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Granular soils subjected to seepage flow may suffer suffusion, ie, a selective internal erosion. Extending the classical approach of poromechanics, we deduce a new form of the Clausius-Duhem inequality accounting for dissipation due to suffusion, and we deduce restrictions on the constitutive laws of the soil. We suggest (a) a possible coupling between the seepage forces and the suffusion kinetics and (b) an extension of an existing elastoplastic model for the skeleton mechanical behaviour. Numerical integrations of the elastoplastic model are carried out under drained axisymmetric triaxial and oedometric conditions. As a result, we prove that the extended model is able to qualitatively reproduce the suffusion induced strains and the strength reduction experimentally observed. Predictions on the oedometric behaviour of suffusive soils are also provided.  相似文献   
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The sustainable management and profitable development of the Pacific island tuna fisheries is the key ocean governance challenge for the Pacific islands region in the short and medium term. Resolving these challenges is fundamental to the long term future of the region and its ability to implement oceans governance across all resource and conservation concerns.  相似文献   
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The storage capacity of a temperate mixed oak–beech stand was investigated as a function of stand density and species composition. Measurements were performed in selected zones delimited by three neighbouring trees. Three independent approaches were compared: (i) a spraying laboratory experiment to estimate the water storage on foliage before and after dripping; (ii) a mechanistic model describing rainfall partitioning within the forest canopy and providing estimates of foliage storage capacities; and (iii) linear regression analyses to evaluate the canopy (foliage + branches) storage capacity using the relationship between throughfall and rainfall. Good agreement was generally observed between the laboratory experiment and the mechanistic model estimates, while estimations from the regression method tended to exceed those from the other approaches. Storage capacity estimates ranged from 0·22 mm to 0·80 mm for pure oak zones, from 0·24 mm to 1·12 mm for mixed zones and from 0·53 mm to 1·17 mm for pure beech zones. The increase of storage capacity with increasing proportion of beech in the canopy resulted from higher beech LAI compared with oak. Similarly, for mixed and pure beech canopies, storage capacity was higher for high density zones than for low density zones as a result of the increase in LAI with increasing local basal area; in contrast, for pure oak, the storage capacity was not related to basal area because of the lower shade‐tolerance of this species compared with beech. Copyright © 2008 John Wiley & Sons, Ltd.  相似文献   
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Zircon is a key mineral in geochemical and geochronological studies in a range of geological settings as it is mechanically and chemically robust. However, distortion of its crystal lattice can facilitate enhanced diffusion of key elements such as U and Pb. Electron backscatter diffraction (EBSD) analysis of ninety-nine zircons from the Lewisian Gneiss Complex (LGC) of northwest Scotland has revealed five zircons with lattice distortion. The distortion can take the form of gradual bending of the lattice or division of the crystal into subgrains. Zircon lattices are distorted because of either post-crystallisation plastic distortion or growth defects. Three of the five distorted zircons, along with many of the undistorted zircons in the population, were analysed by ion microprobe to measure U and Pb isotopes, Ti and REEs. Comparison of Th/U ratio, 207Pb/206Pb age, REE profile and Ti concentration between zircons with and without lattice distortion suggests that the distortion is variably affecting the concentration of these trace elements and isotopes within single crystals, within samples and between localities. REE patterns vary heterogeneously, sometimes relatively depleted in heavy REEs or lacking a Eu anomaly. Ti-in-zircon thermometry records temperatures that were either low (~700 °C) or high (>900 °C) relative to undistorted zircons. One distorted zircon records apparent 207Pb/206Pb isotopic ages (?3.0 to +0.3 % discordance) in the range of ~2,420–2,450 Ma but this does not correlate with any previously dated tectonothermal event in the LGC. Two other distorted zircons give discordant ages of 2,331 ± 22 and 2,266 ± 40 Ma, defining a discordia lower intercept within error of a late amphibolite-facies tectonothermal event. This illustrates that Pb may be mobilised in distorted zircons at lower metamorphic grade than in undistorted zircons. These differences in trace element abundances and isotope systematics in distorted zircons relative to undistorted zircons are generally interpreted to have been facilitated by subgrain walls. Trace elements and isotopes would have moved from undistorted lattice into these subgrain walls as their chemical potential is modified due to the presence of the dislocations which make up the subgrain wall. Subgrain walls provided pathways for chemical exchange between crystal and surroundings. Only five per cent of zircons in this population have lattice distortion suggesting it will not have a major impact on zircon geochronology studies, particularly as three of the five distorted zircons are from strongly deformed rocks not normally sampled in such studies. However, this does suggest there may be a case for EBSD analysis of zircons prior to geochemical analysis when zircons from highly deformed rocks are to be investigated.  相似文献   
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Infrared absorption spectra of the high-pressure polymorphs β-Mg2SiO4 and β-Co2SiO4 have been measured between 0 and 27 GPa at room temperature. Grüneisen parameters determined for 11 modes of β-Mg2SiO4 (frequencies of 300 to 1,050 cm?1) and 5 modes of β-Co2SiO4 (490 to 1,050 cm?1) range between 0.8 and 1.9. Averaging the mid-infrared spectroscopic data for β-Mg2SiO4 yields an average Grüneisen parameter of 1.3 (±0.1), in good agreement with the high-temperature thermodynamic value of 1.35. Similarly, we find a value of 1.05 (±0.2) for the average spectroscopic Grüneisen parameter of β-Co2SiO4.  相似文献   
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We have obtained infrared and Raman spectra for garnets synthesized at high (static) pressures and temperatures along the join Mg3Al2Si3O12 (pyrope) — Mg4Si4O12 (magnesium majorite). The vibrational spectra of Mg-majorite show a large number of additional weak peaks compared with the spectra of cubic pyrope garnet, consistent with tetragonal symmetry for the MgSiO3 garnet phase. The Raman bands for this phase show no evidence for line broadening, suggesting that Mg and Si are ordered on octahedral sites in the garnet. The bands for the intermediate garnet compositions are significantly broadened compared with the end-members pyrope and Mg-majorite, indicating cation disorder in the intermediate phases. Solid state 27Al NMR spectroscopy for pyrope and two intermediate compositions show that Al is present only on octahedral sites, so the cation disorder is most likely confined to Mg-Al-Si mixing on the octahedral sites. We have also obtained a Raman spectrum for a natural, shock-produced (Fe,Mg) majorite garnet. The sharp Raman peaks suggest little or no cation disorder in this sample.  相似文献   
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