Nitrogen uptake,ammonium oxidation and nitrous oxide (N₂O) levels in the coastal waters of western Cook Strait,New Zealand     

John C. Priscu  Malcolm T. Downes 《Estuarine, Coastal and Shelf Science》1985,20(5):529-542

Vertical measurements of $\text{NH}{}_4{}^{\mathrm{+}}$, $\text{NO}{}_3{}^{\mathrm{?}}$ and N₂O concentrations, $\text{NO}{}_3{}^{\mathrm{?}}$ and $\text{NH}{}_4{}^{\mathrm{+}}$ uptake, and $\text{NH}{}_4{}^{\mathrm{+}}$ oxidation rates were measured at 5 sites in western Cook Strait, New Zealand, between 31 March and 3 April 1983. Nitrate increased with depth at all stations reaching a maximum of 10.5 μg-atom $\text{NO}{}_3{}^{\mathrm{?}}\text{N l}{}^{\mathrm{?1}}$ at the most strongly stratified station whereas $\text{NH}{}_4{}^{\mathrm{+}}$ was relatively constant with depth at all stations (～0.1 μg-atom $\text{NH}{}_4{}^{\mathrm{+}}\text{N l}{}^{\mathrm{?1}}$). The highest rates of $\text{NH}{}_4{}^{\mathrm{+}}$ oxidation generally occurred in the near surface waters and decreased with depth. N₂O levels were near saturation with respect to the air above the sea surface and showed no obvious changes during 24 h incubation. $\text{NH}{}_4{}^{\mathrm{+}}$ oxidation by nitrifying bacteria may account for about 30% of the total $\text{NH}{}_4{}^{\mathrm{+}}$ utilization (i.e. bacterial+agal) and, assuming oxidation through to $\text{NO}{}_3{}^{\mathrm{?}}$, may supply about 40% of the algal requirements of $\text{NO}{}_3{}^{\mathrm{?}}$ in the study area. These results suggest that bacterial nitrification is of potential importance to the nitrogen dynamics of the western Cook Strait, particularly with respect to the nitrogen demands of the phytoplankton.  相似文献   

Isotopic partitioning between scallop shell calcite and seawater: effect of shell growth rate     

Richard Owen  Hilary KennedyChristopher Richardson 《Geochimica et cosmochimica acta》2002,66(10):1727-1737

The relationship between molluscan shell growth rate and skeletal δ¹⁸O and δ¹³C was investigated in a detailed field study for the scallop, Pecten maximus. Seasonal variation in shell growth rate was found to be a governing factor influencing shell δ¹⁸O and δ¹³C. At low shell growth rates, shell δ¹⁸O were more positive (of the order +0.4‰) and δ¹³C more negative (up to −2‰) as compared with predicted values for precipitation of inorganic calcite in isotopic equilibrium with seawater. The deviations in δ¹⁸O were hypothesized as reflecting possible differences in solution carbonate chemistry at the site of mineralization in the extrapallial fluid as compared with that of the external seawater medium. The deviations in shell δ¹³C were consistent with incorporation of isotopically depleted respiratory ¹³C (i.e., a metabolic effect). A trend toward more depleted shell δ¹⁸O and δ¹³C values occurred at higher shell growth rates, with negative δ¹⁸O values as compared with predicted equilibrium at shell growth rates above 0.13 mm per day. These simultaneous negative deviations in skeletal δ¹⁸O and δ¹³C were interpreted as resulting from a kinetic effect. The implications for environmental reconstruction from molluscan isotopic records are discussed in light of a model of isotopic behavior based on the findings of the study.  相似文献   

Determining the trophic guilds of fishes and macroinvertebrates in a seagrass food web     

Joseph J. Luczkovich  Garcy P. Ward  Jeffrey C. Johnson  Robert R. Christian  Daniel Baird  Hilary Neckles  William M. Rizzo 《Estuaries and Coasts》2002,25(6):1143-1163

We established trophic guilds of macroinvertebrate and fish taxa using correspondence analysis and a hierarchical clustering strategy for a seagrass food web in winter in the northeastern Gulf of Mexico. To create the diet matrix, we characterized the trophic linkages of macroinvertebrate and fish taxa present inHalodule wrightii seagrass habitat areas within the St. Marks National Wildlife Refuge (Florida) using binary data, combining dietary links obtained from relevant literature for macroinvertebrates with stomach analysis of common fishes collected during January and February of 1994. Heirarchical average-linkage cluster analysis of the 73 taxa of fishes and macroinvertebrates in the diet matrix yielded 14 clusters with diet similarity ≥ 0.60. We then used correspondence analysis with three factors to jointly plot the coordinates of the consumers (identified by cluster membership) and of the 33 food sources. Correspondence analysis served as a visualization tool for assigning each taxon to one of eight trophic guilds: herbivores, detritivores, suspension feeders, omnivores, molluscivores, meiobenthos consumers, macrobenthos consumers and piscivores. These trophic groups, corss-classified with major taxonomic groups, were further used to develop consumer compartments in a network analysis model of carbon flow in this seagrass ecosystem. The method presented here should greatly improve the development of future network models of food webs by providing an objective procedure for aggregating trophic groups.  相似文献   

Lower crustal granulite xenoliths from the Pannonian Basin,Hungary, Part 2: Sr–Nd–Pb–Hf and O isotope evidence for formation of continental lower crust by tectonic emplacement of oceanic crust   总被引：3，自引：0，他引：3  

Gábor Dobosi  Pamela D. Kempton  Hilary Downes  Antal Embey-Isztin  Matthew Thirlwall  Peter Greenwood 《Contributions to Mineralogy and Petrology》2003,144(6):671-683

Mafic granulite xenoliths from the lower crust of the Pannonian Basin are dominated by LREE-depleted bulk-rock compositions. Many of these have MORB-like ¹⁴³Nd/¹⁴⁴Nd but ⁸⁷Sr/⁸⁶Sr is elevated relative to most MORBs. Their '¹⁸O values cover a wide range from +3.8 to +9.5‰. A group of LREE-enriched mafic granulites have higher ⁸⁷Sr/⁸⁶Sr (0.704-0.708) and lower ¹⁴³Nd/¹⁴⁴Nd (0.5128-0.5124), with higher '¹⁸O values on average (+7.8 to +10.6‰) than the LREE-depleted granulites. The LREE-enriched granulites are, however, isotopically similar to newly discovered metasedimentary granulite xenoliths. A sublinear correlation in )Hf-)Nd isotope space has a shallower slope than the crust-mantle array, with the metasedimentary rocks forming the low )Hf end member; the radiogenic end is restricted to the LREE-depleted granulites and these overlap the field of MORB. Pb isotopes for the LREE-depleted samples are less radiogenic on average than those of the LREE-enriched and metasedimentary xenoliths, and metasedimentary granulites have consistently higher ²⁰⁸Pb/²⁰⁴Pb. The wide range in '¹⁸O over a restricted range in Nd and Sr isotope values, in combination with the predominance of LREE-depleted trace-element compositions, is consistent with an origin as a package of hydrothermally altered oceanic crust. The existence of '¹⁸O values lower than average MORB and/or mantle peridotite requires that at least some of these rocks were hydrothermally altered at high temperature, presumably in the oceanic lower crust. The low ¹⁴³Nd/¹⁴⁴Nd of the LREE-enriched mafic granulites cannot be explained by simple mixing between a LREE-depleted melt and an enriched component, represented by the recovered metasediments. Instead, we interpret these rocks as the metamorphic equivalent of the shallowest levels of the ocean crust where pillow basalts are intimately intercalated with oceanic sediments. A possible model is accretion of oceanic crustal slices during subduction and convergence, followed by high-grade metamorphism during the Alpine orogeny.  相似文献   

Granulite and pyroxenite xenoliths from the Deccan Trap: insight into the nature and composition of the lower lithosphere beneath cratonic India     

A.G. Dessai  A. Markwick  H. Downes 《Lithos》2004,78(3):263-290

Granulite and pyroxenite xenoliths in lamprophyre dykes intruded during the waning stage of Deccan Trap volcanism are derived from the lower crust beneath the Dharwar craton of Western India. The xenolith suite consists of plagioclase-poor mafic granulites (55% of the total volume of xenoliths), plagioclase-rich felsic granulites (25%), and ultramafic pyroxenites and websterites (20%) with subordinate wehrlites. Rare spinel peridotite xenoliths are also present, representing mantle lithosphere. The high Mg #, low SiO₂/Al₂O₃ and low Nb/La (<1) ratios suggest that the protoliths of the mafic granulites broadly represent cumulates of sub-alkaline magmas. All of the granulites are peraluminous and light rare-earth element-enriched. The felsic granulites may have resulted from anatexis of the mafic lower crustal rocks; thus, the mafic granulites are enriched in Sr whereas the felsic ones are depleted. Composite xenoliths consisting of mafic granulites traversed by veins of pyroxenite indicate intrusion of the granulitic lower crust by younger pyroxenites. Petrography and geochemistry of the latter (e.g. presence of phlogopite) indicate the metasomatised nature of the deep crust in this region.Thermobarometric estimates from phase equilibria indicate equilibration conditions between 650 and 1200 °C, 0.7-1.2 GPa suggestive of lower crustal environments. These estimates provide a spatial context for the sampled lithologies thereby placing constraints on the interpretation of geophysical data. Integration of xenolith-derived P-T results with Deep Seismic Soundings (DSS) data suggests that the pyroxenites and websterites are transitional between the lower crust and the upper mantle. A three-layer model for the crust in western India, derived from the xenoliths, is consistent with DSS data. The mafic nature of this hybrid lower crust contrasts with the felsic lower crustal composition of the south Indian granulite terrain.  相似文献   

Viruses as potential regulators of regional brown tide blooms caused by the alga,Aureococcus anophagefferens     

Mary Downes Gastrich  Justine A. Leigh-Bell  Christopher J. Gobler  O. Roger Anderson  Steven W. Wilhelm  Martha Bryan 《Estuaries and Coasts》2004,27(1):112-119

Blooms of the brown tide organismAureccoccus anophagefferens have recurred in the coastal bays in New Jersey since 1995 and in the coastal bays of Long Island since 1985. Intracellular viral-like particles (VLPs) were documented during 1999–2000 brown tide blooms in Little Egg Harbor, New Jersey, but it was not determined whether cells were infected during the termination of the bloom. The objective of this study was to determine if VLPs infected and lysed natural populations ofA. anophagefferens in coastal bays of New Jersey and New York in 2002 with the same frequency as in 1999–2000 and especially at the termination of the bloom. Our results confirmed that the highest percentage (37.5%) of VLP-infected cells occurred at the termination of the brown tide bloom in New Jersey in 2002. Intracellular VLPs were present throughout the bloom event. The percentage of visibly infected cells was higher at the beginning of the bloom than during the peak of the bloom. The intracellular VLPs in natural populations ofA. anophagefferens were consistent in size and shape (approximately 140 nm in diameter) and comparable to those in previous studies. Concentrated viral isolates, prepared from waters during brown tide blooms in New York and New Jersey in 2002, infected healthy laboratoryA. anophagefferens cultures in vitro. The viral isolates associated with the highest laboratory viral activity (lysis positive) were concentrated from water samples having the highest viral and bacteria concentrations. The intracellular viruses in these virally infected laboratory cultures ofA. anophagefferens were similar in size and shape to those found in natural populations. The successful isolation of a virus specific toA. anophagefferens from a brown tide bloom in the field, the similarity of ultrastructure of VLPs infecting both natural populations and laboratory infected cultures, and the pattern of VLP infection during bloom activity in combination with the observed high percentage of VLP-infected cells during bloom termination, supports, the hypothesis that viruses may be a major source of mortality for brown tide blooms in regional coastal bays of New Jersey and New York.  相似文献   

Spatial variability of hydrological processes and model structure diagnostics in a 50 km2 catchment          下载免费PDF全文

Hilary McMillan  Myriam Gueguen  Elisabeth Grimon  Ross Woods  Martyn Clark  David E. Rupp 《水文研究》2014,28(18):4896-4913

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Groundwater facie analysis in the upper Cross River basin,southeast Nigeria     

Stephen N. Ukpai  Paulinus N. Nnabo  Hilary N. Eze 《Environmental Earth Sciences》2016,75(20):1345

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Dynamics of epiphytic photoautotrophs and heterotrophs inZostera marina (eelgrass) microcosms: Responses to nutrient enrichment and grazing     

Hilary A. Neckles  Eric T. Koepfler  Leonard W. Haas  Richard L. Wetzel  Robert J. Orth 《Estuaries and Coasts》1994,17(3):597-605

The combined effects of nutrient enrichment and grazing by isopods and amphipods on abundances of seagrass epiphytes were tested inZostera marina L. (eelgrass) microcosms. Using epifluorescence microscopy, densities of epiphytic diatoms, cyanobacteria, heterotrophic flagellates, and heterotrophic bacteria were enumerated after 1 mo and 2 mo of treatment. In general, numbers of diatoms decreased, in the presence of grazers and showed little response to nutrient enrichment, whereas numbers of cyanobacteria increased with nutrient enrichment and showed little response to grazing. Thus, macrofaunal grazing maintained a photoautotrophic community domainated by cyanobacteria, particularly under nutrient enriched conditions. Following 2 mo of treatment, dense macroalgal growth under nutrient-enriched conditins with grazers absent appeared to limit populations of both epiphytic autotrophs. Patterns of abundance of heterotrophic bacteria suggested that the original bacteria population was nutrient limited. Bacteria populations may have been limited by organic carbon supplies at the end of the experiment. Abundances of heterotrophic flagellates and bacteria were strongly correlated on both sampling dates. Results suggest that heterotrophic flagellates might serve as a link between heterotrophic bacterial production and higher trophic levels in seagrass epiphyte food webs.  相似文献   

Sr and Nd isotope geochemistry of coexisting alkaline magma series,Cantal, Massif Central,France     

Hilary Downes 《Earth and Planetary Science Letters》1984,69(2):321-334

Sr and Nd isotope analyses are presented for Tertiary continental alkaline volcanics from Cantal, Massif Central, France. The volcanics belong to two main magma series, silica-saturated and silica-undersaturated (with rare nephelinites). Trace element and isotopic data indicate a common source for the basic parental magmas of both major series; the nephelinites in contrast must have been derived from a mantle source which is isotopically and chemically distinct from that which gave rise to the basalts and basanites.⁸⁷Sr/⁸⁶Sr initial ratios range from 0.7034 to 0.7056 in the main magma series (excluding rhyolites) and¹⁴³Nd/¹⁴⁴Nd ratios vary between 0.512927 and 0.512669; both are correlated with increasing SiO₂ in the lavas. The data can be explained by a model of crustal contamination linked with fractional crystallisation. This indicates that crustal magma chambers are the sites of differentiation since only rarely do evolved magmas not show a crustal isotopic signature and conversely basic magmas have primitive isotopic ratios unless they contain obvious crustal-derived xenocrysts. Potential contaminants include lower crustal granulites or partial melts of upper crustal units. Equal amounts of contamination are required for both magma series, refuting hypotheses of selective contamination of the silica-saturated series.The isotopic characteristics of the apparently primary nephelinite lavas demonstrates widespread heterogeneity in the mantle beneath Cantal. Some rhyolites, previously thought to be extremely contaminated or to be crustally derived, are shown to have undergone post-emplacement hydrothermal alteration.  相似文献