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High fluoride and arsenic concentrations in groundwater have led to serious health problems to local inhabitants at Yuncheng basin, Northern China. In this study, groundwater with high fluoride and arsenic concentration at Yuncheng basin was investigated. A majority of the samples (over 60%) belong to HCO3 type water. The predominant water type for the shallow groundwater collected from southern and eastern mountain areas was Ca/Mg-Ca-HCO3 types. For the shallow groundwater from flow through and discharge area it is Na-HCO3/SO4-Cl/SO4/Cl type. The predominant water type for the intermediate and deep groundwater is of Na/Ca/Mg-Ca-HCO3 type. According to our field investigation, fluoride concentration in groundwater ranges between 0.31 and 14.2 mg/L, and arsenic concentration ranges between 0.243 and 153.7 μg/L. Out of seventy collected groundwater samples, there are 31 samples that exceed the World Health Organization (WHO) standard of 1.5 mg/L for fluoride, and 15 samples exceeds the WHO standard of 10 μg/L for arsenic. Over 40% of high fluoride and arsenic groundwater are related to the Na-HCO3 type water, and the other fifty percent associated with Na-SO4-Cl/HCO3-SO4-Cl type water; little relation was found in calcium bicarbonate type water. A moderate positive correlation between fluoride and arsenic with pH were found in this study. It is due to the pH-dependent adsorption characteristics of F and As onto the oxide surfaces in the sediments. The observed negative correlation between fluoride and calcium could stem from the dissolution equilibrium of fluorite. The high concentration of bicarbonate in groundwater can serve as a powerful competitor and lead to the enrichment of fluoride and arsenic in groundwater. Most of the groundwater with high fluoride or arsenic content has nitrate content about or over 10 mg/L which, together with the observed positive correlations between nitrate and fluoride/arsenic, are indicative of common source of manmade pollution and of prevailing condition of leaching in the study area.  相似文献   
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Hydrological processes in karst basins are controlled by permeable multimedia, consisting of soil pores, epikarst fractures, and underground conduits. Distributed modelling of hydrological dynamics in such heterogeneous hydrogeological conditions is a challenging task. Basing on the multilayer structure of the distributed hydrology‐soil‐vegetation model (DHSVM), a distributed hydrological model for a karst basin was developed by integrating mathematical routings of porous Darcy flow, fissure flow and underground channel flow. Specifically, infiltration and saturated flow movement within epikarst fractures are expressed by the ‘cubic law’ equation which is associated with fractural width, direction, and spacing. A small karst basin located in Guizhou province of southwest China was selected for this hydrological simulation. The model parameters were determined on the basis of field measurement and calibrated against the observed soil moisture contents, vegetation interception, surface runoff, and underground flow discharges from the basin outlet. The results show that due to high permeability of the epikarst zone, a significant amount of surface runoff is only generated after heavy rainfall events during the wet season. Rock exposure and the epikarst zone significantly increase flood discharge and decrease evapotranspiration (ET) loss; the peak flood discharge is directly proportional to the size of the aperture. Distribution of soil moisture content (SMC) primarily depends on topographic variations just after a heavy rainfall, while SMC and actual ET are dominated by land cover after a period of consecutive non‐rainfall days. The new model was able to capture the sharp increase and decrease of the underground streamflow hydrograph, and as such can be used to investigate hydrological effects in such rock features and land covers. Copyright © 2011 John Wiley & Sons, Ltd.  相似文献   
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The present study deals with geochemical characteristics and petrogenesis of three younger granite varieties (coarse-grained biotite-muscovite granites (CBG), garnetiferous muscovite granites (GMG) and Abu Aggag biotite granites (AAG)) in El-Hudi area, east of Aswan, southeastern desert of Egypt. Mineral chemistry and whole rock chemistry data revealed that all granites have high SiO2 (70.8-74.7 wt.%), Al2O3 (12.8-14.3 wt.%), Na2O and K2O (>3.2 wt.%) contents with high Na2O/K2O ratios (~>1). Plagioclase feldspars range in composition from albite to oligoclase (An9-27) in CBG, oligoclase (An13-18) in GMG and albite (An2-6) in AAG. Potash feldspars are mainly perthitic microcline and exhibit chemical formulae as (Or93-96 Ab7-4 An0) in CBG, (Or95-98 Ab5-2 An0) in GMG and (Or82-98 Ab18-2 An0) in AAG. Biotites from CBG and GMG are enriched in (Mg and Ti) and depleted in (Al, Fe, Mn and K) compared with those of AAG. Biotites from CBG and GMG had been derived from calc-alkaline magma, whereas those from AAG had been derived from peraluminous magma. Chlorites from CBG and GMG are Mg-Fe bearing, while that from AAG is Fe-rich chlorite (chamosite). The CBG and GMG are Mg-rich monzogranites originated from high-K calc-alkaline magma with metaluminous to mildly peraluminous nature. The AAG are Fe-rich monzogranites to syenogranites generated from high-K calc-alkaline peraluminous magma. Both CBG and GMG are late- to post-orogenic granites, while the AAG are post-orogenic granites. All three granite varieties are considered as evolved I-type granites, formed under low to moderate water pressures (~ 0.5-7 kbars) and relatively high ranges of crystallization temperatures (~700-890°C). They were generated from partial melting of crustal materials at lower (CBG >30 km depth) and intermediate (GMG & AAG ~20-30 km depth) levels. The crystal fractionation was the predominant process during differentiation of parent magmas of these granites. Geochemical characteristics manifest that AAG represent the highly fractionated member of magma cycle differs from that produced CBG and GMG. The CBG are relatively enriched in both U and Th existing only within the accessory minerals such as zircon, sphene, and allanite.  相似文献   
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BVRI CCD photometry of the poorly studied open cluster NGC 6724 has been carried out down to a limiting magnitude of V ~20 mag. The stars of the cluster have been observed using the Newtonian focus(f/4.84) of the 74-inch telescope at Kottamia Astronomical Observatory in Egypt.Also, the 2 MASS-JHK system is used to confirm the results we obtained. The main photometric parameters have been estimated for the present object; the diameter is found to be 6 arcmin, the distance is 1530±60 pc from the Sun and the age is 900±50 Myr. The optical reddening E(B-V) = 0.65 mag,while the infrared reddening is E(J-H) = 0.20 mag. The slope of the mass function distribution and the relaxation time estimations indicate that cluster NGC 6724 is dynamically relaxed.  相似文献   
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This paper deals with the generation of seismic accelerograms which are compatible with a given response spectrum and other design specifications. The time sampling of the stochastic accelerogram yields a time series represented by a random vector in high dimension. The probability density function of this random vector is constructed using the maximum entropy (MaxEnt) principle under constraints defined by the available information (design specifications). In this paper, an adapted algorithm is proposed to identify the Lagrange multipliers introduced in the MaxEnt principle to take into account the constraints. This algorithm is based on (1) the minimization of an appropriate convex functional and (2) the construction of the probability distribution defined as the invariant measure of an Itô stochastic differential equation in order to estimate the integrals in high dimension of the problem. The constraints related to a seismic accelerogram are developed explicitly. This methodology is validated through an application for which the available information is related to the variance of each component of the random vector representing the accelerogram, statistics on the response spectrum, on the peak ground acceleration, on the cumulative absolute velocity and on the end-values for the velocity and for the displacement.  相似文献   
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The Tafilalt region, located at the eastern end of the Anti-Atlas chain in Morocco, was shaken on 23 and 30 October 1992 by two moderate earthquakes of magnitude mb ∼ 5 and intensity ∼ VI MSK64, which caused two deaths and great damage in the area between Erfoud and Rissani. The review of data available on the seismic crisis allowed us to improve the knowledge on the macroseismic, instrumental and source parameters of the earthquakes. The main results of the present study are: (1) location of the epicentres with the help of data from a close portable network allowed us to propose new epicentral coordinates at 31.361° N, 4.182° W (23 October) and 31.286° N, 4.347° W (30 October); both events have focal depths of 2 km; (2) the shock of 30 October was followed by a series of 305 aftershocks, most of which were located west of Rissani; the 61 best-constrained events had focal depths of 5 to 19 km and magnitudes 0.7 to 3; (3) the largest damage was located in an area between the two epicentres within the Tafilalt valley and was probably amplified by site effects due to the proximity of the water table within the Quaternary sediments; (4) focal mechanisms of the main events correspond to strike-slip faulting with fault planes oriented N–S (left lateral) and E–W (right lateral); the only mechanism available for the aftershocks also corresponds to strike-slip faulting; (5) spectral analysis shows that the scalar seismic moment (Mo) of the first event is slightly larger than the second; the corresponding values of Mw are 5.1 and 5.0, respectively; (6) the dimensions of the faults for a circular fault model are 7.7 ± 1.4 and 7.4 ± 1.2 km, respectively; the average displacement is 4 cm for the first event and 3.7 cm for the second; the stress drop is 0.4 and 0.3 MPa, respectively, in agreement with standard values; (7) the Coulomb Stress test performed for both earthquakes suggests a relationship between both events only when the used location is at the limit of the horizontal uncertainty; (8) finally, the occurrence of these shocks suggests that the Anti-Atlas is undergoing tectonic deformation in addition to thermal uplift as suggested by recent publications.  相似文献   
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In this study, data on several metals (Cd, Pb, Zn and Cu) in soil and isopod Porcellio laevis taken at 21 sites from the most important industrial areas in Tunisia (Bizerte, Nabeul, Zaghouan, Sfax and Gabes) were presented. Heavy metal concentrations in both soil samples and isopods were determined using atomic absorption spectrometry. Soil contamination was estimated using the contamination factor (CF). On the other hand, the bioaccumulation factor (BAF) was determined to estimate metal accumulation in isopods. The CF values show that the level of contamination varies between sampled soils, which may be due to the source of pollution at each site. The BAF values allow defining the order of accumulation in P. laevis which was classified for the majority of the sampled sites as a macro-concentrator of Cu and Zn and a deconcentrator of Cd with some exceptions. A principal component analysis (PCA) was conducted between soil properties (pH, OM and CaCO3) and metal concentrations in soils. Through PCA, we obtained four groups in which soils were distinguished by their physicochemical properties and their metal concentrations. Moreover, linear multiple regressions with a downward stepwise procedure were conducted to test the relationships between the physicochemical parameters and metal concentrations in both soils and isopods. Thus, positive correlations (0.78 < R 2 < 0.99) were obtained for Pb considering dataset from the groups 1, 2 and for Zn with data of groups 2 and 3. Finally, results showed that P. laevis could be used as a bio-indicator for monitoring and reducing the impact of pollution in terrestrial ecosystems.  相似文献   
10.
Analytical expression of the equi-potential surface and the distorted potential by tidal effect for binary galactic system has been derived. The comparison between the numerical results and the observed data has been given.  相似文献   
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