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M. A. Amani A. M. Latifi K. Tahvildari R. Karimian 《International Journal of Environmental Science and Technology》2018,15(6):1301-1312
In this research, ordered mesoporous silica, including MCM-41, was synthesized via sol–gel process and a propyl methacrylate-modified ordered mesoporous silica (MPS-MCM-41) was successfully synthesized via a postsynthesis grafting process. Then both MCM-41 and MPS-MCM-41 were characterized using FTIR, XRD, SEM and BET techniques. The synthesized materials were utilized as adsorbent for removal of diazinon pesticide from aqueous solutions. The effects of pH, contact time, adsorbent dose, initial concentration and temperature have been evaluated using removal efficiencies. Also, the kinetic, thermodynamic and isotherm models of diazinon adsorption were studied for the both MCM-41 and MPS-MCM-41. The results showed that the maximum adsorption capacities are 142 and 254 mg g?1 for the MCM-41 and MPS-MCM-41, respectively, at the initial concentration of 50 mg L?1, temperature of 298 K and adsorbent dose of 0.1 g L?1. The highest percentages of diazinon removal are 56.4 and 87.2 (at adsorbent dose of 2 g L?1 and the temperature of 318 K) for the MCM-41 and MPS-MCM-41, respectively. The Freundlich and Langmuir models are more compatible for describing equilibrium data of the diazinon adsorption capacity on the MCM-41 and MPS-MCM-41, respectively. Thermodynamic study indicated that the adsorption process of diazinon onto MCM-41 and MPS-MCM-41 is exothermic and has a spontaneous nature. The higher adsorption capacity and higher spontaneous nature of MPS-MCM-41 in comparison with MCM-41 might be due to the presence of the both hydrogen bonding and hydrophobic interaction between surface functional groups of MPS-MCM-41 (hydroxyl and propyl methacrylate) and diazinon functional groups. 相似文献
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ABSTRACT The Early Cretaceous was an important epoch in the evolution of the Earth system in which major tectonic episodes occurred, especially along the Alpine–Himalayan belt. The paucity of reliable palaeogeographic data from the central segment of this geological puzzle, however, hampers the reconstruction of a panoramic view of its Early Cretaceous palaeogeography and geodynamic setting. Here we present multidisciplinary provenance data from Lower Cretaceous strata of the overriding plate of the Neo-Tethyan subduction zone (the Sanandaj–Sirjan Zone; SSZ, of central Iran), including structural, basin-fill evolution, petrographic and geochemical analyses. Sandstone provenance analysis of Lower Cretaceous red beds suggests the occurrence of sub-mature litho-quartzose sandstones attributed to an active continental arc margin in convergent setting predominantly derived from plutonic, quartzose sedimentary and metamorphic rocks exposed in the central SSZ. Weathering indices indicate moderate chemical weathering in the source area which may be related to close source-to-sink relationships or arid climate. Our palaeogeographic reconstructions and original geological mapping indicate that the erosion of uplifted basement rocks exposed in horst blocks provided the sediment sources for the syn-extensional deposition of uppermost Jurassic–lowermost Cretaceous conglomerates and Lower Cretaceous siliciclastic red beds within a continental retro-arc basin during initiation of the ‘Neo-Tethys 2?. The polyphase tectonic reactivation along the principal fault of the study area controlled the syn- and post-extensional tectonostratigraphic evolution that reflect the corresponding mechanical decoupling/coupling along the northern Neo-Tethyan plate margin. 相似文献
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This paper assesses the various factors contributing to climate change in the region of the Kashafroud G-WADI Basin in Iran; quantifies
the local impacts of climate change, especially local water scarcity; and simulates and discusses several proposed methods to
combat these impacts. Hydrologic and climatic data are statistically analyzed and VENSIM modeling is used for various simulations
of water resources in the basin. Results show that the natural climate changes affecting Kashafroud Basin include increased temperature,
less rainfall, more frequent droughts, and changes in rainfall patterns, all of which are local symptoms of climate change in recent
years. However, the most important challenge in the basin is the overexploitation of surface and groundwater resources to meet the
growing water demands, especially domestic needs. Changes in land use, reallocation of water uses, groundwater depletion, and degradation
of the quality of surface waters have all contributed to significant changes in the environmental features of this basin, and are
the main reason why water demands now exceed the renewal capacity of the basin. Proposed response measures include reallocation
of resources among different uses, inter-basin water transfers, drawing water from six small dams on the Kashafroud River, reducing
groundwater extraction, and replacing groundwater extraction for agriculture by reuse of urban wastewater. This study concludes that
although changes in global climatic parameters have altered environmental features in the basin, local factors, such as water utilization
beyond the renewable capacity of the basin, are more significant in worsening the impacts of climate change. 相似文献
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Abstract Statistical analysis of extremes is often used for predicting the higher return-period events. In this paper, the trimmed L-moments with one smallest value trimmed—TL-moments (1,0)—are introduced as an alternative way to estimate floods for high return periods. The TL-moments (1,0) have an ability to reduce the undesirable influence that a small value in the statistical sample might have on a large return period. The main objective of this study is to derive the TL-moments (1,0) for the generalized Pareto (GPA) distribution. The performance of the TL-moments (1,0) was compared with L-moments through Monte Carlo simulation based on the streamflow data of northern Peninsular Malaysia. The result shows that, for some cases, the use of TL-moments (1,0) is a better option as compared to L-moments in modelling those series. Citation Ahmad, U.N., Shabri, A. & Zakaria, Z.A. (2011) Trimmed L-moments (1,0) for the generalized Pareto distribution. Hydrol.Sci. J. 56(6), 1053–1060. 相似文献
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Mojtaba Pakparvar Hossein Hashemi Meisam Rezaei Wim M. Cornelis Gholamali Nekooeian Sayyed Ahang Kowsar 《水文科学杂志》2018,63(8):1183-1202
To assess recharge through floodwater spreading, three wells, approx. 30 m deep, were dug in a 35-year-old basin in southern Iran. Hydraulic parameters of the layers were measured. One well was equipped with pre-calibrated time domain reflectometry (TDR) sensors. The soil moisture was measured continuously before and after events. Rainfall, ponding depth and the duration of the flooding events were also measured. Recharge was assessed by the soil water balance method, and by calibrated (inverse solution) HYDRUS-1D. The results show that the 15 wetting front was interrupted at a layer with fine soil accumulation over a coarse layer at the depth of approx. 4 m. This seemed to occur due to fingering flow. Estimation of recharge by the soil water balance and modelling approaches showed a downward water flux of 55 and 57% of impounded floodwater, respectively. 相似文献
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Spatial changes of Extended De Martonne climatic zones affected by climate change in Iran 总被引：1，自引：1，他引：0
Jaber Rahimi Meisam Ebrahimpour Ali Khalili 《Theoretical and Applied Climatology》2013,112(3-4):409-418
In order to better understand the effect associated with global climate change on Iran’s climate condition, it is important to quantify possible shifts in different climatic types in the future. To this end, monthly mean minimum and maximum temperature, and precipitation from 181 synoptic meteorological stations (average 1970–2005) have been collected from the meteorological organization of Iran. In this paper, to study spatial changes of Iran’s climatic zones affected by climate changes, Extended De Martonne’s classification (originally formulated by De Martonne and extended by Khalili (1992)) was used. Climate change scenarios were simulated in two future climates (average conditions during the 2050s and the 2080s) under each of the SRES A1B and A2, for the CSIRO-MK3, HadCM3, and CGCM3 climate models. Coarse outputs of GCMs were downscaled by delta method. We produced all maps for three time periods (one for the current and two for the future) according to Extended De Martonne’s classification. Finally, for each climatic zone, changes between the current and the future were compared. As the main result, simulated changes indicate shifts to warmer and drier zones. For example, in the current, extra arid-cold (A1.1m2) climate is covering the largest area of the country (21.4 %), whereas in both A1B and A2 scenarios in the 2050s and the 2080s, extra arid-moderate (A1.1m3) and extra arid-warm (A1.1m4) will be the climate and will occupy the largest area of the country, about 21 and 38 %, respectively. This analysis suggests that the global climate change will have a profound effect on the future distribution of severe aridity in Iran. 相似文献
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An approach based on regional frequency analysis using L moments and LH moments are revisited in this study. Subsequently, an alternative regional frequency analysis using the partial L moments (PL moments) method is employed, and a new relationship for homogeneity analysis is developed. The results were then compared with those obtained using the method of L moments and LH moments of order two. The Selangor catchment, consisting of 37 sites and located on the west coast of Peninsular Malaysia, is chosen as a case study. PL moments for the generalized extreme value (GEV), generalized logistic (GLO), and generalized Pareto distributions were derived and used to develop the regional frequency analysis procedure. PL moment ratio diagram and Z test were employed in determining the best-fit distribution. Comparison between the three approaches showed that GLO and GEV distributions were identified as the suitable distributions for representing the statistical properties of extreme rainfall in Selangor. Monte Carlo simulation used for performance evaluation shows that the method of PL moments would outperform L and LH moments methods for estimation of large return period events. 相似文献
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In this paper, we investigate Bianchi type-VI cosmological model for the universe filled with dark energy and viscous fluid in the presence of cosmological constant. Also, we show accelerating expansion of the universe by drawing volume scale, pressure and energy density versus cosmic time. In order to solve the Einstein’s field equations, we assume the expansion scalar is proportional to a component of the shear tensor. Therefore, we obtain the directional scale factors and show the EOS parameter crosses over phantom divided-line. 相似文献