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1.
Nutrient fluxes from developed catchments are often a significant factor in the declining water quality and ecological functioning in estuaries. Determining the relative contributions of surface water and groundwater discharge to nutrient‐sensitive estuaries is required because these two pathways may be characterized by different nutrient concentrations and temporal variability, and may thus require different remedial actions. Quantifying the volumetric discharge of groundwater, which may occur via diffuse seepage or springs, remains a significant challenge. In this contribution, the total discharge of freshwater, including groundwater, to two small nutrient‐sensitive estuaries in Prince Edward Island (Canada) is assessed using a unique combination of airborne thermal infrared imaging, direct discharge measurements in streams and shoreline springs, and numerical simulation of groundwater flow. The results of the thermal infrared surveys indicate that groundwater discharge occurs at discrete locations (springs) along the shoreline of both estuaries, which can be attributed to the fractured sandstone bedrock aquifer. The discharge measured at a sub‐set of the springs correlates well with the area of the thermal signal attributed to each discharge location and this information was used to determine the total spring discharge to each estuary. Stream discharge is shown to be the largest volumetric contribution of freshwater to both estuaries (83% for Trout River estuary and 78% for McIntyre Creek estuary); however, groundwater discharge is significant at between 13% and 18% of the total discharge. Comparison of the results from catchment‐scale groundwater flow models and the analysis of spring discharge suggest that diffuse seepage to both estuaries comprises only about 25% of the total groundwater discharge. The methods employed in this research provide a useful framework for determining the relative volumetric contributions of surface water and groundwater to small estuaries and the findings are expected to be relevant to other fractured sandstone coastal catchments in Atlantic Canada. Copyright © 2009 John Wiley & Sons, Ltd. 相似文献
2.
Serban Nicolae Vlad 《Central European Journal of Geosciences》2011,3(3):318-335
Romania has a genuine accumulation of “blind” porphyry CuAuMo systems associated with Cu skarns or AuAg (PbZn) epithermal vein sets. Many such hidden structures were discovered inadvertently during state exploration based on local tradition that Romanian Carpathians are rich in vein and skarn ore types. Notable dichotomy between porphyries associated with peripheral skarns versus epithermal ores is expressed by age (Mesozoic versus Tertiary), precious metal content, alteration types and zoning, shape/size and extension of ore bodies. Preliminary conclusions on metallic/alteration assemblages around porphyries in addition to geophysical information about inferred deep-seated Alpine plutonism promote potential exploration vectors for what will be an increasingly important deposit type in the future. 相似文献
3.
Serban & Simina Dragomirescu 《GeoJournal》1993,29(1):31-39
Hydropower developments are of major importance for the national economy and constitute one of the most impressive symbols of modernisation in the mountains of Romania. Development dates back to the turn of the century and comprehensive surveys were carried out during the 1930s; but construction on a sustained basis has occurred only during the postwar period, involving 118 water storages and some 5700 MW of installed power, a quarter of all installed electricpower in the country. The paper provides an outline of the programme, as a contribution to the wider electrification programme, and considers the impact of these developments in the Carpathians where there is much evidence of integrated rural planning to combine electricity generation with forestry and tourism. The prospects for further development in the context of a market economy are considered in the light of both economic and ecological issues.Because of translation problems this paper was written by the editor from notes submitted by the authors. Grateful acknowledgement is made for additional information provided by Dr. Ion Zavoianu 相似文献
4.
Lindsay C. Stringer S. Serban Scrieciu Mark S. Reed 《Applied geography (Sevenoaks, England)》2009,29(1):77-90
This paper considers the role of stakeholder participation in drawing together the three Rio Conventions, exploring how participatory activities to combat desertification in southern Romania can both support and hinder efforts to conserve biodiversity and mitigate the effects of climate change. It suggests that Romania's growing civil society sector has a potentially vital role to play in promoting synergy through participation, and that participatory processes act as an important mechanism for harnessing multiple benefits. The paper argues that participation needs to be further institutionalised within the Romanian context and in doing so, should emphasise empowerment, equity, trust and learning, integrating different knowledge bases to allow the development of sustainable and synergistic environmental solutions. 相似文献
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6.
M.H. Engel J. Rafalska-Bloch C.F. Schiefelbein J.E. Zumberge A. Serban 《Organic Geochemistry》1986,10(4-6)
Amino acids and sugars are principal constituents of marine organisms. The condensation of amino acids and sugars is one possible nonenzymatic, early diagenetic pathway for the incorporation of these compounds into more complex geopolymers. In this study, aqueous solutions consisting of l-lysine, l-histidine, l-arginine and d-(+)-glucose were heated (100°C) for up to 288 h. Portions of the melanoidin polymer isolated after heating were reheated in the presence of water (hydrous pyrolysis) for 72 h at 325°C. Reaction products were identified by GC and GC/MS. Stable isotopic (δ13C) and elemental analyses were used to follow thermal evolution.While the initial melanoidin was synthesized from a simple, four component system, the products generated during hydrous pyrolysis are of considerable complexity, and include straightchain and branched alkanes, alkadienes, alkynes, indole, dimethyl indane, ethyl phenol, quinoline, and xylenes, in addition to a multitude of as yet, unidentified components. Stable carbon isotopic values for the reactants and products correspond to trends observed for naturally generated geopolymers and light gases. Elemental analyses of the melanoidin prior and subsequent to hydrous pyrolysis indicate a kerogen evolution pathway similar to that observed for natural samples. Considering the intractable nature of kerogen, laboratory simulation studies of simple systems can provide an alternative approach for elucidating the origins of geopolymers and their potential for hydrocarbon generation. 相似文献
7.
Marius Visarion Serban Veliciu Mihai StefĂnescu Reviewer V. Čermák 《Studia Geophysica et Geodaetica》1978,22(2):196-200
Summary Using heat flow and heat generation measurements together with deep seismic sounding and gravity data, a reasonable geothermal model has been constructed for the Romanian Carpathian Bend. At the level of the MOHO discontinuity the calculated temperatures exhibit conspicuous differences between inner and outer border of the Carpathian Bend and a horizontal gradient of 200–300 °C/100 km in the region is not to be excluded.Paper presented at the KAPG Symposium on Geothermics in Liblice, November 1976. 相似文献
8.
Baseflow separation is important for obtaining critical parameters for hydrological models. As measuring the baseflow component directly is difficult, various analytical and empirical baseflow separation methods have been developed and tested. The recursive digital filter (RDF) method is commonly used for baseflow separation due to its simplicity and low data requirement. However, parameters used in the RDF method are often determined arbitrarily, resulting in high uncertainty of the estimated baseflow rate. A more accurate method is the conductivity mass balance (CMB) method, which is established based on the differences in physical processes between baseflow and surface runoff. In this research, the output of the CMB method was used to calibrate the parameters of an RDF model, and the calibrated RDF model was used to estimate monthly, seasonal and annual baseflow rate and baseflow index for the past 19 years using streamflow discharge records. The characteristics of the baseflow hydrographs were found to be consistent with the hydrological and hydrogeological conditions of the research area. Research results indicated that the accuracy of the RDF model has been greatly enhanced after being calibrated with the CMB method so that the RDF model can provide more reliable baseflow separation results for a long‐term study. Copyright © 2012 John Wiley & Sons, Ltd. 相似文献
9.
W.D. Robertson D.R. Van Stempvoort J.W. Roy S.J. Brown J. Spoelstra S.L. Schiff D.R. Rudolph S. Danielescu G. Graham 《Ground water》2016,54(4):579-587
The artificial sweetener acesulfame (ACE) is a potentially useful tracer of waste water contamination in groundwater. In this study, ACE concentrations were measured in waste water and impacted groundwater at 12 septic system sites in Ontario, Canada. All samples of septic tank effluent (n = 37) had ACE >6 µg/L, all samples of groundwater from the proximal plume zones (n = 93) had ACE >1 µg/L and, almost all samples from the distal plume zones had ACE >2 µg/L. Mean mass ratios of total inorganic nitrogen/ACE at the 12 sites ranged from 680 to 3500 for the tank and proximal plume samples. At five sites, decreasing ratio values in the distal zones indicated nitrogen attenuation. These ratios were applied to three aquifers in Canada that are nitrate‐stressed and an urban stream where septic systems are present nearby to estimate the amount of waste water nitrate contamination. At the three aquifer locations that are agricultural, low ACE values (<0.02‐0.15 µg/L) indicated that waste water contributed <15% of the nitrate in most samples. In groundwater discharging to the urban stream, much higher ACE values (0.2‐11 µg/L) indicated that waste water was the likely source of >50% of the nitrate in most samples. This study confirms that ACE is a powerful tracer and demonstrates its use as a diagnostic tool for establishing whether waste water is a significant contributor to groundwater contamination or not. 相似文献
10.
In this research the dissolved inorganic nitrogen (DIN) loadings from direct precipitation, stream flow and groundwater discharge to two small estuaries located in Prince Edward Island (PEI), Canada, were quantified over a 2‐year period. The two estuaries, like many around the world, exhibit deteriorating conditions that are believed to be related to excessive nitrogen transport from adjacent catchments. The significance of the groundwater transport pathway and the temporal variability of the loadings have not been previously investigated. The wet fraction of the atmospheric loading was quantified using available precipitation and DIN concentration records. Stream water entering the estuaries and the discharge from numerous shoreline springs, the predominate form of groundwater discharge, were monitored periodically during the study. The annual DIN loads delivered to both estuaries were dominated by streams, although groundwater discharge provided significant contributions of approximately 15–18%. Temporal variability of DIN loading was large, with monthly loads varying by a factor of 5; this variability was found to be primarily related to the variability of freshwater discharge. Concentrations of nitrate in stream water discharging to the estuaries and shoreline groundwater springs were similar in each catchment, suggesting that there was minimal differential attenuation during transport via these two pathways. The McIntyre Creek estuary had one of the highest normalized loads reported in the literature (1700 kg NO3‐N/ha estuary/year), more than four‐fold that of the Trout River estuary, and this result appears to be related to the larger percentage of land area used for potato production in the catchment. This study demonstrates that direct groundwater discharge to estuaries in PEI should not be ignored and that seasonal variations in loading may be important for managing DIN delivery to such estuaries. Copyright © 2010 John Wiley & Sons, Ltd. 相似文献