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M. A. Amani A. M. Latifi K. Tahvildari R. Karimian 《International Journal of Environmental Science and Technology》2018,15(6):1301-1312
In this research, ordered mesoporous silica, including MCM-41, was synthesized via sol–gel process and a propyl methacrylate-modified ordered mesoporous silica (MPS-MCM-41) was successfully synthesized via a postsynthesis grafting process. Then both MCM-41 and MPS-MCM-41 were characterized using FTIR, XRD, SEM and BET techniques. The synthesized materials were utilized as adsorbent for removal of diazinon pesticide from aqueous solutions. The effects of pH, contact time, adsorbent dose, initial concentration and temperature have been evaluated using removal efficiencies. Also, the kinetic, thermodynamic and isotherm models of diazinon adsorption were studied for the both MCM-41 and MPS-MCM-41. The results showed that the maximum adsorption capacities are 142 and 254 mg g?1 for the MCM-41 and MPS-MCM-41, respectively, at the initial concentration of 50 mg L?1, temperature of 298 K and adsorbent dose of 0.1 g L?1. The highest percentages of diazinon removal are 56.4 and 87.2 (at adsorbent dose of 2 g L?1 and the temperature of 318 K) for the MCM-41 and MPS-MCM-41, respectively. The Freundlich and Langmuir models are more compatible for describing equilibrium data of the diazinon adsorption capacity on the MCM-41 and MPS-MCM-41, respectively. Thermodynamic study indicated that the adsorption process of diazinon onto MCM-41 and MPS-MCM-41 is exothermic and has a spontaneous nature. The higher adsorption capacity and higher spontaneous nature of MPS-MCM-41 in comparison with MCM-41 might be due to the presence of the both hydrogen bonding and hydrophobic interaction between surface functional groups of MPS-MCM-41 (hydroxyl and propyl methacrylate) and diazinon functional groups. 相似文献
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Abstract Statistical analysis of extremes is often used for predicting the higher return-period events. In this paper, the trimmed L-moments with one smallest value trimmed—TL-moments (1,0)—are introduced as an alternative way to estimate floods for high return periods. The TL-moments (1,0) have an ability to reduce the undesirable influence that a small value in the statistical sample might have on a large return period. The main objective of this study is to derive the TL-moments (1,0) for the generalized Pareto (GPA) distribution. The performance of the TL-moments (1,0) was compared with L-moments through Monte Carlo simulation based on the streamflow data of northern Peninsular Malaysia. The result shows that, for some cases, the use of TL-moments (1,0) is a better option as compared to L-moments in modelling those series. Citation Ahmad, U.N., Shabri, A. & Zakaria, Z.A. (2011) Trimmed L-moments (1,0) for the generalized Pareto distribution. Hydrol.Sci. J. 56(6), 1053–1060. 相似文献
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Yeqiao Wang Gregory Bonynge Jarunee Nugranad Michael Traber Amani Ngusaru James Tobey Lynne Hale Robert Bowen Vedast Makota 《Marine Geodesy》2003,26(1):35-48
This article contributes to the understanding of the changes in distribution and total area of mangrove forests along the mainland Tanzania coast over the past decade. Mangroves are recognized as critical coastal habitat requiring protection and special attention. The Tanzania coastline forms a suitable habitat for establishment of mangrove forests. Mangrove forests are distributed from Tanga in the north to Mtwara in the south covering approximately 109,593 hectares from 1988-1990 and about 108,138 hectares in 2000. The largest continuous mangrove stands are found in the districts of Rufiji, Kilwa, Tanga-Muheza, and Mtwara. Comparison of data between these two time periods shows that the geographic coverage of mangroves has no dramatic change in the past decade. The Tanzania Mangrove Management Project and other closely related programs and efforts pertaining to mangrove conservation contribute to direct restoration and natural regeneration of mangroves. This study documents the changes of mangroves and demonstrates that remote sensing and GIS offer important data and tools in the advancement of coastal resource management and ecosystem monitoring. Application of geographic information technologies is critical for improved coastal resources management and decision making for sustainable development in Tanzania. 相似文献
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Relationship between point rainfall, average sampled rainfall and ground truth at the event scale in the Sahel 总被引：1，自引：0，他引：1
Geostatistical techniques are used to quantify the reference mean areal rainfall (ground truth) from sparse raingaugenetworks.
Based on the EPSAT-Niger event cumulative rainfall, a linear relationship between the ground truth considered as the mean
area rainfall estimated from the densely available raingauge network and the area rainfall estimated from sparse network are
derived. Also, a linear relationship between the ground truth and point rainfall is established. As it was reported experimentally
by some authors, the slope of these relationships is less than one. Based on the geostatistical framework, the slope and the
ordinate at the origin can be estimated as a function of the spatial structure of the rainfall process. It is shown that the
slope is smaller than one. For the special case of one gauge inside a fixed area or a Field Of View (FOV), an areal reduction
factor is derived. It has a limit value which depends only on the size of the area and the spatial structure of the rainfall
process. The relative variance error of estimating the FOV cumulative rainfall from point rainfall is also given. 相似文献
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An approach based on regional frequency analysis using L moments and LH moments are revisited in this study. Subsequently, an alternative regional frequency analysis using the partial L moments (PL moments) method is employed, and a new relationship for homogeneity analysis is developed. The results were then compared with those obtained using the method of L moments and LH moments of order two. The Selangor catchment, consisting of 37 sites and located on the west coast of Peninsular Malaysia, is chosen as a case study. PL moments for the generalized extreme value (GEV), generalized logistic (GLO), and generalized Pareto distributions were derived and used to develop the regional frequency analysis procedure. PL moment ratio diagram and Z test were employed in determining the best-fit distribution. Comparison between the three approaches showed that GLO and GEV distributions were identified as the suitable distributions for representing the statistical properties of extreme rainfall in Selangor. Monte Carlo simulation used for performance evaluation shows that the method of PL moments would outperform L and LH moments methods for estimation of large return period events. 相似文献
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In this paper, we investigate Bianchi type-VI cosmological model for the universe filled with dark energy and viscous fluid in the presence of cosmological constant. Also, we show accelerating expansion of the universe by drawing volume scale, pressure and energy density versus cosmic time. In order to solve the Einstein’s field equations, we assume the expansion scalar is proportional to a component of the shear tensor. Therefore, we obtain the directional scale factors and show the EOS parameter crosses over phantom divided-line. 相似文献
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Human effects and environment impacts associated with nanoparticles generated from road traffic have recently attracted wide attention.Knowledge of the influencing variables on both number and mass of nanoparticles,sources,characteristics and limitations of advanced commercially accessible instruments for monitoring nanoparticles,are still scarce and not sufficient to make regulatory decision on solid particles smaller than 23 nm(SPN<23 nm).Given the harmful effects of nanoparticles on human health(i.e.visibility impairment,cardiac-rhythm disturbance,heart attacks,premature death,etc.),their control and assessment seem to be an absolute priority.In this overview,we classify and analyze the existing knowledge of nanoparticles in road traffic atmosphere,recent progress,and emerging priorities in research related to these topics.The major aspects of ongoing research in this field,and a brief discussion of the main sources of atmosphere nanoparticles are presented.The subsequent section focuses on the influencing parameters of nanoparticles including climate conditions,height above the road surface and distance between source(road traffic)and sampling site.The next section provides a comprehensive summary on sampling measurement methodologies and instrumental techniques.We also review the health and environment implications associated with particle exposure.Finally,an evaluation of the state of research related to nanoparticles together with highlights for future research activities are also presented. 相似文献
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