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Bettina Matti Helen E. Dahlke Bastien Dieppois Damian M. Lawler Steve W. Lyon 《水文研究》2017,31(24):4354-4370
Fluvial flood events have substantial impacts on humans, both socially and economically, as well as on ecosystems (e.g., hydroecology and pollutant transport). Concurrent with climate change, the seasonality of flooding in cold environments is expected to shift from a snowmelt‐dominated to a rainfall‐dominated flow regime. This would have profound impacts on water management strategies, that is, flood risk mitigation, drinking water supply, and hydro power. In addition, cold climate hydrological systems exhibit complex interactions with catchment properties and large‐scale climate fluctuations making the manifestation of changes difficult to detect and predict. Understanding a possible change in flood seasonality and defining related key drivers therefore is essential to mitigate risk and to keep management strategies viable under a changing climate. This study explores changes in flood seasonality across near‐natural catchments in Scandinavia using circular statistics and trend tests. Results indicate strong seasonality in flooding for snowmelt‐dominated catchments with a single peak occurring in spring and early summer (March through June), whereas flood peaks are more equally distributed throughout the year for catchments located close to the Atlantic coast and in the south of the study area. Flood seasonality has changed over the past century seen as decreasing trends in summer maximum daily flows and increasing winter and spring maximum daily flows with 5–35% of the catchments showing significant changes at the 5% significance level. Seasonal mean daily flows corroborate those findings with higher percentages (5–60%) of the catchments showing statistically significant changes. Alterations in annual flood occurrence also point towards a shift in flow regime from snowmelt‐dominated to rainfall‐dominated with consistent changes towards earlier timing of the flood peak (significant for 25% of the catchments). Regionally consistent patterns suggest a first‐order climate control as well as a local second‐order catchment control, which causes inter‐seasonal variability in the streamflow response. 相似文献
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Sabine Geiß Nicole Lettmann Aurélien Rey Herbert Lepper Birgit Körner Silvio Mais Theodor Prey Bettina Hilger Moana Engelke Stephan Lebertz Claudine Chatellier George Sawal Dirk Löffler Tom Schillings 《洁净——土壤、空气、水》2011,39(6):537-542
A first preliminary interlaboratory trial was planned to prepare ISO/DIS 12010: Water quality – determination of short chain polychlorinated alkanes (SCCP) in water – method using GC/MS and electron capture negative ionisation (ECNI). The task was to determine the sum of short chain polychlorinated n‐alkanes with carbon chain lengths of C10–C13 and a chlorine content between 49 and 67% in water by GC‐ECNI‐MS and quantification by multiple linear regression described in ISO/DIS 12010 as the compulsory method. Distributed samples were obtained from a real water extract spiked with a target concentration of 0.4 µg/mL sum of SCCP, i.e. the environmental quality target level according to the Water Framework Directive. The interlaboratory trial included the calibration, a column chromatographic clean up, a concentration step and an integration of chromatographic unresolved humps as well as the quantification with multiple linear regression. Reproducibility standard deviations between 21.5 and 22.9% were achieved by 17 participating laboratories from four countries. The method outlined no significant difference of the results between the standard solution and a real water matrix extract. On the basis of this succeeded preliminary interlaboratory trial the final interlaboratory trial for validation of ISO 12010 was prepared in autumn 2010. 相似文献
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Here we have examined interactions of gold nanoparticles differing in primary particle size and coating with the green algae Chlamydomonas reinhardtii as function of the colloidal stability of the particles in the experimental media used for toxicity studies. Interactions of dissolved Au3+ ions with algae were also examined. Included endpoints were photosynthetic yield and algal growth. Morphological and structural effects were examined microscopically and by flow cytometry. The results indicate no significant toxicity of gold nanoparticles to C. reinhardtii. Analysis of published data suggests toxicity of gold nanoparticles on algal growth to relate rather to particular coatings than to the gold core. 相似文献
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GIS-based assessment of landslide susceptibility on the base of the Weights-of-Evidence model 总被引：4，自引：2，他引：2
The major scope of the study is the assessment of landslide susceptibility of Flysch areas including the Penninic Klippen in the Vienna Forest (Lower Austria) by means of Geographical Information System (GIS)-based modelling. A statistical/probabilistic method, referred to as Weights-of-Evidence (WofE), is applied in a GIS environment in order to derive quantitative spatial information on the predisposition to landslides. While previous research in this area concentrated on local geomorphological, pedological and slope stability analyses, the present study is carried out at a regional level. The results of the modelling emphasise the relevance of clay shale zones within the Flysch formations for the occurrence of landslides. Moreover, the distribution of mass movements is closely connected to the fault system and nappe boundaries. An increased frequency of landslides is observed in the proximity to drainage lines, which can change to torrential conditions after heavy rainfall. Furthermore, landslide susceptibility is enhanced on N-W facing slopes, which are exposed to the prevailing direction of wind and rainfall. Both of the latter geofactors indirectly show the major importance of the hydrological conditions, in particular, of precipitation and surface runoff, for the occurrence of mass movements in the study area. Model performance was checked with an independent validation set of landslides, which are not used in the model. An area of 15% of the susceptibility map, classified as highly susceptible, “predicted” 40% of the landslides. 相似文献
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Takehiro Koyaguchi Bettina Scheu Noriko K. Mitani Oleg Melnik 《Journal of Volcanology and Geothermal Research》2008
When a highly viscous bubbly magma is sufficiently decompressed, layer-by-layer fracturing propagates through the magma at a certain speed (fragmentation speed). On the basis of a recent shock tube theory by Koyaguchi and Mitani [Koyaguchi, T., Mitani, N. K., 2005. A theoretical model for fragmentation of viscous bubbly magmas in shock tubes. Journal of Geophysical Research 110 (B10), B10202. doi:10.1029/2004JB003513.], gas overpressures at the fragmentation surface are estimated from experimental data on fragmentation speed in shock tube experiments for natural volcanic rocks with various porosities. The results show that gas overpressure at the fragmentation surface increases as initial sample pressure increases and sample porosity decreases. We propose a new fragmentation criterion to explain the relationship between the gas overpressure at the fragmentation surface, the initial pressure and the porosity. Our criterion is based on the idea that total fragmentation of highly viscous bubbly magmas occurs when the tensile stress at the midpoint between bubbles exceeds a critical value. We obtain satisfactory agreement between our simulation and experiment when we assume that the critical value is inversely proportional to the square root of bubble wall thickness. This fragmentation criterion suggests that long micro-cracks or equivalent flaws (e.g., irregular-shaped bubbles) that reach the midpoints between bubbles are a dominant factor to determine the bulk strength of the bubbly magma. 相似文献
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In most natural sedimentary systems labile and refractory organic material (OM) occur concomitantly. Little, however, is known on how different kinds of OM interact and how such interactions affect early diagenesis in sediments. In a simple sediment experiment, we investigated how interactions of OM substrates of different degradability affect benthic nitrogen (N) dynamics. Temporal evolution of a set of selected biogeochemical parameters was monitored in sandy sediment over 116 days in three experimental set-ups spiked with labile OM (tissue of Mytilus edulis), refractory OM (mostly aged Zostera marina and macroalgae), and a 1:1 mixture of labile and refractory OM. The initial amounts of particulate organic carbon (POC) were identical in the three set-ups. To check for non-linear interactions between labile and refractory OM, the evolution of the mixture system was compared with the evolution of the simple sum of the labile and refractory systems, divided by two. The sum system is the experimental control where labile and refractory OM are virtually combined but not allowed to interact. During the first 30 days there was evidence for net dissolved-inorganic-nitrogen (DIN) production followed by net DIN consumption. (Here ‘DIN’ is the sum of ammonium, nitrite and nitrate.) After 30 days a quasi steady state was reached. Non-linear interactions between the two types of OM were reflected by three main differences between the early-diagenetic evolutions of nitrogen dynamics of the mixture and sum (control) systems: (1) In the mixture system the phases of net DIN production and consumption commenced more rapidly and were more intense. (2) The mixture system was shifted towards a more oxidised state of DIN products [as indicated by increased (nitrite + nitrate)/(ammonium) ratios]. (3) There was some evidence that more OM, POC and particulate nitrogen were preserved in the mixture system. That is, in the mixture system more particulate OM was preserved while a higher proportion of the decomposed particulate N was converted into inorganic N. It can be concluded that during the first days and weeks of early diagenesis the magnitude and composition of the flux of decompositional dissolved N-compounds from sediments into the overlying water was influenced by non-linear interactions of OM substrates of different degradability. Given these experimental results it is likely that the relative spatial distributions of OM of differing degradability in sediments control the magnitude and composition of the return flux of dissolved N-bearing compounds from sediments into the overlying water column. 相似文献
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Benjamin Kaeser Bettina Olker Angelika Kalt Rainer Altherr Thomas Pettke 《Contributions to Mineralogy and Petrology》2009,157(4):453-472
Garnet-bearing and garnet-free pyroxenite xenoliths from Quaternary basanites of Marsabit, northern Kenya, were analysed for
microstructures and mineral compositions (major and trace elements) to constrain the thermal and compositional evolution of
the lithospheric mantle in this region. Garnet-bearing rocks are amphibole-bearing websterite with ~5–10 vol% orthopyroxene.
Clinopyroxene is LREE-depleted and garnet has high HREE contents, in agreement with an origin as cumulates from basaltic mantle
melts. Primary orthopyroxene inclusions in garnet suggest that the parental melts were orthopyroxene-saturated. Rock fabrics
vary from weakly to strongly deformed. Thermobarometry indicates extensive decompression and cooling (~970–1,100°C at ~2.3–2.6 GPa
to ~700–800°C at ~0.5–1.0 GPa) during deformation, best interpreted as pyroxenite intrusion into thick Paleozoic continental
lithosphere subsequently followed by continental rifting (i.e., formation of the Mesozoic Anza Graben). During continental
rifting, garnet websterites were decompressed (garnet-to-spinel transition) and experienced the same P–T evolution as their host peridotites. Strongly deformed samples show compositional overlaps with cpx-rich, initially garnet-bearing
lherzolite, best explained by partial re-equilibration of peridotite and pyroxenite during deformation and mechanical mingling.
In contrast, garnet-free pyroxenites include undeformed, cumulate-like samples, indicating that they are younger than the
garnet websterites. Major and trace element compositions of clinopyroxene and calculated equilibrium melts suggest crystallisation
from alkaline basaltic melt similar to the host basanite, which suggests formation in the context of alkaline magmatism during
the development of the Kenya rift.
Electronic supplementary material The online version of this article (doi:) contains supplementary material, which is available to authorized users. 相似文献