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Shoji Kojima María Constanza San Martín Toshiro Nagase Daisuke Nakashima Claudio Bisso Andrew Menzies 《Resource Geology》2021,71(1):80-90
Modes of occurrence of Au‐ and Ag‐bearing phases and their relation with associated hypogene ore minerals were examined with the objective to elucidate Au‐Ag distribution at the Esperanza porphyry deposit in the Eocene Centinela copper belt, using ore‐microscope modal analysis, semi‐quantitative analyses by automated mineralogy, electron probe microanalysis, and secondary ion mass spectrometer. The Esperanza hypogene mineralization is characterized by early‐stage chalcopyrite‐rich veinlets in the potassic alteration zone and later polymetallic stage with tennantite and galena in the chlorite‐sericitic alteration zone. Only the early‐stage chalcopyrite contains fine‐grained electrum (Au68Ag32 ‐ Au81Ag19) and hessite (Ag2Te), and thus yields positive correlations in Cu vs. Au and Cu vs. Ag grades that are clearly recognized in the hypogene sulfide zone. The early‐stage chalcopyrite grains frequently exhibit polysynthetic twinning suggestive of inversion from intermediate solid solution. These features suggest that the fine‐grained electrum and hessite are products exsolved in the cooling process with the intermediate solid solution to chalcopyrite inversion. In contrast, tennantite and galena of the later‐stage mineralization contain no detectable Ag, and it is thus proposed that the early‐stage inverted chalcopyrite is the principal storage of economically important precious metals. 相似文献
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The transitional character of climatic conditions confers great relevance to paleoclimate studies in the semiarid region where glacial and Holocene geomorphologic records are scarce. Here we present the paraglacial and fluvial evolution of the Turbio valley (30°S) using both field observations and 14C AMS chronology. Two key sites at the uppermost Turbio valley show glacial margins which likely formed during the 17-12 ka Central Andean Pluvial Event and earlier 37-27 ka episodes associated with glacial advances reported elsewhere in the semiarid Andes. Likewise, two episodes of subsequent paraglacial response are identified: a first episode corresponds to early Holocene fine-grained deposits (~ 11,500-7800 cal yr BP) extending far downstream (> 40 km) from the glacial margins. These deposits and coeval debris cones (~ 11,000-5500 cal yr BP) are the result of arid conditions with occasional runoffs that were unable to export sediments along the trunk valley. The second episode corresponds to disconformably overlying fluvial gravels extending ~ 70 km downstream from the glacial margin, indicative of an increase in the fluvial transport capacity occurring not long after 5500 cal yr BP. Fluvial transport increase resulted from a late Holocene shift to wetter climate conditions, representing a forcing factor which enhanced the paraglacial response. 相似文献
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In this present era of the Anthropocene, human activities affect hydrology and droughts. Quantifying this human influence improves our understanding and builds fundamental knowledge for water resource management. Analysis of observation data is useful in progressing this knowledge as these human activities and feedbacks are intrinsically included. Therefore, here we present an observation-based approach, the upstream–downstream comparison, to quantify changes in hydrological drought downstream of a human activity. We demonstrate this approach in a basin in northern Chile, where a reservoir was introduced. A sensitivity analysis is performed to assess how different choices of drought analysis threshold can affect the results and interpretation. We find that many commonly used choices do not exclude human activities from the threshold and therefore could be underestimating the change detected due to the human influence. The upstream–downstream comparison avoids this through the application of the upstream station threshold rather than the human-influenced downstream station. 相似文献
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