Studies on Intercorrelation between Ions Co-Occurring in Precipitation in the Gdańsk-Sopot-Gdynia Tricity (Poland)     

Żaneta Polkowska  Aleksander Astel  Marzena Grynkiewicz  Tadeusz Górecki  Jacek Namieśnik 《Journal of Atmospheric Chemistry》2002,41(3):239-264

The paper presents monitoring results and environmental pollution assessment for the Gdask-Sopot-Gdynia Tricity (Poland), based onanalysis of precipitation. Precipitation samples were collected over a period of 12 months (January–December 1998) at ten locations in the Tricity. The following selected ions were determined in the samples:SO₄ ^2–, F^–, Cl^–, NO₃ ^–,PO₄ ^3–, NH₄ ⁺, Na⁺,Mg²⁺, Ca²⁺, K⁺. The results were subjected to full statistical evaluation. Values of the parameters determined were correlated with each other. An attempt was made to explain co-occurrences of certain ions and the significance of their mutual effects. Pollutant concentrations and loads in precipitation were also correlated with data on wind direction and temperature in the region.Deposition of pollutants was very high in spring due to the prevailing air circulation patterns and low temperatures. Analysis of the correlations between co-occurring ions confirmed the significant impact of the location (sea coast) on the composition of rain water. Ionic ratios in rainwater were similar to those observed for sea salt samples. In addition, heavy traffic was most probably responsible for high concentrations of various forms of nitrogen and sulphates in the vicinity of major highways.  相似文献   

A multi-proxy approach for revealing recent climatic changes in the Russian Altai   总被引：2，自引：0，他引：2  

Olga V. Sidorova  Matthias Saurer  Vladimir S. Myglan  Anja Eichler  Margit Schwikowski  Aleksander V. Kirdyanov  Marina V. Bryukhanova  Oksana V. Gerasimova  Ivan A. Kalugin  Andrey V. Daryin  Rolf T. W. Siegwolf 《Climate Dynamics》2012,38(1-2):175-188

For the first time we present a multi-proxy data set for the Russian Altai, consisting of Siberian larch tree-ring width (TRW), latewood density (MXD), δ¹³C and δ¹⁸O in cellulose chronologies obtained for the period 1779–2007 and cell wall thickness (CWT) for 1900–2008. All of these parameters agree well between each other in the high-frequency variability, while the low-frequency climate information shows systematic differences. The correlation analysis with temperature and precipitation data from the closest weather station and gridded data revealed that annual TRW, MXD, CWT, and δ¹³C data contain a strong summer temperature signal, while δ¹⁸O in cellulose represents a mixed summer and winter temperature and precipitation signal. The temperature and precipitation reconstructions from the Belukha ice core and Teletskoe lake sediments were used to investigate the correspondence of different independent proxies. Low frequency patterns in TRW and δ¹³C chronologies are consistent with temperature reconstructions from nearby Belukha ice core and Teletskoe lake sediments showing a pronounced warming trend in the last century. Their combination could be used for the regional temperature reconstruction. The long-term δ¹⁸O trend agrees with the precipitation reconstruction from the Teletskoe lake sediment indicating more humid conditions during the twentieth century. Therefore, these two proxies could be combined for the precipitation reconstruction.  相似文献   

Robotic optical telescopes global network MASTER II. Equipment, structure, algorithms     

Victor G. Kornilov  Vladimir M. Lipunov  Evgeny S. Gorbovskoy  Aleksander A. Belinski  Dmitry A. Kuvshinov  Natalia V. Tyurina  Nikolai I. Shatsky  Anatoly V. Sankovich  Aleksander V. Krylov  Pavel V. Balanutsa  Vadim V. Chazov  Artem S. Kuznetsov  Dmitry S. Zimnuhov  Victor A. Senik  Andrey G. Tlatov  Aleksander V. Parkhomenko  Denis V. Dormidontov  Vadim V. Krushinsky  Ivan S. Zalozhnyh  Aleksander A. Popov  Sergey A. Yazev  Nikolai M. Budnev  Kirill I. Ivanov  Evgeny N. Konstantinov  Oleg A. Gress  Oleg V. Chvalaev  Vladimir V. Yurkov  Yury P. Sergienko  Irina P. Kudelina 《Experimental Astronomy》2012,33(1):173-196

Presented paper describes the basic principles and features of the implementation of a robotic network of optical telescopes MASTER, designed to study the prompt (simultaneous with gamma radiation) optical emission of gamma-ray bursts and to perform the sky survey to detect unknown objects and transient phenomena. With joint efforts of Sternberg astronomical institute, High altitude astronomical station of the Pulkovo observatory, Ural state university, Irkutsk state university, Blagoveshchensk pedagogical university, the robotic telescopes MASTER?II near Kislovodsk, Yekaterinburg, Irkutsk and Blagoveshchensk were installed and tested. The network spread over the longitudes is greater than 6?h. A further expansion of the network is considered.  相似文献   

Variability of aerosol properties during the 2007–2010 spring seasons over central Europe     

Aleksander Pietruczuk  Anatoli Chaikovsky 《Acta Geophysica》2012,60(5):1338-1358

Aerosol optical properties have been studied for spring seasons when increased values of PM10 are registered. Measurements of aerosol optical properties were taken by collocated lidar and sun-photometers at Belsk, Poland, and Minsk, Belarus. A significant increase of registered aerosol optical thickness (AOT) was found during episodes with elevated PM10 concentrations. An increase of AOT at 1020 nm amounted to 50% in the case of Minsk and 18% in the case of Belsk, while an increase of AOT at 400 nm was 66% and 33%, respectively. We noted an increase of Ångström exponent by 6% at both stations and no significant increase of single scattering albedo. The LIDAR measurements together with NAAPS model results and backtrajectory analysis suggest that both the biomass burning products and the Saharan dust are responsible for increased PM10 concentrations and large AOT values during spring time. The smoke aerosol is transported over Central Europe mainly in the boundary layer, increasing both PM10 concentration and AOT. The dust aerosol transported in the free troposphere slightly affects the AOT values only. Statistically significant correlation between PM10 concentration and AOT was found during reporting period.  相似文献   

Atmospheric and Surface Water Pollution Interpretation in the Gdańsk Beltway Impact Range by the Use of Multivariate Analysis     

Aleksandra Dubiella‐Jackowska  Aleksander Astel  aneta Polkowska  Wojciech Staszek  B&#x;aej Kud&#x;ak  Jacek Namienik 《洁净——土壤、空气、水》2010,38(9):865-876

The present study deals with the application of the hierarchical cluster analysis and non‐parametric tests in order to interpret the Gdańsk Beltway impact range. The data set represents concentration values for major inorganic ions (Na⁺, NH, K⁺, Mg²⁺, Ca²⁺, F⁻, Cl⁻, NO, and SO) as well as electrolytic conductivity and pH measured in various water samples [precipitation, throughfall water, road runoff, and surface water (drainage ditches, surface water reservoirs, and spring water)] collected in the vicinity of the beltway. Several similarity groups were discovered both in the objects and in the variables modes according to the water sample. In the majority of cases clear anthropogenic (fertilizers usage and transport, road salting in winter) and semi‐natural (sea salt aerosols, erosion of construction materials) impacts were discovered. Spatial variation was discovered for road runoff samples and samples collected from surface water reservoirs and springs. Surprisingly no clear seasonal variability was discovered for precipitation chemistry, while some evidences for existing of summer and winter specific chemical profile was discovered for road runoff samples. In general, limited range of the Gdańsk Beltway impact was proven.  相似文献   

Amplitude curves ofP waves for the region of central Asia     

Jiří Vaněk  Aleksander Tskhakaya  Reviewer J. Janský 《Studia Geophysica et Geodaetica》1977,21(3-4):259-267

Summary The amplitude-distance curves of P waves, valid for the region of Central Asia, were derived in the distance range between 13° and 36° using observations of a network of eight Caucasian seismic stations. The curves are characterized by an anomalous increase of amplitudes between 13° and 20° followed by a large decrease of amplitudes in the distance range between 20° and 35°. Both the increase and decrease of amplitudes are interrupted by several local maxima. A comparison of the present amplitude curves with those derived for the regions of South-Eastern Europe and Asia Minor enabled us to correlate the individual local maxima of amplitude curves and to investigate the variation of their position due to the lateral inhomogeneity of the upper mantle structure in Eurasia.A. Tskhakaya deceased in 1970.  相似文献   

Organic carbon and sulphur compounds in wetland soils: insights on structure and transformation processes using K-edge XANES and NMR spectroscopy     

Aleksander Jokic  Elena Ponomarenko  Darwin W Anderson 《Geochimica et cosmochimica acta》2003,67(14):2585-2597

X-ray absorption near-edge structure (XANES) and nuclear magnetic resonance (NMR) spectroscopy were used in combination to characterize organic carbon structures in a series of wetland soils in Saskatchewan, and XANES spectroscopy was also used to examine sulphur speciation in the soils. The organic C contents of most of the wetland soils are consistently higher by a factor of two to five times compared to adjacent well-drained soils. NMR analyses indicate that the organic matter in the wetland soils consists of predominantly aliphatic structures such as carbohydrates and long chain poly(methylene) units which are refractory structures found in plant waxes. The poly(methylene) structures have a significant capacity to sorb nonpolar organic molecules. The phenolic OH and carboxyl group content of the wetland soils studied is an additional significant factor in their sequestering ability for heavy metals or pesticides. Carbon XANES spectroscopy shows that the surface (∼10 nm) layer of particulate organic matter has a structure dominated by aromatic, carbohydrate and carboxylic acid-like material apparently derived from partially degraded lignin and cellulose polymers which are adsorbed onto clay minerals. The aliphatic structures remaining in this surface layer are probably recalcitrant (poly)methylene units. At a depth of ∼100 nm, the aliphatic content significantly increases suggesting the presence of more labile structures. The presence of these more labile aliphatic compounds may be due to slow decomposition rates in the wet, often cool environments present and to the protective action of the more refractory components in the surface ∼10 nm of the organic matter. Drying of the wetlands, either by draining or as a result of climate change, is likely to result in the rapid decomposition of these labile organic structures releasing carbon dioxide. Our data indicate that the preservation of the organic carbon compounds in these soils is a result of their presence as surface adsorbed layers on the soil mineral particles. The soils contain three different classes of sulphur compounds: reduced organic sulphur such as sulphides, low valent oxidized sulphur such as sulphoxides, and high valent oxidized sulphur such as sulphonate and sulphate. Of these, reduced sulphur species constitute between one-third and two-thirds of the total. Sulphonate structures comprise between a fifth and a third of the total. Sulphates exhibit a wide variation in content, and sulphoxides are either not detected or are present to a lesser extent (<5%). Drying of the wetlands would cause oxidation of sulphides to sulphates.  相似文献   

Structure and chemistry of (111) twin boundaries in MgAl<Subscript>2</Subscript>O<Subscript>4</Subscript> spinel crystals from Mogok     

Nina Daneu  Aleksander Rečnik  Takashi Yamazaki  Tadej Dolenec 《Physics and Chemistry of Minerals》2007,34(4):233-247

The atomic scale structure and chemistry of (111) twins in MgAl₂O₄ spinel crystals from the Pinpyit locality near Mogok (Myanmar, formerly Burma) were analysed using complementary methods of transmission electron microscopy (TEM). To obtain a three-dimensional information on the atomic structure, the twin boundaries were investigated in crystallographic projections and Using conventional electron diffraction and high-resolution TEM (HRTEM) analysis we have shown that (111) twins in spinel can be crystallographically described by 180° rotation of the oxygen sublattice normal to the twin composition plane. This operation generates a local hcp stacking in otherwise ccp lattice and maintains a regular sequence of kagome and mixed layers. In addition to rotation, no other translations are present in (111) twins in these spinel crystals. Chemical analysis of the twin boundary was performed by energy-dispersive X-ray spectroscopy (EDS) using a variable beam diameter (VBD) technique, which is perfectly suited for analysing chemical composition of twin boundaries on a sub-nm scale. The VBD/EDS measurements indicated that (111) twin boundary in spinel is Mg-deficient. Quantitative analyses of HRTEM (phase contrast) and HAADF-STEM (Z-contrast) images of (111) twin boundary have confirmed that Mg²⁺ ions are replaced with Be²⁺ ions in boundary tetrahedral sites. The Be-rich twin boundary structure is closely related to BeAl₂O₄ (chrysoberyl) and BeMg₃Al₈O₁₆ (taaffeite) group of intermediate polysomatic minerals. Based on these results, we conclude that the formation of (111) twins in spinel is a preparatory stage of polytype/polysome formation (taaffeite) and is a result of thermodynamically favourable formation of hcp stacking due to Be incorporation on the {111} planes of the spinel structure in the nucleation stage of crystal growth. The twin structure grows as long as the surrounding geochemical conditions allow its formation. The incorporation of Be induces a 2D-anisotropy and exaggerated growth of the crystal along the (111) twin boundary.  相似文献   

Biomass Size Spectra of Near-Shore Shallow-Water Benthic Communities in the Gulf of Gdańsk Southern Baltic Sea     

Aleksander  Drgas  Teresa  Radziejewska Jan  Warzocha 《Marine Ecology》1998,19(3):209-228

The concept of size spectra, developed by S heldon & P arsons 1967 and S heldon et al. 1972, seeks to describe community structure by evoking the distribution of biomass over a sequence of equal intervals of the logarithm of body size. In this study, biomass size spectra were prepared for benthic macro- and meiobenthos communities at 5 stations, differing in their sediment characteristics, located in the shallow, coastal area of the Gulf of Gdańsk Southern Baltic Sea. The purpose of this study was to determine whether the community spectra would allow distinct separation of ecological categories of the benthos and whether habitat differences between stations would significantly affect benthic size spectra.
Benthic biomass at the stations sampled depended mainly on nematodes and oligochaetes among the meiobenthos and on hydrobiid snails and M. edulis among the macrobenthos. Regardless of habitat, size spectra peaked initially at the meiofaunal range weight class 25 1. 19–501.19 ng C, identical to that reported in other studies. The separation between meio- and macrobenthic peaks, however, was not as pronounced as that found in other studies. Normalized size spectra demonstrated that most of the variations in the spectra between stations was introduced by macrobenthos, which differed between the coarse- and fine-grained sediments. Nonetheless, those differences were not strong enough to significantly affect the spectra. In consequence, the benthic biomass spectra of all the stations were found to conform to a common pattern and could be represented by a single, average spectrum.  相似文献   

Correction to: Zeolite containing rocks of kudurs and reasons of geophagy within the territory of Sikhote-Alin Nature Zapovednik,Far East of Russia     

Panichev  Aleksander  Seryodkin  Ivan  Popov  Vladimir  Chekryzhov  Igor  Makarevich  Raisa  Lutsenko  Tatiana  Stolyarova  Tatiana  Sergievich  Aleksander  Khoroshikh  Pavel  Maksimova  Darya  Petrunenko  Yury 《Arabian Journal of Geosciences》2020,13(4):1-11

This paper establishes a mechanical model of the stress distribution in front of the driving face during coal roadway excavation. Theoretical research shows that the stress state in the plastic zone of the driving face is consistent with the limit equilibrium equation, and the elastic zone is in accordance with the equilibrium equation based on elasticity mechanics. Based on this improved mechanical state solution model, different coal material constitutive hypotheses are used for the analysis. The width of the plastic zone calculated under the brittle-perfectly elastic model can reach 2–5 times the height of the roadway, and the stress concentration coefficient can reach two or more times. 3DEC numerical simulation software was used to simulate the stress distribution of the heading face. The results of the simulation are similar to those of the theoretical analysis. Compared with the elastic-perfectly plastic model, the calculated results of the brittle-perfectly elastic model are more consistent with the numerical simulation results. The heading face coal during roadway excavation shows obvious damage, and the strength characteristics of the coal decrease.  相似文献