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Buntsandstein deposits generated in a slowly subsiding basin on the western margin of the Iberian Chain are represented by a stratigraphic succession of fluvial deposits less than 100 m thick (conglomerates, sandstones, and shales). Diagenetic processes in sandstones can be grouped as eodiagenetic, mesodiagenetic, and telodiagenetic. Eodiagenesis can be associated with Muschelkalk, Keuper, and probably early Jurassic times. Mesodiagenesis is probably related to Jurassic times. Diagenetic chemical reactions suggest a maximum burial less than 1.5 km and low temperatures (<120°C). Patterns of porosity reduction by compaction and cementation suggest four diagenetic stages: (1) Loss of primary porosity by early mechanical compaction; (2) early cementation (K-feldspar and dolomite); (3) dissolution of cements; and (4) framework collapse by re-compaction. These stages are manifested by the presence of two types of sandstone. Type I sandstones present high intergranular volume (mean, 30%). Type II sandstones are characterized by high compactional porosity loss and exhibit low values of intergranular volume (mean, 16.9%). Type II sandstones are associated with the dissolution of cement and later re-compaction of type I sandstones. An intermediate telodiagenetic phase is deduced and related to the sharp unconformity between Lower Cretaceous sediments and the underlying sediments. This suggests that a mechanically unstable framework collapsed during the Cretaceous, generating type II sandstones. The analyzed diagenetic paths have a wide applicability on similar marginal areas of rift basins. 相似文献
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Feng Ding Volkhard Spiess Ian R. MacDonald Markus Brüning Noemi Fekete Gerhard Bohrmann 《Marine and Petroleum Geology》2010,27(4):959-972
During German R/V Meteor M67/2 expedition to Campeche Knolls, southern Gulf of Mexico, a set of 2D high resolution seismic data was acquired to study the near-surface sediment structure and its relationship with hydrocarbon seepages in this salt province. The comprehensive survey covered 20 individual bathymetric highs or ridges and identified three principle structural types: Passive Type, Chaopopte Type, and Asymmetric Flap Type. The first type is the result of passive diapirism, whereas the latter two were initialized by a regional compressional event in the Miocene, but are later differently modified by salt tectonism. Chapopote Type structures appear as symmetrical domes, with uplifted coarse-grained Miocene sediments in their cores and rather thin syn-kinematic sediments covering the crests. Asymmetric Flap Type structures are also first folded as domes or ridges, but one flap later subsided together with salt evacuation, resulting in single uplifted monoclines. With the coarse-grained pre-kinematic sediments as reservoir units, both structural types can focus and accumulate hydrocarbons. The geometries of the structures suggest that hydrocarbons are accumulated in the center of the Chapopote Type structures and in the subsided flaps of the Asymmetric Flap Type structures. Hydrocarbon leakage from these thinly sealed reservoirs is regarded as the principle mechanism for the seepage in the study area, and accordingly the most seepage-prone positions are above these reservoirs. The seep locations suggested by analysis of sea-surface oil slick images of SAR satellite data are also examined in this study. These independently derived seep locations confirm the seepage-prone positions to be above the shallow buried reservoirs. This study suggest that the shallow sediment structures control the distribution of the hydrocarbon seeps of the north-western Campeche Knolls, although the hydrocarbons are sourced from the greater depth. 相似文献
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Antonio Martínez Cortizas Jenny K. Sjöström Eleonor E. Ryberg Malin E. Kylander Joeri Kaal Olalla López-Costas Noemi Álvarez Fernández Richard Bindler 《Boreas: An International Journal of Quaternary Research》2021,50(4):1161-1178
Store Mosse (the ‘Great Bog’ in Swedish) is one of the most extensive bog complexes in southern Sweden (~77 km2), where pioneering palaeoenvironmental research has been carried out since the early 20th century. This includes, for example, vegetation changes, carbon and nitrogen dynamics, peat decomposition, atmospheric metal pollution, mineral dust deposition, dendrochronology, and tephrochronology. Even though organic matter (OM) represents the bulk of the peat mass and its compositional change has the potential to provide crucial ecological information on bog responses to environmental factors, peat OM molecular composition has not been addressed in detail. Here, a 568-cm-deep peat sequence was studied at high resolution, by attenuated reflectance Fourier-transform infrared spectroscopy (FTIR-ATR) in the mid-infrared region (4000–400 cm–1). Principal components analysis was performed on selected absorbances and change-point modelling was applied to the records to determine the timing of changes. Four components accounted for peat composition: (i) depletion/accumulation of labile (i.e. carbohydrates) and recalcitrant (i.e. lignin and other aromatics, aliphatics, organic acids and some N compounds) compounds, due to peat decomposition; (ii) variations in N compounds and carbohydrates; (iii) residual variation of lignin and organic acids; and (iv) residual variation of aliphatic structures. Peat decomposition showed two main patterns: a long-term trend highly correlated to peat age (r = 0.87), and a short-term trend, which showed five main phases of increased decomposition (at ~8.4–8.1, ~7.0–5.6, ~3.5–3.1, ~2.7–2.1 and ~1.6–1.3 ka) – mostly corresponding to drier climate and its effect on bog hydrology. The high peat accumulation event (~5.6–3.9 ka), described in earlier studies, is characterized by the lowest degree of peat decomposition of the whole record. Given that FTIR-ATR is a quick, non-destructive, cost-effective technique, our results indicate that it can be applied in a systematic way (including multicore studies) to peat research and provide relevant information on the evolution of peatlands. 相似文献
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Marc H. Taylor Jorge Tam Vernica Blaskovic Pepe Espinoza R. Michael Balln Claudia Wosnitza-Mendo Juan Argüelles Erich Díaz Sara Purca Noemi Ochoa Patricia Ayn Elisa Goya Dimitri Gutirrez Luis Quipuzcoa Matthias Wolff 《Progress in Oceanography》2008,79(2-4):366
The Northern Humboldt Current Ecosystem is one of the most productive in the world in terms of fish production. Its location near to the equator permits strong upwelling under relatively low winds, thus creating optimal conditions for the development of plankton communities. These communities ultimately support abundant populations of grazing fish such as the Peruvian anchoveta, Engraulis ringens. The ecosystem is also subject to strong inter-annual environmental variability associated with the El Niño Southern Oscillation (ENSO), which has major effects on nutrient structure, primary production, and higher trophic levels. Here our objective is to model the contributions of several external drivers (i.e. reconstructed phytoplankton changes, fish immigration, and fishing rate) and internal control mechanisms (i.e. predator-prey) to ecosystem dynamics over an ENSO cycle. Steady-state models and time-series data from the Instituto del Mar del Perú (IMARPE) from 1995 to 2004 provide the base data for simulations conducted with the program Ecopath with Ecosim. In simulations all three external drivers contribute to ecosystem dynamics. Changes in phytoplankton quantity and composition (i.e. contribution of diatoms and dino- and silicoflagellates), as affected by upwelling intensity, were important in dynamics of the El Niño of 1997–98 and the subsequent 3 years. The expansion and immigration of mesopelagic fish populations during El Niño was important for dynamics in following years. Fishing rate changes were the most important of the three external drivers tested, helping to explain observed dynamics throughout the modeled period, and particularly during the post-El Niño period. Internal control settings show a mix of predator–prey control settings; however a “wasp-waist” control of the ecosystem by small pelagic fish is not supported. 相似文献
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Julie Ziffer Humberto Campins Javier Licandro Noemi Pinilla-Alonso Yanga Fernandez Schelte J. Bus 《Earth, Moon, and Planets》2005,97(3-4):203-212
We present near infrared reflectance spectra from 0.8 to 2.5 μm of two asteroids with low Tisserand invariant, 1373 Cincinnati and 2906 Caltech. We compare our spectra with cometary nuclei and other asteroids in their class. Asteroids Cincinnati and Caltech have Tisserand invariant values of 2.72 and 2.97, respectively, values less than 3 are considered suggestive of cometary origin. The observed spectral slopes in the near-infrared are consistent with both the spectra of cometary nuclei and of primitive asteroids. However, both asteroids have features in the near-infrared that are not seen in cometary nuclei, but are present in other X-type asteroids. 1373 Cincinnati has a sharp slope change between 0.75 and 1.0 μm and 2906 Caltech has a broad and shallow absorption between 1.35 and 2.2 μm. Our attempts to model the visible and near-infrared spectrum of these two objects, with the components successfully used by Emery and Brown (2004, Icarus
164, 104–121) to fit Trojan asteroids, did not yield acceptable fits.Visiting Astronomer at the Infrared Telescope Facility, which is operated by the University of Hawaii under contract to the National Aeronautics and Space Administration. 相似文献
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Kurt H. Wogau Carlos E. Cordova Luis Morett-Alatorre Guillermo Acosta Ochoa 《Geoarchaeology》2024,39(2):168-182
Located in the Basin of Mexico, the eastern shore of former Lake Texcoco sustained a variety of human occupations throughout the Holocene, including preceramic hunter-gatherers, incipient agriculturalists, and a variety of settlements in the ceramic periods. Nonetheless, the environmental dynamics of occupations on the lakeshore have not been fully addressed. The Archaic preagricultural Texcoco Man site (>5000 B.C.E.) and the Late Formative TX-LF-14 site (c. 550-200 B.C.E.), among others, occupy this fluvio-lacustrine transitional environment. Few stratigraphic works in and around the sites have been performed. Consequently, it is difficult to understand the dynamics of the sedimentary system in space and time. This work highlights and describes the fluvio-lacustrine sedimentary dynamics and the resulting landscape that past societies inhabited on the eastern shore of Texcoco Lake. Because the study area has been altered by historic and modern draining, our work employs Lake Santiaguillo and its main tributary, the Tejamen River in the Durango state, as a modern analog to study their sedimentary dynamics. The analyses of surface geomorphology in the Texcoco study area were employed to corroborate the modern analog interpretation. To achieve these goals, we conducted a GIS-based morphometric analysis and LANDSAT-8 imagery to study the variations in landforms through wet and dry events. The results indicate an increase in the lake volume, low bifurcation in the active fluvial channels, few inundated surfaces, and the presence of bird-foot deltaic channels during high precipitation events. In contrast, low precipitation events are characterized by reduced lake volume, increased fluvial channel bifurcation, and expanded floodplains. This heterogeneous landscape thus provided a rich source of diverse natural resources of saline and freshwater aquatic habitats. Simultaneously, constant or recurring flooding events generated a challenging landscape for prehistoric settlers who implemented diverse technologies, such as the construction of tlateles, on the levees of deltaic channels to reduce the risk and impact of flooding events. 相似文献
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Victoria Ochoa Carmen Riva Melissa Faria Carlos Barata 《Marine pollution bulletin》2013,66(1-2):135-142
Marine bivalves such as oysters are widely used as bioindicators to monitor marine coastal pollution. This study aimed to use B-esterase activity responses in oysters (Crassostrea gigas) cultured in Ebro Delta bays to monitor environmental effects of pesticides. The B esterases investigated were acetylcholinesterase, propionylcholinesterase, and carboxylesterase and their activities were measured in adductor muscle and gills from oysters transplanted in Ebro Delta bays where the are traditionally grown. Enzyme activities were related with physico-chemical parameters and pesticide levels measured in water. Cholinesterase activities measured in gills were unaffected across sites and periods. Conversely, carboxylesterase activities in oyster gills varied across periods and sites and were negatively correlated with residue levels of organophoshporous and carbamate pesticides in water. Therefore, inhibition of carboxylesterase activities can be considered a good indicator of exposure to anti-cholinergic pesticides in oysters. 相似文献
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Cristina Morea Dalle Ore Luciano V. Dalle Ore Ted L. Roush Dale P. Cruikshank Joshua P. Emery Noemi Pinilla-Alonso Giuseppe A. Marzo 《Icarus》2013,222(1):307-322
Trans-neptunian objects (TNOs) are a population of small objects orbiting the Sun beyond Neptune. Because of their distance they are difficult to observe spectroscopically, but a large body of photometric observations is available and growing. TNOs are important tracers of the evolution of the outer Solar System and key when testing current dynamical evolution theories. Previous statistical studies of the colors of TNOs have yielded useful but limited results regarding the chemical history and evolution of these bodies.With the aim at obtaining compositional information on the small and distant TNOs we introduce a statistical cluster analysis (labelled albedo) based on colors and published albedos of TNOs. We compare it to a previous taxonomy, to illustrate the significance of including the albedo information when determining the composition of the objects. When the albedo contribution is removed from the data, the new taxonomy (now labelled classical) is in general agreement with the published ones, supporting the applicability of our approach. Making use of modeled reflectance spectra of a variety of plausible mixtures found on the surface of TNOs, we extract the average surface composition of each taxon, for both the classical and the albedo taxonomy, in a statistically consistent fashion.Differently from previous and classical, the albedo taxonomy establishes a direct link between the colors and albedos of the objects and their surface composition, allowing, for the first time, a quick assessment of the chemical history of TNOs. In fact, under closer examination the taxa show trends in composition that might be evolutionary in nature. If a simple ‘snow lines’ model is adopted, we can infer that albedo taxa relate the current objects’ locations to their original ones, prior to the migration of the outer planets. We regard the large population that characterizes the darkest classes spread at a variety of semi-major axis distances as one of the intriguing results of this work. 相似文献