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1.
Granulitized coesite-bearing eclogite from Weihai, northeastern part of the Shandong peninsula, eastern China was studied in detail to reveal the modification of mineral chemistry during decompression metamorphism. Considerable modification of chemical composition is recorded in clinopyroxene that occurs both as inclusions in garnet and as a matrix mineral. Careful examination of chemical variation with the change in microstructure made it possible to estimate the equilibrium composition of minerals at the coesite eclogite and garnet granulite stages. We were able to define three reference points on the P–T path, namely, coesite eclogite (3 GPa, 660±40°C), granulite (1 GPa, 700±30°C) and amphibolite (0.9 GPa, 600±20°C). The path thus obtained is similar to those obtained by previous workers and supports nearly isothermal decompression of coesite eclogite. 相似文献
2.
山东海阳所麻粒岩向过渡榴辉岩转化的变质动力学过程及其构造意义 总被引：8，自引：3，他引：5
在山东半岛东南端的乳山海阳所,角闪岩和长英质片麻岩呈互层产出.在某些角闪岩层的中心残留有弱变形的麻粒岩和强变形的过渡榴辉岩(斜长石榴辉岩)团块.在弱变形的麻粒岩团块中发育有窄的(<1cm)剪切条带.沿着这些剪切条带和在强变形过渡榴辉岩团块中,原麻粒岩被转化为含斜长石的过渡榴辉岩.变形和流体在这一转化过程中加速了元素扩散和迁移的速度,在变形强和有流体加入的部位麻粒岩向榴辉岩转化的程度明显增强.麻粒岩相矿物组合(Cpx-Ⅰ+Opx+Pl-Ⅰ+ Hbl-Ⅰ + Grt-Ⅰ+ Ilm)及其花岗变晶结构被完好地保存于弱变形的麻粒岩中,其矿物成分显示出0.8～0.9 GPa和780℃～830℃的麻粒岩相变质条件.榴辉岩相叠加在麻粒岩中形成了一系列的环边状矿物和结构:环边状石榴石(Grt-Ⅱ)形成于麻粒岩相斜长石(Pl-Ⅰ)和暗色矿物(如Cpx-Ⅰ、Opx和Hbl-Ⅰ)的交界处,细粒石榴石(Grt-Ⅱ)、富钠单斜辉石(Cpx-Ⅱ)和石英形成于麻粒岩相角闪石(Hbl-Ⅰ)的外缘.同时榴辉岩相叠加造成麻粒岩相单斜辉石边缘钙契尔马克组份的降低和硬玉组份的升高.但在弱变形的麻粒岩中,麻粒岩相单斜辉石(Cpx-Ⅰ)的外缘并无榴辉岩相单斜辉石形成.沿着弱变形麻粒岩中的剪切条带和在过渡榴辉岩中,榴辉岩相矿物[Grt-Ⅱ+ Omp/Di(Cpx-Ⅱ)+ Ab(Pl-Ⅱ)+ Qtz + Hbl-Ⅱ+ Ky + Zo + Rut]广泛发育,它们的定向排列形成了明显的面理.其形成的温压条件为1.0～1.4 GPa和560℃～680℃,为过渡榴辉岩相变质.虽然其中仍然残留有被拉长的麻粒岩相单斜辉石,但它们含有很高的硬玉组份,且其外缘环绕有细粒的钠质透辉石或绿辉石(Cpx-Ⅱ).海阳所榴辉岩相变质的温压条件远远低于位于海阳所东南和东北的苏鲁超高压变质带中柯石英榴辉岩变质的温压条件.因此海阳所地区代表一条不同于超高压变质带的冷榴辉岩带,它可能与大别山南部的冷榴辉岩带相当.苏鲁超高压变质带的南部边界位于海阳所以北. 相似文献
3.
Ultrahigh-pressure garnet lherzolite from Chijiadian, Rongcheng County, in the Su-Lu region of eastern China 总被引：3，自引：0，他引：3
Abstract Petrological studies of a serpentinized garnet lherzolite body in Rongcheng of the Su-Lu region of eastern China revealed unusually high pressure. Spinel lherzolite probably in a subducting slab was transformed to garnet lherzolite at mantle depth. During exhumation, they were subsequently subjected to the granulite and then amphibolite overprinting and a phase of serpentinization. The peak P–T conditions of the garnet lherzolite estimated after detailed analysis of the metamorphic texture are 4–5 GPa and 820°C or 5–6 GPa and 780°C, depending on the chosen geothermobarometers. The lower dP/dT of the garnet lherzolite can be interpreted as the results of subduction of an old (say 100 Ma older than the time of collision) and cold, slab underneath the margin of the Sino–Korean craton. 相似文献
4.
Summary Basic and pelitic schists of the garnet and biotite zones in the Sanbagawa belt in Shikoku, Japan, commonly contain phengite developed at different stages of metamorphism. Textures of the phengite and associated minerals show that Al-rich phengite is a prograde product and Al-poor phengite is a retrograde product.
With 5 Figures
On leave from the Geological Survey of Slovakia, Spissa, Spisska, Nova Ves, Slovakia 相似文献
Mehrfache Stadien der Phengit-Bildung in den Sanbagawa-Schiefern
Zusammenfassung Basische und pelitische Schiefer der Granat- und Biotitzonen im Sanbagawa Gürtel in Shikoku, Japan, führen Phengite, die während verschiedener Stadien der Metamorphose entstanden sind. Texturen der Phengite und assoziierter Minerale zeigen, daß Al-reicher Phengit das Produkt prograder Metamorphose ist, während Al-armer Phengit auf retrograde Metamorphose zurückgeht.
With 5 Figures
On leave from the Geological Survey of Slovakia, Spissa, Spisska, Nova Ves, Slovakia 相似文献
5.
Two types of biotite isograd are defined in the low-grade metamorphism of the Wazuka area, a Ryoke metamorphic terrain in the Kii Peninsula, Japan. The first, BI1, is defined by the reaction of chlorite+K-feldspar= biotite+muscovite+quartz+H2O that took place in psammitic rocks, and the second, BI2, by the continuous reaction between muscovite, chlorite, biotite and quartz in pelitic rocks. The Fe/Mg ratios of the host rocks do not significantly affect the reactions. From the paragenesis of pelitic and psammitic metamorphic rocks, the following mineral zones were established for this low-pressure regional metamorphic terrain: chlorite, transitional, chlorite-biotite, biotite, and sillimanite. The celadonite content of muscovite solid solution in pelitic rocks decreases systematically with the grade of metamorphism from 38% in the chlorite zone to 11% in the biotite zone. Low pressure does not prohibit muscovite from showing the progressive change of composition, if only rocks with appropriate paragenesis are chosen. A qualitative phase diagram of the AKF system relevant to biotite formation suggests that the higher the pressure of metamorphism, the higher the celadonite content of muscovite at BI1, which is confirmed by comparing the muscovites from the Barrovian and Ryoke metamorphism. 相似文献
6.
A garnet-omphacite-kyanite-coesite geothermobarometer is constructed to estimate the peak metamorphic pressure of ultrahigh-pressure
(UHP) eclogites. For this we use a quaternary regular solution model for garnet, and propose a new model for sodic pyroxene
that assumes double site solid-solution (Na,Ca)M2(Al,Fe3+,Fe2+,Mg)M1Si2O6, where cations in the M2- and the M1-sites mix randomly but with inter-site interactions, not only between nearest neighboring
cations but also between next nearest neighboring cations. In the new model, overall excess interaction parameters are quantitatively
deduced from the previous experimental data and critical temperature, and the activity of the jadeite component agrees reasonably
with that based on the Landau theory. Furthermore, the relations of the calculated order parameter to temperature and composition
are consistent with other experimental works. These facts support the usefulness of the new model. Application of our geothermobarometer
to kyanite eclogite gave metamorphic conditions around 3.4 GPa and 800 ∘C for both samples from the Dora Maira Massif, Western Alps, and from Rongcheng County, in the Su-Lu region of eastern China.
Received: 30 December 1996 / Accepted: 25 August 1997 相似文献
7.
Tsuyoshi Morohashi Shohei Banno Masao Yamasaki 《Contributions to Mineralogy and Petrology》1974,47(3):187-196
Single whole crystals of calcic augite from M. Etna, Sicily, which display both sector and oscillatory zoning, have been serially sectioned and the form of the sectors mapped out. The principal intersectorial chemical variation is shown to be that of Ti and Al by as much as 39% (cation %) change in each, and the least variation, that of Ca (showing a 0.77 to 3.20% change). For each of three isochronous surfaces the ratio of Ti∶Al is shown to be individually constant no matter what the sector and this is thought to indicate near equilibrium conditions at the crystal/liquid interface. In addition to sector zoning these crystals display two types of concentric banding, having dimensions of about 0.25 mm, 20 μm. The 20 μm banding is shown to be both optically and chemically oscillated. Relative diffusion rates of cationic species in the melt, and growth rates of crystal faces are thought to play an important role in the formation of the oscillations, and the sector zoning. 相似文献
8.
Garnet-orthopyroxene and orthopyroxene-clinopyroxene relationships in simple and complex systems 总被引：10，自引：2，他引：10
Use of simple mixing models of orthopyroxene and garnet solid solutions enables extrapolation of experimentally determined equilibria in the MgSiO3-Al2O3 system to uninvestigated parts of pressure-temperature-composition space. Apparent discrepancies in the experimental data for simple and multicomponent systems may be explained by considering the effect of CaO and FeO on reducing pyrope activity in the garnet solid solutions. Equilibration pressures of natural garnet-orthopyroxene assemblages may be calculated, provided temperatures are known, from a combination of the experimental data on the MgSiO3-Al2O3 system and analyses of coexisting natural phases.Despite the presence of a compositional gap in the system, the solubility of enstatite in diopside coexisting with orthopyroxene can also be approximately treated by an ideal solution model. An empirical approach has been developed to take account of Fe2+ on the orthopyroxene-clinopyroxene miscibility gap in natural systems in order to calculate equilibration temperatures of 2-pyroxene assemblages. The model presented reproduces almost all of the available experimental data for multicomponent systems to within 60° C. 相似文献
9.
In pelitic schists of the Sanbagawa metamorphic belt, sphene, rutile, and ilmenite occur as discrete grains, in composite aggregates, and as inclusions in garnets. Textural relationships, disposition of inclusions in garnet, and the compositions of ilmenites suggest that the titanium-bearing accessories stable at the peak metamorphic conditions were as follows: sphene in the chlorite zone, sphene plus rutile in the garnet zone, and ilmenite in the highest grade of the belt, the biotite zone. Rutile appears in the garnet zone as a consequence of Ca incorporation into garnet and a progressive increase in
.Retrograde reactions were responsible for the composite aggregates of rutile, sphene and ilmenite and these must be carefully evaluated before prograde relationships between titanium-bearing accessories can be properly understood. 相似文献
10.
Masaki Enami Simon R. Wallis Yasuyuki Banno 《Contributions to Mineralogy and Petrology》1994,116(1-2):182-198
Sodic pyroxene (jadeite content X
jd=0.1–0.3) occurs locally as small inclusions within, albite porphyroblasts and in the matrix of hematite-bearing quartz schists in the Sanbagawa (Sambagawa) metamorphic belt, central Shikoku, Japan. The sodic, pyroxene-bearing samples are characteristically free from chlorite and their typical mineral assemblage is sodic pyroxene+subcalcic (or sodic) amphibole+phengitic mica+albite+quartz+hematite+titanite±epidote. Spessartine-rich garnet occurs in Mn-rich samples. Sodic pyroxene in epidote-bearing samples tends to be poorer in acmite content (average X
Acm=0.26–0.50) than that in the epidote-free samples (X
Acm=0.45–0.47). X
Jd shows no systematic relationship to metamorphic grade, and is different among the three sampling regions [Saruta-gawa, Asemi-gawa and Bessi (Besshi)]. The average X
Jd of the Saruta-gawa samples (0.21–0.29) is higher than that of the Asemi-gawa (0.13–0.17) and Bessi (0.14–0.23). The P-T conditions of the Asemi-gawa and Bessi regions are estimated at 5.5–6.5 kbar, >360°C in the chlorite zone, 7–8.5 kbar, 440±15°C in the garnet zone and 8–9.5 kbar, 520±25°C in the albite-biotite zone. Metamorphic pressure of the Saruta-gawa region is systematically 1–1.5 kbar higher than that of the Asemi-gawa and Bessi regions, and materials of the Saruta-gawa region have been subducted to a level 3–5 km deeper than materials that underwent metamorphism at equivalent temperatures and are now exposed in the Asemi-gawa and Bessi regions. Pressure slightly increases toward the north (structurally high levels) through the Sanbagawa belt of central shikoku. Two types of zonal structure were observed in relatively coarse-grained sodic pyroxenes in the matrix. One type is characterized by increasing X
Jd from core to rim, the other type by decreasing X
Jd from core to rim. Both types of zoned pyroxenes show an increase in X
Fe
2+[=Fe2+/(Fe2++Mg)] from core to rim. The first type of zoning was observed in a sample from the chlorite zone of lowest grade, whereas the latter occurs in the garnet and albite-biotite zones of higher grade. The contrast in zonal structure implies that dP/dT during prograde metamorphism decreased with increasing metamorphic grade and may have been negative in some samples from the higher-grade zones. The estimated dP/dT of the prograde stage of the chlorite zone is 3.2 kbar/100°C, and that of the garnet and albite-biotite zones is -1.8 to 0.9 kbar/100°C. The variation of dP/dT at shallow and deep levels of a subduction system probably reflects the difference of heating duration and/or change in thermal gradient of the subduction zone by continuous cooling of the surrounding mantle. 相似文献