Northwest Africa 11024—A heated and dehydrated unique carbonaceous (CM) chondrite     

Samuel Ebert  Addi Bischoff  Dennis Harries  Sarah Lentfort  Jean‐Alix Barrat  Andreas Pack  Jrme Gattacceca  Robbin Visser  Peter Schmid‐Beurmann  Stephan Kimpel 《Meteoritics & planetary science》2019,54(2):328-356

Based on the high abundance of fine‐grained material and its dark appearance, NWA 11024 was recognized as a CM chondrite, which is also confirmed by oxygen isotope measurements. But contrary to known CM chondrites, the typical phases indicating aqueous alteration (e.g., phyllosilicates, carbonates) are missing. Using multiple analytical techniques, this study reveals the differences and similarities to known CM chondrites and will discuss the possibility that NWA 11024 is the first type 3 CM chondrite. During the investigation, two texturally apparent tochilinite–cronstedtite intergrowths were identified within two thin sections. However, the former phyllosilicates were recrystallized to Fe‐rich olivine during a heating event without changing the textural appearance. A peak temperature of 400–600 °C is estimated, which is not high enough to destroy or recrystallize calcite grains. Thus, calcites were never constituents of the mineral paragenesis. Another remarkable feature of NWA 11024 is the occurrence of unknown clot‐like inclusions (UCLIs) within fine‐grained rims, which are unique in this clarity. Their density and S concentration are significantly higher than of the surrounding fine‐grained rim and UCLIs can be seen as primary objects that were not formed by secondary alteration processes inside the rims. Similarities to chondritic and cometary interplanetary dust particles suggest an ice‐rich first‐generation planetesimal for their origin. In the earliest evolution, NWA 11024 experienced the lowest degree of aqueous alteration of all known CM chondrites and subsequently, a heating event dehydrated the sample. We suggest to classify the meteorite NWA 11024 as the first type 3 CM chondrite similar to the classification of CV3 chondrites (like Allende) that could also have lost their matrix phyllosilicates by thermal dehydration.  相似文献   

The presolar grain inventory of fine‐grained chondrule rims in the Mighei‐type (CM) chondrites     

Jan Leitner  Knut Metzler  Christian Vollmer  Christine Floss  Pierre Haenecour  Jnos Kodolnyi  Dennis Harries  Peter Hoppe 《Meteoritics & planetary science》2020,55(6):1176-1206

We investigated the inventory of presolar silicate, oxide, and silicon carbide (SiC) grains of fine‐grained chondrule rims in six Mighei‐type (CM) carbonaceous chondrites (Banten, Jbilet Winselwan, Maribo, Murchison, Murray and Yamato 791198), and the CM‐related carbonaceous chondrite Sutter's Mill. Sixteen O‐anomalous grains (nine silicates, six oxides) were detected, corresponding to a combined matrix‐normalized abundance of ~18 ppm, together with 21 presolar SiC grains (~42 ppm). Twelve of the O‐rich grains are enriched in ¹⁷O, and could originate from low‐mass asymptotic giant branch stars. One grain is enriched in ¹⁷O and significantly depleted in ¹⁸O, indicative of additional cool bottom processing or hot bottom burning in its stellar parent, and three grains are of likely core‐collapse supernova origin showing enhanced ¹⁸O/¹⁶O ratios relative to the solar system ratio. We find a presolar silicate/oxide ratio of 1.5, significantly lower than the ratios typically observed for chondritic meteorites. This may indicate a higher degree of aqueous alteration in the studied meteorites, or hint at a heterogeneous distribution of presolar silicates and oxides in the solar nebula. Nevertheless, the low O‐anomalous grain abundance is consistent with aqueous alteration occurring in the protosolar nebula and/or on the respective parent bodies. Six O‐rich presolar grains were studied by Auger Electron Spectroscopy, revealing two Fe‐rich silicates, one forsterite‐like Mg‐rich silicate, two Al‐oxides with spinel‐like compositions, and one Fe‐(Mg‐)oxide. Scanning electron and transmission electron microscopic investigation of a relatively large silicate grain (490 nm × 735 nm) revealed that it was crystalline åkermanite (Ca₂Mg[Si₂O₇]) or a an åkermanite‐diopside (MgCaSi₂O₆) intergrowth.  相似文献   

Oxygen and Nutrient Exchanges at the Sediment-Water Interface: a Global Synthesis and Critique of Estuarine and Coastal Data     

W. R. Boynton  M. A. C. Ceballos  E. M. Bailey  C. L. S. Hodgkins  J. L. Humphrey  J. M. Testa 《Estuaries and Coasts》2018,41(2):301-333

Estuarine and coastal marine sediment-water fluxes are considered to be important ecological features, but a global-scale assessment has yet to be developed. Goals of this work were to assemble a global-scale database of net sediment-water flux measurements, examine measurement techniques, characterize the geographic distribution and magnitude of sediment fluxes, explore the data for controls on sediment flux magnitude, and assess the importance of sediment fluxes in ecosystem-level metabolism and primary production. We examined 480 peer-reviewed sources and found sediment flux data for 167 estuarine and coastal systems. Most measurements were made in North America, Europe, and Australia. Fluxes varied widely among systems, some by several orders of magnitude. Inter-annual variability within sites was less than an order of magnitude but time series flux data to evaluate this were rare. However, limited time series data exhibited large and rapid responses to decreased external nutrient loading rates, climate change effects (possible temperature effects), and variability in trophic conditions. Comparative analyses indicated organic matter supply to sediments set the upper limits of flux magnitude, with other factors playing secondary roles. Two metrics were developed to assess ecosystem-level importance of sediment-water fluxes. Sediments represented 30% or more of depth-integrated rates of aerobic system respiration at depths of <10 m. An annual phytoplankton production data set was used to estimate N and P demand; sediments supplied an average of 15–32% of N and 17–100% of P demand and, in some cases, was as large or larger than external nutrient inputs. The percent of demand supplied by sediments was highest in temperate latitudes and lower in high and tropical latitudes.  相似文献   

Balance of Catchment and Offshore Nutrient Loading and Biogeochemical Response in Four New Zealand Coastal Systems: Implications for Resource Management     

John R. Zeldis  Dennis P. Swaney 《Estuaries and Coasts》2018,41(8):2240-2259

Nutrient mass balance analyses are a way of obtaining ‘whole system’ viewpoints on coastal biogeochemical functions and their forcing. Seasonal mass balances are presented for four large bay systems in New Zealand (NZ), with the aim of showing how they can inform coastal management. Freshwater volumes, and surface and groundwater, wastewater and atmospheric inorganic and organic nitrogen (N) and phosphorus (P) were balanced with levels of salinity, N and P from ocean surveys, used to determine non-conservative N and P fluxes and, via stoichiometry, carbon (C) fluxes. For Golden and Tasman Bays and Hauraki Gulf, exchange with adjacent shelf waters usually dominated total N supply (80–85%). In contrast, for the Firth of Thames, 51% of total N and 85% of dissolved inorganic N supply originated from its agricultural catchment. Net ecosystem metabolism (NEM; balance of autotrophy and heterotrophy) of Golden and Tasman Bays and Hauraki Gulf was usually nearly balanced. In contrast, Firth NEM was highly seasonally variable, often exhibiting strong heterotrophy coincident with expression of respiration-related stressors (low O₂ and high DIC/low pH). Denitrification accounted for about 51% of total N export across the four systems, signifying its importance as a eutrophication-regulating ecosystem service. Budgets made 12 years apart in the Firth showed decreased denitrification efficiency, coincident with large increases in system N and phytoplankton. The findings for land-ocean nutrient balance, NEM and denitrification showed how mass balance budgeting can inform coastal management, including inventories of nutrient inputs, balances of oceanic and terrestrial nutrient loading, and potential for risk associated with biogeochemical responses.  相似文献   

A comparison of frameworks for separating the impacts of human activities and climate change on river flow in existing records and different near-future scenarios     

Soghra Andaryani  Vahid Nourani  James Ball  Saeed Jahanbakhsh Asl  Hamidreza Keshtkar  Dennis Trolle 《水文研究》2021,35(7):e14301

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Assessing the Completeness of Bicycle Trail and Lane Features in OpenStreetMap for the United States   总被引：1，自引：0，他引：1       下载免费PDF全文

Hartwig H. Hochmair  Dennis Zielstra  Pascal Neis 《Transactions in GIS》2015,19(1):63-81

This article assesses the completeness of bicycle trail and on‐street lane features in OpenStreetMap (OSM). Comparing OSM cycling features with reference data from local planning agencies for selected US Urbanized Areas shows that OSM bicycle trails tend to be more completely mapped than bicycle lanes. Manual evaluation of mapped cycling features in OSM and Google Maps for selected test areas within the Central Business Districts of Portland (OR) and Miami (FL) through comparison with governmental datasets, satellite imagery, and Google Street View, shows that the Bicycle layer in Google Maps can help to identify some missing or erroneously mapped OSM cycling links. However, Google Maps was also found to have some gaps in its data layers, suggesting that consultation of current trail and lane data from local planning authorities, if available, should be considered as an additional data source for bicycle related planning projects.  相似文献   

The pitfalls and potential of debt-for-nature swaps: A US-Indonesian case study   总被引：1，自引：0，他引：1  

Danny Cassimon  Martin Prowse  Dennis Essers   《Global Environmental Change》2011,21(1):93-102

The vital role of forests in limiting the likelihood of dangerous climate change has precipitated renewed interest in debt-for-nature swaps. This article uses evidence on past debt-for-nature deals and similar debt mechanisms to assess a recent second wave of such swaps. It outlines five typical shortcomings of this form of financial transaction: that they often fail to deliver additional resources to the debtor country and/or debtor government budget; often fail to deliver more resources for conservation/climate purposes; often have a negligible effect on overall debt burdens (and, as such, do not generate more ‘indirect’ benefits); and are often in conflict with principles of alignment with government policy and alignment with government systems (these two last shortcomings being important elements within the new aid delivery paradigm). Our analysis is applied to a recent debt-for-nature swap between the United States and Indonesia. We show that this case, which we consider a litmus test for current swap practice, performs unevenly across the five shortcomings. First, although the US-Indonesian swap does increase available resources to Indonesia at the country level, it does not generate extra budgetary room for the Indonesian government. Second, the extent to which the resources provided by the swap are additional to other donor support and reserved domestic budget lines for conservation goals is unclear. Third, the swap is too insignificant to create indirect (positive) economic effects. Regarding alignment issues, fourth, the swap is very much in line with current national policy, but, fifth, appears at odds with the new aid delivery paradigm's insistence on system alignment. We argue that if a second generation of debt-for-nature swaps is to be pursued then they need to avoid the common pitfalls associated with this form of finance. Moreover, there is a need to debate broader ways of linking debt service repayments to climate mitigation and adaptation.  相似文献   

意大利产业区重组：集团化、创新与国际化     

王周杨  魏也华 《地理科学》2011,(11):1335-1341

近30 a来,意大利产业区成为西方学术界研究的热点与争论焦点。传统的意大利产业区模式主要强调中小企业为主的＂弹性专业化＂生产系统与本地社区的嵌入性。在全球化与知识经济的宏观背景下,意大利产业区正在经历一系列的以集团化、创新与国际化为主要特征的产业重组过程：产业区的组织结构开始由中小企业为主的＂弹性专业化＂生产系统向＂产...  相似文献   

Foreign Hypermarket Retailers in China: Spatial Penetration,Local Embeddedness,and Structural Paradox          下载免费PDF全文

Ling Zhang  Yehua Dennis Wei 《Geographical review》2015,105(4):528-550

As the world economy shifts towards services, transnational corporations (TNCs) in the service sector have accelerated their expansion in emerging economies. This paper examines the development and embeddedness of foreign hypermarket retailers in China. It also analyzes the spatial penetration patterns of retail TNCs, the impacts of home and host economies on their local embeddedness, and how they resolve the structural paradox between enforcing standardization and conducting localization. The expansion of retail TNCs has been influenced by the gradual liberalization policies of the Chinese government. Spatially, they expanded in two directions: from the eastern costal region to the central and western hinterland, and along China's urban hierarchy from larger cities to smaller cities. While home economies greatly influenced their initial strategies, foreign hypermarket retailers are constantly adjusting to better embed in the Chinese market and to more effectively resolve the structural paradox.  相似文献   

中国城市尺度科学知识网络与技术知识网络结构的时空复杂性   总被引：11，自引：4，他引：7  

李丹丹  汪涛  魏也华  袁丰 《地理研究》2015,34(3)

知识在产业集聚、区域创新中的地位越来越突出,城市知识储量及其在区域知识网络中的地位对城市的综合竞争力有重要影响。学术论文合作与专利合作是知识溢出的体现形式,是科学和技术发展的重要成果,也是度量区域创新能力的主要指标。以2000-2009年中国生物技术领域合著论文和共同申请专利的信息为原始数据,分别构建中国城市间科学知识网络(scientific knowledge network,SKN)与技术知识网络(technological knowledge network,TKN)。运用复杂网络与地学空间分析方法,从整体网络结构特征、择优链接性、中心城市及其自我网络的空间特征等方面进行分析,探究知识溢出的时空复杂性。研究表明:1 SKN和TKN具有无标度网络特征;SKN节点度数的异质性高于TKN。2两种网络均呈异配性,即城市选择合作对象存在明显择优链接性,知识溢出具有粘着性和空间依赖性。3 SKN中心城市具有明显的等级结构,空间分布总体呈"大分散小集聚"特点;TKN中心城市层级结构不明显,尚未形成明显极化中心。4 SKN中心城市自我网络的合作空间,由最初的沿海省会城市间的合作转向长三角、珠三角、京津冀等区域间和沿海城市与内陆城市间的合作,区域间知识溢出明显;TKN中心城市自我网络仍多分布于沿海城市和少数中西部省会城市,区域间知识溢出不明显。5 SKN中心城市及其自我网络的时空演变存在等级扩散和传染扩散的现象,符合时空梯度推移规律,且空间等级梯度逐渐向扁平化转变;TKN中心城市及其自我网络的时空演变以等级扩散为主,时空梯度推移现象不明显。研究结论为量化知识溢出及知识溢出网络结构的时空演化过程提供新的研究视角,对城市创新政策的制定有一定借鉴意义。  相似文献