Spinel assemblages in lunar meteorites Graves Nunataks 06157 and Dhofar 1528: Implications for impact melting and equilibration in the Moon's upper mantle     

Axel Wittmann  Randy L. Korotev  Bradley L. Jolliff  Paul K. Carpenter 《Meteoritics & planetary science》2019,54(2):379-394

Magnesium‐rich spinel assemblages occur in the two lunar vitric breccia meteorites—Dhofar (Dho) 1528 and Graves Nunataks (GRA) 06157. Dho 1528 contains up to ~0.7 mm cumulate Mg‐rich spinel crystals associated with Mg‐rich olivine, Mg‐ and Al‐rich pyroxene, plagioclase, and rare cordierite. Using thermodynamic calculations of these mineral assemblages, we constrain equilibration depths and discuss an origin of these lithologies in the upper mantle of the Moon. In contrast, small, 10 to 20 μm spinel phenocryst assemblages in glassy melt rock clasts in Dho 1528 and GRA 06157 formed from the impact melting of Mg‐rich rocks. Some of these spinel phenocrysts match compositional constraints for spinel associated with “pink spinel anorthosites” inferred from remote sensing data. However, such spinel phenocrysts in meteorites and Apollo samples are typically associated with significant amounts of olivine ± pyroxene that exceed the compositional constraints for pink spinel anorthosites. We conclude that the remotely sensed “pink spinel anorthosites” have not been observed in the collections of lunar rocks. Moreover, we discuss impact‐excavation scenarios for the spinel‐bearing assemblages in Dhofar 1528 and compare the bulk rock composition of Dho 1528 to strikingly similar compositions of Luna 20 samples that contain ejecta from the Crisium impact basin.  相似文献   

Multivariate adaptive regression splines for estimating riverine constituent concentrations     

Hong Huang  Xiaoliang Ji  Fang Xia  Shuhui Huang  Xu Shang  Han Chen  Minghua Zhang  Randy A. Dahlgren  Kun Mei 《水文研究》2020,34(5):1213-1227

Regression-based methods are commonly used for riverine constituent concentration/flux estimation, which is essential for guiding water quality protection practices and environmental decision making. This paper developed a multivariate adaptive regression splines model for estimating riverine constituent concentrations (MARS-EC). The process, interpretability and flexibility of the MARS-EC modelling approach, was demonstrated for total nitrogen in the Patuxent River, a major river input to Chesapeake Bay. Model accuracy and uncertainty of the MARS-EC approach was further analysed using nitrate plus nitrite datasets from eight tributary rivers to Chesapeake Bay. Results showed that the MARS-EC approach integrated the advantages of both parametric and nonparametric regression methods, and model accuracy was demonstrated to be superior to the traditionally used ESTIMATOR model. MARS-EC is flexible and allows consideration of auxiliary variables; the variables and interactions can be selected automatically. MARS-EC does not constrain concentration-predictor curves to be constant but rather is able to identify shifts in these curves from mathematical expressions and visual graphics. The MARS-EC approach provides an effective and complementary tool along with existing approaches for estimating riverine constituent concentrations.  相似文献   

Petrogenesis of lunar impact melt rock meteorite Oued Awlitis 001     

Axel Wittmann  Randy L. Korotev  Bradley L. Jolliff  Kunihiko Nishiizumi  A. J. Timothy Jull  Marc W. Caffee  Michael Zanetti  Anthony J. Irving 《Meteoritics & planetary science》2019,54(10):2167-2188

Oued Awlitis 001 is a highly feldspathic, moderately equilibrated, clast‐rich, poikilitic impact melt rock lunar meteorite that was recovered in 2014. Its poikilitic texture formed due to moderately slow cooling, which judging from textures of rocks in melt sheets of terrestrial impact structures, is observed in impact melt volumes at least 100 m thick. Such coherent impact melt volumes occur in lunar craters larger than ~50 km in diameter. The composition of Oued Awlitis 001 points toward a crustal origin distant from incompatible‐element‐rich regions. Comparison of the bulk composition of Oued Awlitis 001 with Lunar Prospector 5° γ‐ray spectrometer data indicates a limited region of matches on the lunar farside. After its initial formation in an impact crater larger than ~50 km in diameter, Oued Awlitis 001 was excavated from a depth greater than ~50 m. The cosmogenic nuclide inventory of Oued Awlitis 001 records ejection from the Moon 0.3 Ma ago from a depth of at least 4 m and little mass loss due to ablation during its passage through Earth's atmosphere. The terrestrial residence time must have been very short, probably less than a few hundred years; its exact determination was precluded by a high concentration of solar cosmic ray‐produced ¹⁴C. If the impact that excavated Oued Awlitis 001 also launched it, this event likely produced an impact crater >10 km in diameter. Using petrologic constraints and Lunar Reconnaissance Orbiter Camera and Diviner data, we test Giordano Bruno and Pierazzo as possible launch craters for Oued Awlitis 001.  相似文献   

Petrology and geochemistry of feldspathic impact‐melt breccia Abar al' Uj 012, the first lunar meteorite from Saudi Arabia          下载免费PDF全文

Marianna Mészáros  Beda A. Hofmann  Pierre Lanari  Randy L. Korotev  Edwin Gnos  Nicolas D. Greber  Ingo Leya  Richard C. Greenwood  A. J. Timothy Jull  Khalid Al‐Wagdani  Ayman Mahjoub  Abdulaziz A. Al‐Solami  Siddiq N. Habibullah 《Meteoritics & planetary science》2016,51(10):1830-1848

Abar al' Uj (AaU) 012 is a clast‐rich, vesicular impact‐melt (IM) breccia, composed of lithic and mineral clasts set in a very fine‐grained and well‐crystallized matrix. It is a typical feldspathic lunar meteorite, most likely originating from the lunar farside. Bulk composition (31.0 wt% Al₂O₃, 3.85 wt% FeO) is close to the mean of feldspathic lunar meteorites and Apollo FAN‐suite rocks. The low concentration of incompatible trace elements (0.39 ppm Th, 0.13 ppm U) reflects the absence of a significant KREEP component. Plagioclase is highly anorthitic with a mean of An_96.9Ab_3.0Or_0.1. Bulk rock Mg# is 63 and molar FeO/MnO is 76. The terrestrial age of the meteorite is 33.4 ± 5.2 kyr. AaU 012 contains a ~1.4 × 1.5 mm² exotic clast different from the lithic clast population which is dominated by clasts of anorthosite breccias. Bulk composition and presence of relatively large vesicles indicate that the clast was most probably formed by an impact into a precursor having nonmare igneous origin most likely related to the rare alkali‐suite rocks. The IM clast is mainly composed of clinopyroxenes, contains a significant amount of cristobalite (9.0 vol%), and has a microcrystalline mesostasis. Although the clast shows similarities in texture and modal mineral abundances with some Apollo pigeonite basalts, it has lower FeO and higher SiO₂ than any mare basalt. It also has higher FeO and lower Al₂O₃ than rocks from the FAN‐ or Mg‐suite. Its lower Mg# (59) compared to Mg‐suite rocks also excludes a relationship with these types of lunar material.  相似文献   

Stratigraphy of the Cenomanian–Turonian Oceanic Anoxic Event OAE2 in shallow shelf sequences of NE Egypt     

Ahmed El-Sabbagh  Abdel Aziz Tantawy  Gerta Keller  Hassan Khozyem  Jorge Spangenberg  Thierry Adatte  Brian Gertsch 《Cretaceous Research》2011,32(6):705-722

Two shallow water late Cenomanian to early Turonian sequences of NE Egypt have been investigated to evaluate the response to OAE2. Age control based on calcareous nannoplankton, planktic foraminifera and ammonite biostratigraphies integrated with δ¹³C stratigraphy is relatively good despite low diversity and sporadic occurrences. Planktic and benthic foraminiferal faunas are characterized by dysoxic, brackish and mesotrophic conditions, as indicated by low species diversity, low oxygen and low salinity tolerant planktic and benthic species, along with oyster-rich limestone layers. In these subtidal to inner neritic environments the OAE2 δ¹³C excursion appears comparable and coeval to that of open marine environments. However, in contrast to open marine environments where anoxic conditions begin after the first δ¹³C peak and end at or near the Cenomanian–Turonian boundary, in shallow coastal environments anoxic conditions do not appear until the early Turonian. This delay in anoxia appears to be related to the sea-level transgression that reached its maximum in the early Turonian, as observed in shallow water sections from Egypt to Morocco.  相似文献   

A thermometric indicator method as a replacement for the filter paper spot test in the titration of clays using methylene blue     

Alebachew Demoz  Randy J. Mikula 《Engineering Geology》2011,117(1-2):12-16

Large numbers of soil samples are routinely analyzed using methylene blue (MB) titration to determine clay content. Although, the MB filter paper spot test titration is simple, it is labor-intensive, subjective, and leaves no record for subsequent re-examination. Preliminary thermometric monitoring of the titration indicated a switch from endothermic to exothermic reaction during titration. We examined this nearly universal property of physicochemical processes as a potential replacement method to automate the MB clay titration, making use of literature data.We translated the isothermal enthalipmetric titration of montmorillonite using MB by Rytwo and Ruiz-Hitzky to an adiabatic thermometric titration (2003). The plot of temperature versus titrant volume gave two intersecting linear segments dependent on the titrated percentage of the clay's cation exchange capacity (CEC). The MB filter paper spot test endpoint reflects the first excess MB that persists in the solid suspension, which also happens to be a function of the clay's CEC. The spot test endpoint is correlated to the thermometric indicator point and, for montmorillonite, the two are related by an exact factor of two. Although this factor will naturally be dependent on the clay minerals in the samples, the analyses show that the thermometric indicator titration method is a viable replacement for the spot test. The proposed automation is commonplace as it is practiced with other types of titrations.  相似文献   

Deccan volcanism linked to the Cretaceous-Tertiary boundary mass extinction: New evidence from ONGC wells in the Krishna-Godavari Basin     

G. Keller  P. K. Bhowmick  H. Upadhyay  A. Dave  A. N. Reddy  B. C. Jaiprakash  T. Adatte 《Journal of the Geological Society of India》2011,78(5):399-428

A scientific challenge is to assess the role of Deccan volcanism in the Cretaceous-Tertiary boundary (KTB) mass extinction. Here we report on the stratigraphy and biologic effects of Deccan volcanism in eleven deep wells from the Krishna-Godavari (K-G) Basin, Andhra Pradesh, India. In these wells, two phases of Deccan volcanism record the world’s largest and longest lava mega-flows interbedded in marine sediments in the K-G Basin about 1500 km from the main Deccan volcanic province. The main phase-2 eruptions (∼80% of total Deccan Traps) began in C29r and ended at or near the KTB, an interval that spans planktic foraminiferal zones CF1–CF2 and most of the nannofossil Micula prinsii zone, and is correlative with the rapid global warming and subsequent cooling near the end of the Maastrichtian. The mass extinction began in phase-2 preceding the first of four mega-flows. Planktic foraminifera suffered a 50% drop in species richness. Survivors suffered another 50% drop after the first mega-flow, leaving just 7 to 8 survivor species. No recovery occurred between the next three mega-flows and the mass extinction was complete with the last phase-2 mega-flow at the KTB. The mass extinction was likely the consequence of rapid and massive volcanic CO₂ and SO₂ gas emissions, leading to high continental weathering rates, global warming, cooling, acid rains, ocean acidification and a carbon crisis in the marine environment.  相似文献   

AGU会刊Eos专访奥巴马总统科学顾问John Holdren     

Randy Showstack  左玉玲 《国际地震动态》2011,(2):1-3

奥巴马政府2011年1月即将面对共和党领导的众议院,日前,总统科学顾问JohnHoldren就广泛话题接受了美国地球物理联合会（AGU）会刊Eos的独家专访。在此之前,他曾在2010年12月13日旧金山举行的AGU秋季会议上发表过政策演讲。  相似文献   

Comment on “Post‐impact event bed (tsunamite) at the Cretaceous‐Palaeogene boundary deposited on a distal carbonate platform interior”          下载免费PDF全文

Eric Font  Gerta Keller  Diethard Sanders  Thierry Adatte 《地学学报》2017,29(5):329-331

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Oxygen‐18 dynamics in precipitation and streamflow in a semi‐arid agricultural watershed,Eastern Washington,USA     

Bryan G. Moravec  C. Kent Keller  Jeffrey L. Smith  Richelle M. Allen‐King  Angela J. Goodwin  Jerry P. Fairley  Peter B. Larson 《水文研究》2010,24(4):446-460

Understanding flow pathways and mechanisms that generate streamflow is important to understanding agrochemical contamination in surface waters in agricultural watersheds. Two environmental tracers, δ¹⁸O and electrical conductivity (EC), were monitored in tile drainage (draining 12 ha) and stream water (draining nested catchments of 6‐5700 ha) from 2000 to 2008 in the semi‐arid agricultural Missouri Flat Creek (MFC) watershed, near Pullman Washington, USA. Tile drainage and streamflow generated in the watershed were found to have baseline δ¹⁸O value of ?14·7‰ (VSMOW) year round. Winter precipitation accounted for 67% of total annual precipitation and was found to dominate streamflow, tile drainage, and groundwater recharge. ‘Old’ and ‘new’ water partitioning in streamflow were not identifiable using δ¹⁸O, but seasonal shifts of nitrate‐corrected EC suggest that deep soil pathways primarily generated summer streamflow (mean EC 250 µS/cm) while shallow soil pathways dominated streamflow generation during winter (EC declining as low as 100 µS/cm). Using summer isotopic and EC excursions from tile drainage in larger catchment (4700‐5700 ha) stream waters, summer in‐stream evaporation fractions were estimated to be from 20% to 40%, with the greatest evaporation occurring from August to October. Seasonal watershed and environmental tracer dynamics in the MFC watershed appeared to be similar to those at larger watershed scales in the Palouse River basin. A 0·9‰ enrichment, in shallow groundwater drained to streams (tile drainage and soil seepage), of δ¹⁸O values from 2000 to 2008 may be evidence of altered precipitation conditions due to the Pacific Decadal Oscillation (PDO) in the Inland Northwest. Copyright © 2009 John Wiley & Sons, Ltd.  相似文献