Lateritization cycles and their relation to the formation and quality of kaolin deposits in south Kerala, India     

K. Soman  A.D. Slukin 《Chemical Geology》1987,60(1-4):273-280

Laterite occurs extensively over the crystalline and sedimentary rocks in the midland and lowland areas of south Kerala, India. Two lateritization cycles are identified in this area. Large, good-quality kaolin deposits, composed mostly of kaolinite, are characteristic of the sedimentary sequence in south Kerala. These deposits were formed on deposition of the weathering materials of the khondalites towards the first cycle of lateritization. After deposition and uplift of the sedimentary rocks, another lateritization cycle affected these, as well as the khondalites during pre-Quaternary times with the formation of a planation surface at 25–125 m above sea level having thick laterite profiles. The laterite profiles over the kaolin deposits show higher concentration of Fe-oxides (mostly in the form of hematite) and titania, compared to their concentration in the kaolins. Higher contents of Cr and Ni are also characteristic of the laterite over kaolin deposits. Recrystallization of the kaolinite, appearance of Al, Fe and Si amorphous phases in the kaolin clays and partial removal of Fe and Ti from them are attributed to the second lateritization cycle.  相似文献   

An anomalous cooling event observed in the Bay of Bengal during June 2009     

Neethu Chacko  Muthalagu Ravichandran  Rokkam R. Rao  Sadananda Satheesh Chandra Shenoi 《Ocean Dynamics》2012,62(5):671-681

Sea surface temperature (SST) variability over the Bay of Bengal (BoB) has the potential to trigger deep moist convection thereby affecting the active-break cycle of the monsoons. Normally, during the summer monsoon season, SST over the BoB is observed to be greater than 28°C which is a pre-requisite for convection. During June 2009, satellite observations revealed an anomalous basin-wide cooling and the month is noted for reduced rainfall over the Indian subcontinent. In this study, we analyze the likely mechanisms of this cooling event using both satellite and moored buoy observations. Observations showed deepened mixed layer, stronger surface currents, and enhanced heat loss at the surface in the BoB. Mixed layer heat balance analysis is carried out to resolve the relative importance of various processes involved. We show that the cooling event is primarily induced by the heat losses at the surface resulting from the strong wind anomalies, and advection and vertical entrainment playing secondary roles.  相似文献   

Occurrence of well-crystallized nontronite in the gas vesicles of a megaporphyritic basalt flow near Nighoj, Ahmednagar district, Maharashtra     

P. K. Sarkar  D. V. Upasani  A. C. Soman 《Journal of the Geological Society of India》2013,82(4):363-367

Occurrence of well crystallized nontronite in a megaporphyritic basalt flow from Nighoj area, Maharashtra, India is reported. Thin section studies of the vesicles from periphery to the centre reveal the presence of greenish palagonite, probably indicating the stages of devitrification of glass and the weathering of palagonite to the formation of nontronite. The centre of the vesicles is marked by the presence of dark greenish-brown, radiating and fibrous sheets of nontronite. X-ray diffraction (XRD) analysis reveals the dominant presence of smectite (nontronite) as the major phase with traces of pyroxene. Scanning Electron Microscopy (SEM) shows well developed sheets of nontronite within the gas vesicles of the megaporphyritic basalt flows. In the present investigation, the nontronite within the gas vesicles of the megaporphyritic basalts at Nighoj was formed in-situ due to the devitrification of glass containing palagonite. Palagonite is an intermediate step in the alteration that may be accomplished by the steam generated in quenching of the lava. Weathering of palagonite under conditions of poor drainage is essential to the genesis of nontronite as has been suggested by Victor and Vernon (1946).  相似文献   

Theoretical calculation of oxygen isotope fractionation factors in carbonate systems     

Thomas Chacko  Peter Deines 《Geochimica et cosmochimica acta》2008,72(15):3642-3660

Using established methods of statistical mechanical calculation and a recent compilation of vibrational frequency data, we have computed oxygen isotope reduced partition function ratios (β values) for a large number of carbonate minerals. The oxygen isotope β values of carbonates are inversely correlated to both the mass and radius of the cation bonded to the carbonate anion but neither correlation is good enough to be used as a precise and accurate predictor of β values. There is an approximately 0.6% relative increase in the β values of aragonite per 10 kbar increase in pressure. These estimates of the pressure effect on β values are broadly similar to those deduced previously for calcite using the methods of mineral physics. In comparing the β values of our study with those derived recently from first-principles lattice dynamics calculations, we find near-perfect agreement for calcite and witherite (<0.3% deviation), reasonable agreement for dolomite (<0.9% deviation) and somewhat poorer agreement for aragonite and magnesite (1.5-2% deviation). In the system for which we have the most robust constraints, CO₂-calcite, there is excellent agreement between our calculations and experimental data over a broad range of temperatures (0-900 °C). Similarly, there is good to excellent correspondence between calculation and experiment for most other low to moderate atomic mass carbonate minerals (aragonite to strontianite). The agreement is not as good for high atomic mass carbonates (witherite, cerussite, otavite). In the case of witherite and cerussite, the discrepancy may be due, in part, to our calculation methodology, which does not account for the effect of cation mass on the magnitude of vibrational frequency shifts associated with heavy isotope substitution. However, the calculations also reveal an incompatibility between the high- and low-temperature experimental datasets for witherite and cerussite. Specifically, the shapes of fractionation factor versus 1/T² curves in the calcite-witherite and calcite-cerussite systems do not conform to the robust constraints on the basic shape of these curves provided by theory. This suggests that either the high- or low-temperature datasets for both minerals is in error. Dolomite-calcite fractionation factors derived from our calculations fall within the wide range of fractionations for this system given by previous experimental and natural sample studies. However, our compilation of available low-temperature (25-80 °C) experimental data reveal an unusual temperature dependence of fractionations in this system; namely, the data indicate an increase in the magnitude of fractionations between dolomite (or proto-dolomite) and calcite with increasing temperature. Such a trend is incompatible with theory, which stipulates that fractionations between carbonate minerals must decrease monotonically with increasing temperature. We propose that the anomalous temperature dependence seen in the low-temperature experimental data reflect changes in the crystallinity and degree of cation ordering of the dolomite phase over this temperature interval and the effect these changes have on the vibrational frequencies of dolomite. Similar effects may be present in natural systems at low-temperature and must be considered in applying experimental or theoretical fractionation data to these systems. In nearly all cases, carbonate mineral-calcite fractionation factors given by the present calculations are in as good or better agreement with experimental data than are fractionations derived from semi-empirical bond strength methods.  相似文献   

1891–1883 Ma Southern Bastar–Cuddapah mafic igneous events, India: A newly recognized large igneous province     

Jason E. French  Larry M. Heaman  Thomas Chacko  Rajesh K. Srivastava 《Precambrian Research》2008,160(3-4):308-322

A newly recognized remnant of a Paleoproterozoic Large Igneous Province has been identified in the southern Bastar craton and nearby Cuddapah basin from the adjacent Dharwar craton, India. High precision U–Pb dates of 1891.1 ± 0.9 Ma (baddeleyite) and 1883.0 ± 1.4 Ma (baddeleyite and zircon) for two SE-trending mafic dykes from the BD2 dyke swarm, southern Bastar craton, and 1885.4 ± 3.1 Ma (baddeleyite) for a mafic sill from the Cuddapah basin, indicate the existence of 1891–1883 Ma mafic magmatism that spans an area of at least 90,000 km² in the south Indian shield.This record of 1.9 Ga mafic/ultramafic magmatism associated with concomitant intracontinental rifting and basin development preserved along much of the south-eastern margin of the south Indian shield is a widespread geologic phenomenon on Earth. Similar periods of intraplate mafic/ultramafic magmatism occur along the margin of the Superior craton in North America (1.88 Ga Molson large igneous province) and in southern Africa along the northern margin of the Kaapvaal craton (1.88–1.87 Ga dolerite sills intruding the Waterberg Group). Existing paleomagnetic data for the Molson and Waterberg 1.88 Ga large igneous provinces indicate that the Superior and Kalahari cratons were at similar paleolatitudes at 1.88 Ga but a paleocontinental reconstruction at this time involving these cratons is impeded by the lack of a robust geological pin such as a Limpopo-like 2.0 Ga deformation zone in the Superior Province. The widespread occurrence of 1.88 Ga intraplate and plate margin mafic magmatism and basin development in numerous Archean cratons worldwide likely reflects a period of global-scale mantle upwelling or enhanced mantle plume activity at this time.  相似文献   

Variability of Total Suspended Matter in the Northern Coastal Bay of Bengal as Observed from Satellite Data     

Neethu Chacko  Chiranjivi Jayaram 《Journal of the Indian Society of Remote Sensing》2017,45(6):1077-1083

The coastal regions of northern Bay of Bengal (BoB) are one of the most turbid areas owing to the large freshwater discharge from the three major river systems. This study is conducted to investigate the seasonal and interannual variability of total suspended matter (TSM) in the northern BoB. TSM concentration derived from medium resolution imaging spectrometer for the period 2002–2011 is used for this study. TSM concentration is observed to be the highest during summer monsoon season along the north-eastern region, off the Ganges–Brahmaputra river mouth. The variability of the TSM concentration depicts the role of river runoff associated with the summer monsoon in influencing the same. It is observed that the sediment concentration tapers away towards the offshore regions with the maximum extent observed up to 21.5°N latitude. Interannual variability is also observed with highest TSM concentrations occurring in the years 2003, 2008 and 2011 and least during 2004. Time series analysis performed at three major river discharge regions illustrated the distinct and highly variable nature of TSM dynamics prevailing in the northern BoB.  相似文献   

Animating Place: Exploring Encounters in the Diverse City          下载免费PDF全文

Elizabeth Chacko  Michele Lobo  Adeline Tay 《Geographical review》2016,106(2):157-162

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Evaluation of SARAL / AltiKa Measured Significant Wave Height and Wind Speed in the Indian Ocean Region     

Chiranjivi Jayaram  Saurabh Bansal  A. Sai Krishnaveni  Neethu Chacko  V. M. Chowdary  D. Dutta  K. H. Rao  C. B. S. Dutt  J. R. Sharma  V. K. Dadhwal 《Journal of the Indian Society of Remote Sensing》2016,44(2):225-231

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Quantitative precipitation forecasting over Narmada Catchment     

K Krishna Kumar  M K Soman 《Journal of Earth System Science》1993,102(2):313-328

Quantitative precipitation forecasting (QPF) has been attempted over the Narmada Catchment following a statistical approach. The catchment has been divided into five sub-regions for the development of QPF models with a maximum lead-time of 24 hours. For this purpose the data of daily rainfall from 56 raingauge stations, twice daily observations on different surface meteorological parameters from 28 meteorological observatories and upper air data from 11 aerological stations for the nine monsoon seasons of 1972–1980 have been utilized. The horizontal divergence, relative vorticity, vertical velocity and moisture divergence are computed using the kinematic method at different pressure levels and used as independent variables along with the rainfall and surface meteorological parameters. Multiple linear regression equations have been developed using the stepwise procedure separately with actual and square root and log-transformed rainfall using 8-year data (1972–1979). When these equations were verified with an independent data for the monsoon season of 1980, it was found that the transformed rainfall equations fared much better compared to the actual rainfall equations. The performance of the forecasts of QPF model compared to the climatological and persistence forecasts has been assessed by computing the verification scores using the forecasts for the monsoon season of 1980.  相似文献   

Distribution of global and net radiation over the Indian Ocean and its environments     

Dir. Anna Mani  O. Chacko  V. Krishnamurthy  V. Desikan 《Theoretical and Applied Climatology》1967,15(1-2):82-98

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