High-sensitive measurement of uranium L_III-edge X-ray absorption near-edge structure (XANES) for the determination of the oxidation states of uranium in crustal materials     

Yuhei Yamamoto  Yoshio Takahashi  Yutaka Kanai  Yoshio Watanabe  Tomoya Uruga  Hajime Tanida  Yasuko Terada  Hiroshi Shimizu   《Applied Geochemistry》2008,23(8):2452-2461

The uranium L_III-edge XANES spectra for natural rocks at the concentration range of 0.96–124 mg kg⁻¹ were measured using a log spiral bent crystal Laue analyzer (BCLA) combined with a multi-element Ge detector. It was found that the quality of the XANES spectra using the BCLA was greatly improved due to a reduction of interfering fluorescence from major components such as Rb and Sr. The ratio of signal to background intensities in the U L_III-edge XANES spectra increased by a factor of 2.9–17 with the use of the BCLA, which greatly enhanced the detection limit for the speciation of the oxidation states of U or the U(IV)/U(VI) ratio of natural samples. In addition, it was demonstrated that the fluorescence XANES method coupled with the BCLA enable determination of the speciation of U for various natural samples such as acidic igneous rocks, ferromanganese nodules, sediments, and some sedimentary rocks such as shale and limestone.  相似文献   

Stability of Temperature and Conductivity Sensors of Argo Profiling Floats   总被引：7，自引：3，他引：7  

Eitarou Oka  Kentaro Ando 《Journal of Oceanography》2004,60(2):253-258

After recalibration of the temperature and conductivity sensors of three Argo profiling floats recovered after operations for four to nine months, the results indicate that the floats basically showed no significant drift, either in temperature or salinity, and adequately fulfilled the accuracy requirement of the Argo project (0.005°C for temperature and 0.01 psu for salinity). Only the third float showed a significant offset in salinity of about −0.02 psu, as expected from comparison between the float data and the shipboard conductivity-temperature-depth data. This offset was caused by the operational error of the PROVOR-type float, in which the surface water was pumped immediately after the launch, fouling the conductivity sensor cell. This revised version was published online in July 2006 with corrections to the Cover Date.  相似文献   

Growth of chum salmon (Oncorhynchus keta) correlated with sea-surface salinity in the North Pacific   总被引：1，自引：0，他引：1  

Morita  Shoko H.; Morita  Kentaro; Sakano  Hiroyuki 《ICES Journal of Marine Science》2001,58(6):1335-1339

  相似文献   

Validity of sea surface temperature observed with the TRITON buoy under diurnal heating conditions     

Yoshimi Kawai  Hiroshi Kawamura  Sumio Tanba  Kentaro Ando  Kunio Yoneyama  Norio Nagahama 《Journal of Oceanography》2006,62(6):825-838

In order to investigate the validity of buoy-observed sea surface temperature (SST), we installed special instruments to measure near-surface ocean temperature on the TRITON buoy moored at 2.07°N, 138.06°E from 2 to 13 March 2004, in addition to a standard buoy sensor for the regular SST measurement at 1.5-m depth. Large diurnal SST variations were observed during this period, and the variations of the temperatures at about 0.3-m depth could be approximately simulated by a one-dimensional numerical model. However, there was a notable discrepancy between the buoy-observed 1.5-m-depth SST (SST_1.5m) and the corresponding model-simulated temperature only during the daytime when the diurnal rise was large. The evaluation of the heat balance in the sea surface layer showed that the diurnal rise of the SST_1.5m in these cases could not be accounted for by solar heating alone. We examined the depth of the SST_1.5m sensor and the near-surface temperature observed from a ship near the buoy, and came to the conclusion that the solar heating of the buoy hull and/or a disturbance in the temperature field around the buoy hull would contribute to the excessive diurnal rise of the SST_1.5m observed with the TRITON buoy. However, the temperature around the hull was not sufficiently homogenized, as suggested in a previous paper. For the diurnal rise of the SST_1.5m exceeding 0.5 K, the daytime buoy data became doubtful, through dynamics that remain to be clarified. A simple formula is proposed to correct the unexpected diurnal amplitude of the buoy SST_1.5m.  相似文献   

X-ray observation of the Jovian impacts of comet Shoemaker - Levy 9     

Kentaro Terada  Hitoshi Negoro  Kiyoshi Hayashida  Shunji Kitamoto  Hiroshi Tsunemi  Hiroshi Oya  Takayuki Ono  Akira Morioka  Yuzuru Tawara  Toshifumi Mukai  Masahiro Hoshino  Toshio Terasawa 《Earth, Moon, and Planets》1994,66(1):75-81

An ASCA observation of the Jovian impact of the comet Shoemaker-Levy 9 is reported. Four impacts of H, L, Q1 and R were observed and four impacts of B, C, G, and Q2 were observed within 60 minutes after their impacts. No significant flaring of X-ray emission was observed. Upper limit X-ray fluxes of 90 % confidence level, averaged 5 minutes just after the impacts, were 2.4 × 10^–13 erg sec^–1 cm^–2, 3.5 × 10^–13 erg sec^–1 cm^–2, 1.6 × 10^–13 erg sec^–1 cm^–2 and 2.9 × 10^–13 erg sec^–1 cm^–2 for the impacts of H, L, Q1 and R, respectively, in the 0.5(0.7 for H and Q1)–10 keV energy range. However, a hint of X-ray enhancement around Jupiter from July 17 to July 19 was detected with about 2 6 × 10^–14 erg sec^–1 cm^–2 in the 0.5–10 keV energy range.  相似文献   

Rare Earth, Major and Trace Elements in the Kunimiyama Ferromanganese Deposit in the Northern Chichibu Belt, Central Shikoku, Japan   总被引：1，自引：0，他引：1  

Yasuhiro Kato    Koichiro Fujinaga  Tatsuo Nozaki    Kentaro Nakamura    Ryuji Ono  Hiroshi Osawa 《Resource Geology》2005,55(4):291-300

Abstract. Rare earth, major and trace element geochemistry is reported for the Kunimiyama stratiform ferromanganese deposit in the Northern Chichibu Belt, central Shikoku, Japan. The deposit immediately overlies greenstones of mid-ocean ridge basalt (MORB) origin and underlies red chert. The ferromanganese ores exhibit remarkable enrichments in Fe, Mn, P, V, Co, Ni, Zn, Y and rare earth elements (excepting Ce) relative to continental crustal abundance. These enriched elements/ Fe ratios and Post-Archean Average Australian Shale-normalized REE patterns of the ferromanganese ores are generally analogous to those of modern hydrothermal ferromanganese plume fall-out precipitates deposited on MOR flanks. However in more detail, Mn and Ti enrichments in the ferromanganese ores are more striking than the modern counterpart, suggesting a significant contribution of hydrogenetic component in the Kunimiyama ores. Our results are consistent with the interpretation that the Kunimiyama ores were umber deposits that primarily formed by hydrothermal plume fall-out precipitation in the Panthalassa Ocean during the Early Permian and then accreted onto the proto-Japanese island arc during the Middle Jurassic. The presence of strong negative Ce anomaly in the Kunimiyama ores may indicate that the Early Permian Panthalassa seawater had a more striking negative Ce anomaly due to a more oxidizing oceanic condition than today.  相似文献   

Comparative assessment of Japan's long-term carbon budget under different effort-sharing principles     

Takeshi Kuramochi  Jusen Asuka  Hanna Fekete  Kentaro Tamura  Niklas Höhne 《Climate Policy》2016,16(8):1029-1047

This article assesses Japan's carbon budgets up to 2100 in the global efforts to achieve the 2?°C target under different effort-sharing approaches based on long-term GHG mitigation scenarios published in 13 studies. The article also presents exemplary emission trajectories for Japan to stay within the calculated budget.

The literature data allow for an in-depth analysis of four effort-sharing categories. For a 450?ppm CO₂e stabilization level, the remaining carbon budgets for 2014–2100 were negative for the effort-sharing category that emphasizes historical responsibility and capability. For the other three, including the reference ‘Cost-effectiveness’ category, which showed the highest budget range among all categories, the calculated remaining budgets (20th and 80th percentile ranges) would run out in 21–29 years if the current emission levels were to continue. A 550?ppm CO₂e stabilization level increases the budgets by 6–17 years-equivalent of the current emissions, depending on the effort-sharing category. Exemplary emissions trajectories staying within the calculated budgets were also analysed for ‘Equality’, ‘Staged’ and ‘Cost-effectiveness’ categories. For a 450?ppm CO₂e stabilization level, Japan's GHG emissions would need to phase out sometime between 2045 and 2080, and the emission reductions in 2030 would be at least 16–29% below 1990 levels even for the most lenient ‘Cost-effectiveness’ category, and 29–36% for the ‘Equality’ category. The start year for accelerated emissions reductions and the emissions convergence level in the long term have major impact on the emissions reduction rates that need to be achieved, particularly in the case of smaller budgets.

Policy relevance

In previous climate mitigation target formulation processes for 2020 and 2030 in Japan, neither equity principles nor long-term management of cumulative GHG emissions was at the centre of discussion. This article quantitatively assesses how much more GHGs Japan can emit by 2100 to achieve the 2?°C target in light of different effort-sharing approaches, and how Japan's GHG emissions can be managed up to 2100. The long-term implications of recent energy policy developments following the Fukushima nuclear disaster for the calculated carbon budgets are also discussed.  相似文献   

Internal Microanatomy and Zoological Affinity of the Early Cambrian Olivooides     

HAN Jian  LI Guoxiang  Kubota Shin  Ou Qiang  Toshino Sho  Wang Xing  Yang Xiaoguang  Uesugi Kentaro  Masato Hoshino  Sasaki Osamu  Kano Harumas  Sato Tomohiko  Komiya Tsuyoshi 《《地质学报》英文版》2016,90(1):38-65

The early Cambrian pentamerous microfossil Olivooides/Punctatus in South China, which is characterized by a diagnostic stellate tubular apex, has been well-known for its almost complete development sequence that can be confidently traced from embryos and hatched juveniles, to conical adults. However, its zoological affinity remains highly controversial. Here we describe the internal microanatomic structures of the soft-body inside the peridermal theca of Olivooides multisulcatus Qian, 1977, including interradial pairs of tentacles, adradial and perradial frenula, perradial oral marginal lappets and twins of perradial gastric saccule-like humps as well as a circular velarium with striated coronal muscles. Particularly, one specimen shows bifurcated velarial canals along the bell aperture. Both the components of the soft-body and the external theca (or cyst) are arranged in perfect pentaradial symmetry. These characteristics are more compatible with those of living cubomedusans and co-occurring Cambrian athecate embryonic cubozoans. Concerning the presence of peridermal theca, Olivooides most likely represents an extinct thecate stem-group cubomedusae but devoid of both perradial eyes and specialized pedalia. The well-grown soft body inside the peridermal tube displays a set of mixed features of both polyp and medusa.  相似文献   

Dynamical downscaling of future sea level change in the western North Pacific using ROMS     

Zhao-Jun?LiuEmail authorView author&#;s OrcID profile  Shoshiro?Minobe  Yoshi?N.?Sasaki  Mio?Terada 《Journal of Oceanography》2016,72(6):905-922

The future regional sea level (RSL) rise in the western North Pacific is investigated by dynamical downscaling with the Regional Ocean Modeling System (ROMS) with an eddy-permitting resolution based on three global climate models—MIROC-ESM, CSIRO-Mk3.6.0, and GFDL-CM3—under the highest greenhouse-gas emission scenario. The historical run is forced by the air-sea fluxes calculated from Coordinated Ocean Reference Experiment version 2 (COREv2) data. Three future runs—ROMS-MIROC, ROMS-CSIRO, and ROMS-GFDL—are forced with an atmospheric field constructed by adding the difference between the climate model parameters for the twenty-first and twentieth century to fields in the historical run. In all downscaling, the RSL rise along the eastern coast of Japan is generally half or less of the RSL rise maxima off the eastern coast. The projected regional (total) sea level rises along the Honshu coast during 2081–2100 relative to 1981–2000 are 19–25 (98–104), 6–15 (71–80), and 8–14 (80–86) cm in ROMS-MIROC, ROMS-CSIRO, and ROMS-GFDL, respectively. The discrepancies of the RSL rise along the Honshu coast between the climate models and downscaling are less than 10 cm. The RSL changes in the Kuroshio Extension (KE) region in all downscaling simulations are related to the changes of KE (northward shift or intensification) with climate change.  相似文献   

Stability of richterite₅₀-tremolite₅₀ solid solution at high pressures and possible presence of sodium calcic amphibole under upper mantle conditions     

Yu Hariya  Shoichi Terada 《Earth and Planetary Science Letters》1973,18(1):72-76

High pressure experiments have been made on the stability of richterite₅₀-tremolite₅₀ solid solution by the piston-cylinder type high pressure apparatus in the pressure range from 15 to 40 kb, at temperatures from 700 to 1150°C. This amphibole is stable up to 40 kb at 700°C, and the breakdown pressure gradually decreases with increasing temperatures. It is suggested that this amphibole, on the basis of high pressure experiments, may occur in the upper mantle.  相似文献