrumental photon activation analysis, to estimate contamination effects from the sample holders. The synthetic quartz plate used for the sample holders was also analyzed. Ten elements (Na, Al, Cr, Mn, Fe, Ni, Eu, W, Au, and Th) and 14 elements (Na, Al, K, Sc, Ti, Cr, Zn, Ga, Br, Sb, La, Eu, Ir, and Au) could be detected in the VACNTs and polyimide film, respectively. The VACNT data show that contamination by this material with respect to the Murchison meteorite is negligible in terms of the elemental ratios (e.g., Fe/Mn, Na/Al, and Mn/Cr) used for the classification of meteorites due to the extremely low density of VACNTs. However, for the Au/Cr ratio, even small degrees (1.7 wt%) of contamination by VACNTs will change the Au/Cr ratio. Elemental ratios used for the classification of meteorites are only influenced by large amounts of contamination (>60 wt%) of polyimide film, which is unlikely to occur. In contrast, detectable effects on Ti isotopic compositions are caused by >0.1 and >0.3 wt% contamination by VACNTs and polyimide film, respectively, and Hf isotopic changes are caused by >0.1 wt% contamination by VACNTs. The new sample holders (VACNTs and polyimide film) are suitable for chemical classification of Hayabusa2‐return samples, because of their ease of use, applicability to multiple analytical instruments, and low contamination levels for most elements.  相似文献   
10.
More than 30 years of chemical oxygen demand (COD) and dissolved inorganic nitrogen (DIN) data for the inner area of the Ariake Sea were analyzed with a box model to show the changes in the average seasonal budget and the decadal-scale variation during the summer. The COD peaked in August and March on average. This summertime peak can be explained by an enhanced riverine load and increased primary production. The peak in March suggested additional organic matter production. There were also two peaks in DIN concentration on average: a summertime peak that could be explained by an enhanced riverine load, and a peak in December that was more complicated to explain. From the 1970s to the early 1990s, the bottom water in this area became increasingly hypoxic due to increased COD during the summer, even though there were minimal increases in terrestrial COD and nutrient loads and there were tidal flats covering a widespread area during this period. The increase in COD was caused by increased net ecosystem production, which was due to enhanced primary production induced by an increased freshwater residence time and decreased bivalve grazing. There was a negative feedback control in which hypoxia progressively increased, leading to declines in bivalve biomass, which in turn decreased the grazing pressure limiting primary production, meaning that primary production increased and the area became even more hypoxic. The net DIN production decreased during the 1980s and the 1990s. This was consistent with the change in net ecosystem production according to the COD.  相似文献   
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