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In the analysis of water quality by remote sensing, it is widely reported, that, several parameters of water quality are correlated with the reflectances and the ratios of reflectances of the water body in different spectral bands. In this paper, it is shown empirically, that, the pairwise product of the reflectances in different bands is better correlated than the bands and their ratios. A possible explanation for this pnenomenon is also suggested.  相似文献   
2.
The present work reports studies on the spatial distribution of tropospheric ozone extending over both southern and northern hemispheres. This study is based on a univariate approach to the spatial data series obtained at regular spatial intervals. Mann?CKendall's (MK) trend analysis has been carried out to discern the trend within the spatial distribution of the tropospheric ozone, and it has been observed that in all seasons, except monsoon (JJAS), there is a linear trend within the spatial distribution. Studying both monthly and seasonal behavior through autoregressive integrated moving average (ARIMA), it has been revealed that ARIMA (0,2,2) can be used as a representative of the spatially distributed tropospheric ozone over southern and northern hemispheres. The representative model has been confirmed through the study of Willmott's index and prediction yield.  相似文献   
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Accessibility Futures   总被引:1,自引:0,他引:1  
This study uses accessibility as a performance measure to evaluate a matrix of future land use and network scenarios for planning purposes. The concept of accessibility dates to the 1950s, but this type of application to transportation planning is new. Previous research has established the coevolution of transportation and land use, demonstrated the dependence of accessibility on both, and made the case for the use of accessibility measures as a planning tool. This study builds off of these findings by demonstrating the use of accessibility‐based performance measures in the Twin Cities Metropolitan Area. This choice of performance measure also allows for transit and highway networks to be compared side‐by‐side. For roadway modeling, zone‐to‐zone travel time matrix was computed using stochastic user equilibrium (SUE) assignment with travel time feedback to trip distribution. A database of schedules was used on the transit networks to assign transit routes. This travel time data was joined with the land use data from each scenario to obtain the employment, population, and labor accessibility from each traffic analysis zone (TAZ) within specified time ranges. Tables of person‐weighted accessibility were computed for 20 minutes with zone population as the weight for employment accessibility and zone employment as the weight for population and labor accessibility. Maps of accessibility by zone were produced to show the spatial distribution of accessibility across the region. The results show that a scenario where population and employment growth are concentrated in the center of the metropolitan area would produce the highest accessibility no matter which transportation network changes are made. However, another scenario which concentrates population growth in the center of the metropolitan area and shifts employment growth to the periphery consistently outperforms the scenario representing the projected 2030 land use without any growth management strategy.  相似文献   
4.
Detrital mode, composition of feldspars and heavy minerals, and major element chemistry of sandstones from the Permo-Triassic succession in the intracratonic Satpura Gondwana basin, central India have been used to investigate provenance. The Talchir Formation, the lowermost unit of the succession, comprises glacio-marine and glacio-fluvial deposits. The rest of the succession (base to top) comprising the Barakar, Motur, Bijori, Pachmarhi and Denwa formations, largely represent variety of fluvial depositional systems with minor fluvio-deltaic and fluvio-lacustrine sedimentation under a variety of climatic conditions including cold, warm, arid, sub-humid and semi-arid. QFL compositions of the sandstones indicate a predominantly continental block provenance and stable cratonic to fault-bounded basement uplift tectonic setting. Compositional maturity of sandstones gradually increases upwards from the Early Permian Talchir to the Middle Triassic Denwa but is punctuated by a sharp peak of increased maturity in the Barakar sandstones. This temporal change in maturity was primarily controlled by temporal variation in fault-induced basement uplift in the craton and was also influenced by climatic factors. Plots of different quartz types suggest plutonic source rocks for the Talchir sandstones and medium-to high-rank metamorphic plus plutonic source rocks for the younger sandstones. Composition of alkali feldspars in the Permo-Triassic sandstones and in different Precambrian rocks suggests sediment derivation from felsic igneous and metasedimentary rocks. Compositions of plagioclase in the Talchir and Bijori sandstones are comparable with those of granite, acid volcanic and metasedimentary rocks of the Precambrian basement suggesting the latter as possible source. Rare presence of high-K plagioclase in the Talchir sandstones, however, indicates minor contribution from volcanic source rock. Exclusively plagioclase-bearing metasedimentary rock, tonalite gneiss and mafic rocks are the probable sources of plagioclase in the Upper Denwa sandstones. Quartz-rich nature of the sandstones, predominance of K-feldspar over plagioclase and albite rich character of plagioclase in the sandstones is consistent with deposition in an intracratonic, pull-apart basin like the Satpura Gondwana basin. Composition of garnet and its comparison with that from the Precambrian basement rocks suggests mica-schist and amphibolite as possible sources. Predominance of dravite variety of tourmaline in the Permian sandstones suggests sediment supply from metasedimentary rocks. Presence of both dravite and schorl variety of tourmaline in subequal amount in the Triassic sandstones indicates sediment derivation from granitic and metasedimentary rocks. However, schorl-bearing rocks are absent in the basement complex of the study area. A-CN-K plot suggests granites, acid volcanic rock and meta-sediments of the basement as possible sources of the Talchir sandstones and metasedimentary rocks for the Barakar to Pachmarhi sandstones. The Denwa sandstones were possibly derived from K-feldspar-free, plagioclase-bearing metasediments, mafic rocks and tonalite gneiss. Chemical Index of Alteration (CIA) values suggest low intensity source rock weathering for the Talchir sandstones and higher intensity source rock weathering for the others. Various bivariate plots of major oxides composition of the sandstones suggest passive to active continental margin setting and even arc tectonic setting for a few samples.  相似文献   
5.
Two independent analytical methods (sequential extraction and kinetic extraction methods) were applied in order to understand the distribution and speciation of La in the coastal and estuarine sediments from the central east coast of India. Sequential extraction study revealed that La was primarily present as inert complexes (~ 50–60% of the total La) in all the sediments. Amounts of ~ 20–30% of the total La in all the sediments were found to associate with the total organic carbon (TOC) in the sediments. The dissociation rate constants of La–sediment complexes obtained from kinetic extraction studies revealed that the concentration of thermodynamically weak complexes of La gradually increased with the increasing La/TOC ratio in the sediments.  相似文献   
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7.
Interactions of mercury (Hg) with different molecular weight fractions of humic substances (HS) play an important role in controlling distribution, diffusion, speciation, and bioavailability of Hg in natural systems. This study suggests that Hg prefers to associate with higher molecular weight fractions of HS and this association particularly predominates at low pH and high ionic strengths of the medium. The concentrations of aggregated HS (with higher molecular weight) become high at lower pH (acidic condition) and high ionic strength. Molecular weight of HS gradually decreases with the increasing pH (basic condition) and low ionic strength of the medium. The disaggregation property of HS which involves the release of monomers from the surface of the aggregates produces HSs of different intermediate molecular weight with different Hg complexing capacity. Distribution of Hg in different molecular weight fractions of HS is dependent on aggregational and disaggregational properties of HS in aquatic medium. Association of Hg with high molecular weight fraction of HS may alter distribution and bioavailability of Hg in a system as the bioreactivity of organic matter decrease along a continuum of size in aquatic medium.  相似文献   
8.
Free metal ion concentration is generally considered a useful indicator of a metal’s bioavailability and ecotoxicity to aquatic biota. This article reports the speciation of nickel in mining and municipal effluents from Sudbury (Ontario, Canada), and also in model solutions containing a fully characterized laurentian fulvic acid (LFA) at environmentally relevant concentrations. A column ion exchange technique (IET) using a cation exchange resin (Dowex 50W-X8) was applied to determine free nickel ion concentrations. In model solutions, reasonable correlation was found between the predictions of an equilibrium-based computer speciation code, Windermere Humic Aqueous Model (WHAM) VI, and the results obtained by IET at low nickel-to-fulvic acid ratios. However at higher mole ratios, the WHAM VI predicted higher free nickel ion concentrations than IET. Only three out of six effluent samples showed reasonable agreement between the IET and the WHAM VI results, indicating the need for further development of IET for application to effluent waters.  相似文献   
9.
In the study reported in this paper we have dealt with the intrinsic complexity of the daily total ozone time series over Mumbai, India (19°23′N, 72 15°00′E) by means of detrended fluctuation analysis and phase portrait analysis. From the detrended fluctuation analysis of first order it is revealed that the said time series is characterized by persistent power-law correlation which is stronger in shorter time scale than in the longer time scale. The phase portrait analysis is based on a non-linear autonomous system generated from regression equations; infinitely many stable nodes are found along the straight line x = 273.556 and from the behaviors of the contours, it has been revealed that the daily total ozone concentration is unlikely to go beyond 315 DU (approximately) and it is almost stable.  相似文献   
10.
The present study deals with daily total ozone concentration time series over four metro cities of India namely Kolkata, Mumbai, Chennai, and New Delhi in the multivariate environment. Using the Kaiser–Meyer–Olkin measure, it is established that the data set under consideration are suitable for principal component analysis. Subsequently, by introducing rotated component matrix for the principal components, the predictors suitable for generating artificial neural network (ANN) for daily total ozone prediction are identified. The multicollinearity is removed in this way. Models of ANN in the form of multilayer perceptron trained through backpropagation learning are generated for all of the study zones, and the model outcomes are assessed statistically. Measuring various statistics like Pearson correlation coefficients, Willmott’s indices, percentage errors of prediction, and mean absolute errors, it is observed that for Mumbai and Kolkata the proposed ANN model generates very good predictions. The results are supported by the linearly distributed coordinates in the scatterplots.  相似文献   
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