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1.
硼同位素地球化学应用研究进展 总被引：1，自引：0，他引：1
硼的2个稳定同位素(10 B和11B)间较大的同位素相对质量差导致自然界明显的硼同位素分馏,加上硼易溶于水和活泼的化学性质,使其在不同的地质环境下具有不同的同位素组成.现已查明自然界硼同位素组成(δ11 B)的变化范围为-70‰～+75‰.较负的δ11B值见于非海相蒸发硼酸盐矿物和某些电气石,而较正的δ11 B值见于盐湖卤水和蒸发海水.20世纪80年代以来,随着硼同位素测量方法的建立和改进,硼同位素地球化学研究领域不断拓宽.目前,硼同位素已成功地应用于判别沉积环境、示踪地下水污染、研究矿床成因、示踪海水入侵、重建古海洋与古气候条件和研究大陆化学风化等方面.综合概述了硼同位素的分馏机理、硼同位素在自然界的分布及其硼同位素在地球化学领域研究中取得的成果、最新进展以及研究中存在的问题,以促进硼同位素地球化学研究在我国的进一步发展. 相似文献
2.
不同构造带硅酸盐化学风化率的制约:气候还是构造? 总被引：7，自引：0，他引：7
虽然构造—风化-气候之间的制约关系仍然存在各种争论,但无疑的是,硅酸盐矿物的化学风化是调节地质时间尺度全球大气二氧化碳分压,进而保持地球表层气候稳定的关键性因素。目前最大的挑战在于如何理解地表制约硅酸盐矿物化学风化的因素,特别是当仅仅从气候要素变化难以解释长时间尺度硅酸盐化学风化率的时候。综合不同构造区内岩石物理剥蚀率和硅酸盐化学风化率的数据表明,不同时间、空间尺度硅酸盐风化率与构造和气候之间既存在相互耦合也存在矛盾的关系,仅仅归因于单一要素是不能得到圆满解释的。构造隆升区的强剥蚀可能是造成硅酸盐风化率增加的重要因素之一,但是将晚新生代地表系统的各种变化与各构造带（如青藏高原）的阶段性隆升联系起来可能是草率的。在不同类型构造带内,气候和构造对硅酸盐风化的制约并非是相互排斥的,特别是长时间尺度,因此“构造隆升-化学风化-气候变化”假说也正面临着全新的挑战。 相似文献
3.
Jingbo Zhao Changyan Wang Zhangdong Jin Guizhen Sun Jun Xiao 《Environmental Geology》2009,57(8):1753-1760
Two springs (Cuihua Spring, Shuiqiuchi Spring) in Cuihua Mountain of the Qinling Mountains were observed and sampled monthly
during 2004 and 2005 to trace their physical properties and chemical compositions with seasons. Although both pH values and
cation (Ca2+, Mg2+, K+, and Na+) contents of Cuihua Spring are higher than those of Shuiqiuchi Spring, seasonal variations in both springs are obvious. The
pH values of both spring waters are between 5.69 and 6.98, lower than that of rainwater during summer and autumn. From January
to November, the pH values of both springs similarly vary from high to low and then to high again. Variations in electric
conductivities of two spring waters are contrary, although their electric conductivities are positively correlative with the
cation content respectively. This can be attributed to different water sources of the two springs or different acidic rocks
they passed. The contents of HCO3
−, Ca2+, Mg2+, K+, and Na+ are low, indicating a low silicate weathering that the strata in this district are mainly composed of granite and schist
of quartz and mica. Differing from change in spring water in karst regions of South China where abundant precipitation and
dilution of rainwater cause low pH and electric conductivity in summer and autumn, the seasonal variations in the pH values
and the electric conductivities of two springs in Qinling Mountains are attributed to seasonal changes in CO2 produced by microorganisms’ activity in soil within respective year, rather than rainfall. The microorganisms’ activity in
soil produces more CO2 during summer and autumn. Therefore, the water nature of springs in silicate regions chiefly reflects the seasonal changes
of CO2 produced by the microorganisms in soil. 相似文献
4.
成矿流体对德兴斑岩铜矿床中伊利石结晶度的控制作用 总被引：2，自引：0，他引：2
伊利石广泛存在于铜厂大型斑岩铜矿床内,是特征的热液蚀变矿物,其结晶度和膨胀层含量受携带矿质的热液流体量控制。以浸染状强矿化为特征的斑岩体中上部及接触带附近伊利石结晶程度较好,主要是高水／岩比作用的结果。同时指示出伊利石结晶程度好的部位,矿化品位高,蚀变程度也强。 相似文献
5.
黑碳是不完全燃烧产生的一种难熔的含碳物质的连续统一体,由焦碳(char)和烟炱(soot)组成.岱海与太湖沉积物焦碳和烟炱浓度对比显示,两个湖泊焦碳浓度和通量变化受局地火事件影响,无明显的规律; 而烟炱具有相似的变化历史,主要反映在1970年代后期急剧升高,与中国工业化历史一致.烟炱粒径细小,具区域传输特点,可以通过沉积物指示大气烟炱.结合当前大气气溶胶烟炱浓度,恢复了岱海与太湖地区最近200年来的大气烟炱浓度.其变化趋势与200年来北半球温度对比显示,大气烟炱中的高浓度对应于高温,低浓度对应低温.这种历史关系进一步证实大气烟炱在全球增温中具有极其重要的作用. 相似文献
6.
Zhangdong Jin Hangxin Cheng Li Chen Xiangdong Li Guangwei Zhu Guangmin Zhuang Na Qian 《中国地球化学学报》2010,29(1):33-41
To assess the contamination trends and potential bio-availability of sediment-bound heavy metals, concentrations of heavy
metals in acid-leaching fraction and in bulk sediments from the two typical bays (the Meiliang Bay and Xuhu Bay) of the Taihu
Lake, East China, were studied. Pb and Zn showed elevated concentrations in the sediments from both areas, although sedimentation
history and degree of pollution are different between the two bays. In the Meiliang Bay, both Pb and Zn pollutions started
in the late 1970’s, the same time as the beginning of eutrophication of the lake, while the in the Xuhu Bay the metal contamination
started since recent 10 years. The concentrations of acid-leachable Pb in the sediments from the Meiliang Bay are correlated
with the historical eutrophication process. Before the eutrophication and heavy metal pollution, the chemical properties of
the lake sediments were the same as the source compositions of the Xiashu loess. Both Pb and Zn in the sediments mainly occur
in leachable forms by nitric or hydrochloric acid, whilst most of Cu is in residual fraction. The results indicate that both
Pb and Zn may have higher mobility and bioavailability in water and biology than Cu. 相似文献
7.
Major ion geochemistry of shallow groundwater in the Qinghai Lake catchment, NE Qinghai-Tibet Plateau 总被引：6，自引：2，他引：4
Conventional hydrochemical techniques and statistical analyses were applied to better understand the solute geochemistry and the hydrochemical process of shallow groundwater in the Qinghai Lake catchment. Shallow groundwater in the Qinghai Lake catchment is slightly alkaline, and is characterized by a high ion concentrations and low water temperature. The total dissolved solids (TDS) in most of the samples are <1,000?mg/L, i.e. fresh water and depend mainly on the concentration of SO4 2?, Cl? and Na+. Groundwater table is influenced directly by the residents?? groundwater consumption. Most of the groundwaters in the Qinghai Lake catchment belong to the Ca2+(Na+) ?CHCO3 ? type, while the Qinghai Lake, part of the Buha (BHR) and the Lake Side (LS) samples belong to the Na+?CCl? type. The groundwater is oversaturated with respect to aragonite, calcite and dolomite, but not to magnesite and gypsum. Solutes are mainly derived from strong evaporite dissolution in Daotang, BHR and LS samples and from strong carbonate weathering in Hargai and Shaliu samples. Carbonate weathering is stronger than evaporite dissolution with weak silicate weathering in the Qinghai Lake catchment. Carbonate weathering, ion exchange reaction and precipitation are the major hydrogeochemical processes responsible for the solutes in the groundwater in the Qinghai Lake catchment. Most of the shallow groundwaters are suitable for drinking. More attention should be paid to the potential pollution of nitrate, chloride and sulfide in shallow groundwater in the future. 相似文献
8.
湖泊沉积物中元素相态的连续提取分析—以岱海为例 总被引：7，自引：1，他引：6
如何利用湖泊/海洋沉积物地球化学代用指标有效地指示环境很大程度取决于元素的来源及其在沉积物中赋存形态的确定.对位于半干旱区的内蒙古岱海14个沉积物样品的连续提取实验及18个元素在水可溶态、可交换态、碳酸盐结合态、铁锰氧化物结合态、有机物结合态及残留态等六种赋存相态中含量变化进行了测试和研究,结合沉积物的矿物组成,结果表明在岱海流域内只经历了较弱的化学风化过程,除了Ca和Sr外,其他元素主要赋存于残留态中,只发生了很小程度的活化溶解.受元素亲合性和湖水物理化学状态的制约,出溶的Sr与Ca的赋存相态基本一致,而出溶的Pb、Be、Co、Cu、K、Mn、Fe等元素则与自生碳酸盐、有机质表现出一定的亲合性.元素在不同赋存相态中分布为地球化学环境代用指标的提取和解释提供了机理性的实验依据. 相似文献
9.
10.
Li Weiqiang Zhao Shugao Wang Xiaomin Li Shilei Wang Guoguang Yang Tao Jin Zhangdong 《中国科学:地球科学(英文版)》2020,63(1):108-120
In this study, we performed an integrated investigation of K and Mg isotopes in hydrothermally altered rocks from the giant Dexing porphyry Cu deposit in China. Both the altered porphyry intrusion and the surrounding wall rocks exhibit large variations in K and Mg isotope compositions, with δ41K values ranging between-1.02‰ and 0.38‰, and δ26Mg values ranging between-0.49‰ and 0.32‰. The δ41K and δ26Mg values of the majority of altered samples are higher than the isotopic baseline values for upper continental crust. We attribute the general increase in δ41 K and δ26Mg in altered rocks to hydrothermal alteration,which caused preferential incorporation of heavy K and Mg isotopes in alteration products, particularly phyllosilicates. However,a few altered samples show anomalously low δ41K and δ26Mg values. The δ41K and δ26Mg values do not correlate with K and Mg concentrations, or mineralogy of altered samples. The variable K-Mg isotope data likely reflect fluids of different physicalchemical properties, or different isotopic compositions. Based on the combined K-Mg isotope data, at least three groups of hydrothermal fluids are distinguished from the Dexing porphyry deposit. Therefore, K-Mg isotopes are potentially a novel tracer for fingerprinting fluids in complex hydrothermal systems. 相似文献