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Comparative Assessment of Sludge Pre‐Treatment Techniques to Enhance Sludge Dewaterability and Biogas Production 
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下载免费PDF全文 Didem Okutman Tas Cigdem Yangin‐Gomec Tugba Olmez‐Hanci Osman A. Arikan Deniz I. Cifci Elif B. Gencsoy Alpaslan Ekdal Emine Ubay‐Cokgor 《洁净——土壤、空气、水》2018,46(1)
Effectiveness of ultrasonication, microwave technologies, and enzyme addition prior to anaerobic digestion is investigated using sludge samples taken from the secondary settling tank of a domestic wastewater treatment plant to improve methane production, enhance dewaterability characteristics of the sludge, and to reduce excess sludge. Microwave pre‐treatment (1500 W, 10 min at 175 °C) results in better extra digester performance (compared to the control reactor) in terms of methane production (25 m3 ton?1 suspended solids (SS)) than ultrasound (no improvement) and enzyme pre‐treatment (11 m3 ton?1 SS). While methane production is not improved as a result of ultrasonication pre‐treatment (15 000 kJ kg?1 SS), a noticeable increase (19%) is observed in the case of microwave pre‐treatment. Higher compactibility values are obtained after ultrasonication and microwave application compared to the control (i.e., from 7.1 to 8.7 and 9.2%, respectively) before anaerobic digestion. Although ultrasonication and microwave application decrease the dewaterability of the raw sludge (capillary suction time (CST) from 827 to 1364 and 2290 s, respectively), similar dewaterability results are obtained at the end of the anaerobic digestion process for all pre‐treated sludge samples. An economic assessment of this study shows that pre‐treatment with microwave results in more than 10‐fold less net cost compared to the enzyme application. 相似文献
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Taner Ekici Musa Alpaslan Osman Parlak Abidin Temel 《Chemie der Erde / Geochemistry》2007,67(3):201-212
The study area is located on the middle sector of the Malatya-Ovacık Fault Zone (MOFZ) in the eastern Anatolia. Four basaltic flows from bottom to top, which are tholeiitic in character and intercalated with Pliocene sedimentary rocks, were erupted along this fault zone. Chemical compositions of these flows reveal some differences between the first flow and others in terms of high-field strength elements (HFSEs) (e.g. Ti, Zr, Nb). Limited variations in compositions within the first flow and upper flows suggest a limited fractionation range. Trace-element patterns exhibit that all the flows have similar and OIB-like patterns without positive peak at Pb and a trough at Nb—Ta, indicating minimal or no crustal contribution. Rare-earth element (REE) patterns indicate that the first flow has flat patterns with negative Eu anomaly, whereas the upper flows have variable enrichments in LREE and depletions in HREE. La/SmN, Dy/YbN and Zr/Y ratios exhibit that the degree of partial melting decreases from the first flow to upper flows. Higher values of La/YbN ratio for the upper flows and depletions at Y and Yb on the trace-element patterns suggest the presence of garnet as a residual phase, which imply that the depth of partial melting took place solely in the garnet-stability field. OIB-like trace-element patterns and trace-element ratios (e.g. La/Nb, Ce/Y and Zr/Nb) emphasize that the melts forming the Arguvan basalt were originated from the asthenospheric mantle rather than the lithospheric mantle. 相似文献
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Musa Alpaslan Taner Eki&#x;ci&#x; Nazmi&#x; Otlu Durmu Boztug Abi&#x;di&#x;n Temel 《Geological Journal》2005,40(2):193-214
The Miocene Karamağara volcanics (KMV) crop out in the Saraykent region (Yozgat) of Central Anatolia. The KMV include four principal magmatic components based on their petrography and compositional features: basaltic andesites (KMB); enclaves (KME); andesites (KMA); and dacites (KMD). Rounded and ellipsoidal enclaves occur in the andesites, ranging in diameter from a few millimetres to ten centimetres. A non‐cognate origin for the enclaves is suggested due to their mineralogical dissimilarity to the enclosing andesites. The enclaves range in composition from basaltic andesite to andesite. Major and trace element data and primitive mantle‐normalized rare‐earth element (REE) patterns of the KMV exhibit the effects of fractional crystallization on the evolution of the KME which are the product of mantle‐derived magma. The KMA contain a wide variety of phenocrysts, including plagioclase, clinopyroxene, orthopyroxene, hornblende and opaque minerals. Comparison of textures indicates that many of the hornblende phenocrysts within the KMA were derived from basaltic andesites (KMB) and are not primary crystallization products of the KMA. Evidence of disequilibrium in the hybrid andesite includes the presence of reacted hornblendes, clinopyroxene mantled by orthopyroxene and vice versa, and sieve‐texture and inclusion zones within plagioclase. The KMV exhibit a complex history, including fractional crystallization, magma mixing and mingling processes between mantle and crust‐derived melts. Textural and geochemical characteristics of the enclaves and their hosts require that mantle‐derived basic magma intruded the deep continental crust followed by fractional crystallization and generation of silicic melts from the continental material. Hybridization between basic and silicic melts subsequently occurred in a shallow magma chamber. Modelling of major element geochemistry suggests that the hybrid andesite represents a 62:38 mix of dacite and basaltic andesite. The implication of this process is that calc‐alkaline intermediate volcanic rocks in the Saraykent region represent hybrids resulting from mixing between basic magma derived from the mantle and silicic magma derived from the continental crust. Copyright © 2005 John Wiley & Sons, Ltd. 相似文献
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The Quaternary volcanic rocks from Gögova region constitute an example of on intra-continental volcanism in Southern Anatolia, Turkey. These rocks were erupted along the left-lateral strike-slip Yumurtalιk fault zone. They comprise basaltic lavas containing mafic enclaves. The enclaves are distributed widely through the lavas and are spherical to ellipsoidal in shape. Both the host lavas and the mafic enclaves have an alkaline character. Fractional crystallization process was important in the formation of the mafic enclaves where olivine was the main crystallizing phase. However, fractional crystallization was not a dominant process in the host lavas. Geochemical and petrological characteristics of both the mafic enclaves and the host lavas imply that magma mingling occurred during or immediately before eruption. 相似文献
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In this study, a total of 100 samples from 25 brands of carbonated natural mineral waters (CNMWs) produced in Turkey were analyzed for a total of 36 water quality constituents to determine their suitability for human consumption. Parameters examined include pH, electrical conductivity, ammonia, nitrate, nitrite, sulfate, sulfite, orthophosphate, chloride, fluoride, bicarbonate, and 25 major/trace elements analyzed by inductively coupled plasma‐mass spectrometry (ICP‐MS). The presence of these constituents in this type of water was investigated considering recent concerns about their quality and the lack of trace element information on the manufacturer labels. The analytical results obtained in this study were compared to the European Union (EU) norms, labeled values on bottles, as well as values from the literature. Results of this study have shown that Turkish CNMWs may contain high concentrations of sulfite, which is a known allergen, especially for chronic asthmatic population. CNMWs surveyed in this study have also appreciable amounts of fluoride (>1.5 mg L?1) that may have detrimental effects on health of children. The EU standards for As, Ba, Mn, and Ni were exceeded in seven CNMWs classified as “high mineral”. Compared to similar type of bottled waters from Europe and North America, CNMWs from Turkey generally contained higher elemental concentrations. 相似文献
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Deciphering factors controlling trace element distribution in the soils of Karaduvar industrial-agricultural area (Mersin,SE Turkey) 总被引：1，自引：0，他引：1
Cüneyt Güler Musa Alpaslan Mehmet Ali Kurt Abidin Temel 《Environmental Earth Sciences》2010,60(1):203-218
In this study, 30 topsoil samples were collected from Karaduvar area (Mersin, SE Turkey) where at present various industrial
and agricultural activities are occurring. Using a five-step ultrasound-assisted sequential extraction (UASE) procedure, trace
elements in soil samples were partitioned into the following: (1) soluble-exchangeable; (2) bound to carbonates; (3) bound
to Fe- and Mn-oxides; (4) bound to organic matter and sulfide compounds, and (5) residual fraction. Concentrations of 11 trace
elements in the extracts were determined using ICP-MS. Total concentrations ranged between (in mg kg−1) 3.35 and 7.26 for As; 1.18 and 3.96 for Cd; 10.76 and 20.26 for Co; 37.99 and 63.48 for Cr; 18.55 and 243.1 for Cu; 338.7
and 565.6 for Mn; 4.42 and 6.44 for Mo; 148 and 279.3 for Ni; 10.12 and 73.71 for Pb; 17.93 and 36.55 for V, and 25.46 and
331.7 for Zn. Factor analysis was applied to dataset in order to discriminate between natural and anthropogenic pollution
sources and factors controlling the spatial distribution of trace elements in the area. Results suggest that distributions
of Co, Cr, Mn, and Ni are mainly controlled by lithological factors, whereas, distributions of Cu, Pb, and Zn can be attributed
to agricultural activities such as pesticide/herbicide use and fertilizer application, as well as irrigation with petroleum
hydrocarbon-contaminated groundwater. Highest concentrations of Cd and Mo are generally observed around the diesel-fired thermal
power plant and ATAŞ refinery. Highest concentrations of As and V are generally observed at the NW sector of the area; however,
no definitive source can be designated for both of these elements. 相似文献
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The bulk mass of the intrusive rocks found in the surroundings of Ağören/East Anatolia is composed mainly of K-feldspar, quartz and plagioclase. Moreover the minerals biotite, muscovite and rarely amphiboles are present as minor components and apatite, zircon, chlorite, sericite, tourmaline as well as titanite are found as accessory components. The intrusives can be defined as granites and qaurtzmonzonites by plotting within the QAP diagram. They show a clearly prealuminous character (A/CNK ratio >1.1) and typical geochemical attributes of S-type granites.The distribution pattern of trace – and rare earth elements in various diagrams indicate that the initial magma was generated by collision processes and accompanyed crust thickening and consequently a partial melting of the underlying Akdağ metamorphics and Hinis metaophiolites. 相似文献