Sewage sludge ash (SSA), the waste generated in sewage sludge incineration, was obtained from Wuhan Sewage Treatment Plant and used as a low-cost sorbent for removing Cu(Ⅱ) from wastewaters. The sorbent was first modified with 5 % sulfuric acid to increase its sorption capacity. The specific surface area, porosity, cation-exchange capacity (CEC) and pHZPC of the sorbent were measured. Batch experiments were made to study the effect of contact time, solution pH value and temperature on sorption. Both Langmuir and Freundlich models well described the Cu(Ⅱ) sorption process, with correlation coefficient (R2) values of 0.993 4 and 0.989 9 respectively. And the sorption process follows the Lagergren first order kinetic model. The equilibrium sorption capacity of acidified SSA to Cu(Ⅱ) is estimated to be 7.78 mg/g under optimal conditions. 相似文献
The mechanisms behind the seasonal deepening of the mixed layer(ML) in the subtropical Southeast Pacific were investigated using the monthly Argo data from 2004 to 2012. The region with a deep ML(more than 175 m) was found in the region of(22?–30?S, 105?–90?W), reaching its maximum depth(~200 m) near(27?–28?S, 100?W) in September. The relative importance of horizontal density advection in determining the maximum ML location is discussed qualitatively. Downward Ekman pumping is key to determining the eastern boundary of the deep ML region. In addition, zonal density advection by the subtropical countercurrent(STCC) in the subtropical Southwest Pacific determines its western boundary, by carrying lighter water to strengthen the stratification and form a "shallow tongue" of ML depth to block the westward extension of the deep ML in the STCC region. The temperature advection by the STCC is the main source for large heat loss from the subtropical Southwest Pacific. Finally, the combined effect of net surface heat flux and meridional density advection by the subtropical gyre determines the northern and southern boundaries of the deep ML region: the ocean heat loss at the surface gradually increases from 22?S to 35?S, while the meridional density advection by the subtropical gyre strengthens the stratification south of the maximum ML depth and weakens the stratification to the north. The freshwater flux contribution to deepening the ML during austral winter is limited. The results are useful for understanding the role of ocean dynamics in the ML formation in the subtropical Southeast Pacific. 相似文献
With increased demand for the tunnel construction in rock–soil interface composite formations, the influence on surrounding environment especially the excavation face instability during construction and ground settlement in the long term has gained great attention. The researches about environmental disturbance by shield tunneling construction in single ground as the soil or rock conditions have been developed continuously. However, due to the complexity and uncertainty of the interaction between rock–soil interface composite formations and shield machines, works on these special conditions have not been carried out sufficiently. In this paper the theoretical, experimental and numerical researches on the excavation face stability and ground settlement are discussed while the in situ datum are used to support them. First, the typical projects in rock–soil interface composite formations are listed and the difficulties met are summarized. Second, the failure model of excavation face and support pressure from the tunneling shield in rock–soil interface composite formations are discussed. Then, a comprehensive survey of the factors of ground settlement during and after construction and some effective prediction models are made. Finally, the existing problems and directions for future research are introduced. 相似文献
In order to reduce the effects of the low strength and high compressibility of soft soil, geosynthetic-reinforced pile foundations (GRPF) are widely applied for the construction of high-speed railways. Though its reinforcement effect is proved acceptable in practices so far, it is unclear whether it will keep this performance as the train speed continues increasing. Since it is impossible to study the problem in field tests, only mathematical and physical models can be used. However, the nonlinear behaviour of the soft soil complicates the use of analytical models. Therefore, this paper presents a small-scale model test to study the possible changes in stress distribution and deformation in the GRPF under increasing dynamic loads. One test with a natural foundation, without piles or geosynthetic, shows the difference with a similar construction with GRPF foundation. Furthermore, three GRPF tests show the influence of the embankment thickness. The results show the long-term dynamic loading significantly affects the dynamic stress and displacements of the subsoil between the piles of the GRPF. This effect can be divided into three stages with an increasing level of load amplitude: no impact, advantageous impact, and adverse impact. When the dynamic load reaches the adverse impact stage, the long-term dynamic loads reduce the dynamic pile–soil stress ratio, which means that more soil settlement will develop, because more dynamic stress is applied to the soft soil. The test results show that the reduction in dynamic stress on the subsoil in the GRPF construction is clearly lower than the dynamic stress on the natural foundation, due to the existence of rigid piles. Moreover, a thicker embankment gives significantly lower dynamic stresses on the subsoil between the piles. For the thickest embankment tested, the adverse impact stage was not found at all: the arching kept enhancing under long-term dynamic loading with high load amplitudes.
This paper applies the narrow band Internet of things communication technology to develop a wireless network equipment and communication system, which can quickly set up a network with a radius of 100 km on water surface. A disposable micro buoy based on narrow-band Internet of things and Beidou positioning function is also developed and used to collect surface hydrodynamic data online. In addition, a web-based public service platform is designed for the analysis and visualization of the data collected by buoys. Combined with the satellite remote sensing data, the study carries a series of marine experiments and studies such as sediment deposition tracking and garbage floating tracking. 相似文献