Early solar system aqueous activity: K isotope evidence from Allende     

Yun Jiang  Piers Koefoed  Olga Pravdivtseva  Heng Chen  Chun‐Hui Li  Fang Huang  Li‐Ping Qin  Jia Liu  Kun Wang 《Meteoritics & planetary science》2021,56(1):61-76

The alkali element K is moderately volatile and fluid mobile; thus, it can be influenced by both primary processes (evaporation and recondensation) in the solar nebula and secondary processes (thermal and aqueous alteration) in the parent body. Since these primary and secondary processes would induce different isotopic fractionations, K isotopes could become a potential tracer to distinguish them. Using recently developed methods with improved precision (0.05‰, 95% confidence interval), we systematically measured the K isotopic compositions and major/trace elemental compositions of chondritic components (18 chondrules, 3 CAIs, 2 matrices, and 5 bulks) in the carbonaceous chondrite fall Allende. Among all the components analyzed in this study, CAIs, which formed initially under high‐temperature conditions in the solar nebula and were dominated by nominally K‐free refractory minerals, have the highest K₂O content (average 0.53 wt%) and have K isotope compositions most enriched in heavy isotopes (δ⁴¹K: ?0.30 to ?0.25‰). Such an observation is consistent with previous petrologic studies that show CAIs in Allende have undergone alkali enrichment during metasomatism. In contrast, chondrules contain lower K₂O content (0.003–0.17 wt%) and generally lighter K isotope compositions (δ⁴¹K: ?0.87‰ to ?0.24‰). The matrix and bulks are nearly identical in K₂O content and K isotope compositions (0.02–0.05 wt%; δ⁴¹K: ?0.62 to ? 0.46‰), which are, as expected, right in the middle of CAIs and chondrules. This strongly indicates that most of the chondritic components of Allende suffered aqueous alteration and their K isotopic compositions are the ramification of Allende parent‐body processing instead of primary nebular signatures. Nevertheless, we propose the small K isotope fractionations observed (< 1‰) among Allende components are likely similar to the overall range of K isotopic fractionation that occurred in nebular environment. Furthermore, the K isotope compositions seen in the components of Allende in this study are consistent with MC‐ICP‐MS analyses of the components in ordinary chondrites, which also show an absence of large (10‰) isotope fractionations. This is not expected as evaporation experiments in nebular conditions suggest there should be large K isotopic fractionations. Nevertheless, possible nebular processes such as chondrules back exchanging with ambient gas when they formed could explain this lack of large K isotopic variation.  相似文献   

Using hysteretic behaviour and hydrograph classification to identify hydrological function across the “hillslope–depression–stream” continuum in a karst catchment     

Runrun Zhang  Xi Chen  Zhicai Zhang  Chris Soulsby 《水文研究》2020,34(16):3464-3480

In cockpit karst landscapes, fluxes from upland areas contribute large volumes of water to low-lying depressions and stream flow. Hydrograph hysteresis and similarity between monitoring sites is important for understanding the space–time variability of hydrologic responses across the “hillslope–depression–stream” continuum. In this study, the hysteretic feature of hydrographs was assessed by characterizing the loop-like relationships between responses at upstream sites relative to subsurface discharge at the outlet of a small karst catchment. A classification of hydrograph responses based on the multi-scale smoothing Kernel -derived distance classifies the hydrograph responses on the basis of similarities between hillslope and depression sites, and those at the catchment outlet. Results demonstrate that the temporal and spatial variability of hydrograph hysteresis and similarity between hillslope flow and outlet stream flow can be explained by the local heterogeneity of depression aquifer. Large depression storage deficits emerging in the highly heterogeneous aquifer produce strong hysteresis and multiple relationships of upstream hydrographs relative to the outlet subsurface discharge. In contrast, when depression storage deficits are filled during consecutive rainfall events, depression hydrographs at the high permeability sites are almost synchronous or exhibit a monotonous function with the hydrographs at the outlet. This reduced hydrograph hysteresis enhances preferential flow paths in fractured rocks and conduits that can accelerate the hillslope flow to the outlet. Therefore, classification of hydrograph similarities between any upstream sites and the catchment outlet can help to identify the dominant hydrological functions in the heterogeneous karst catchment.  相似文献   

Investigation of the elevation of saltwater wedge due to subsurface dams     

Qinpeng Chang  Tianyuan Zheng  Youyuan Chen  Xilai Zheng  Marc Walther 《水文研究》2020,34(22):4251-4261

Subsurface dams are rather effective and used for the prevention of saltwater intrusion in coastal regions around the world. We carried out the laboratory experiments to investigate the elevation of saltwater wedge after the construction of subsurface dams. The elevation of saltwater wedge refers to the upward movement of the downstream saltwater wedge because the subsurface dams obstruct the regional groundwater flow and reduce the freshwater discharge. Consequently, the saltwater wedge cannot further extend in the longitudinal direction but rises in the vertical profile resulting in significant downstream aquifer salinization. In order to quantitatively address this issue, field-scale numerical simulations were conducted to explore the influence of various dam heights, distances, and hydraulic gradients on the elevation of saltwater wedge. Our investigation shows that the upward movement of the saltwater wedge and its areal extension in the vertical domain of the downstream aquifer become more severe with a higher dam and performed a great dependence on the freshwater discharge. Furthermore, the increase of the hydraulic gradient and the dam distance from the sea boundary leads to a more pronounced wedge elevation. This phenomenon comes from the variation of the freshwater discharge due to the modification of dam height, location, and hydraulic gradient. Large freshwater discharge can generate greater repulsive force to restrain the elevation of saltwater wedge. These conclusions provide theoretical references for the behaviour of the freshwater–seawater interface after the construction of subsurface dams and help optimize the design strategy to better utilize the coastal groundwater resources.  相似文献   

城市“腾笼换鸟”产业转型升级的困境与出路——基于北京市的调查研究     

王颖  段霞  吴康 《地理科学》2020,40(5):786-792

剖析北京“腾笼换鸟”产业转型升级的现状,在针对“新鸟”进笼“老鸟”去哪问题,“老笼”空间结构合理优化问题,“老鸟”涅槃“新鸟”培育问题,“老鸟”和“新笼”承接问题的分析基础上,提出应完善京津冀产业链协作,“腾笼换鸟”拓展区域联动发展空间;东西城合并成首都特区,“腾笼换鸟”保护北京历史文化名城;切实发挥政府的职能作用,“腾笼换鸟”提升企业内在动力机制;规划建设“微中心”小城镇,“腾笼换鸟”促进北京人口有效疏解的建议。  相似文献   

东北三省全面振兴的社会经济支撑能力评估     

马丽  田华征  康蕾  戚伟 《地理科学》2020,40(6):863-873

在解析支撑能力和东北问题特点的基础上，从“创新、协调、绿色、开放、共享”五大理念出发建立全面振兴社会经济支撑能力评价指标体系和综合评价方法，以地级市为单元对东北三省进行评估。研究发现：各地市社会经济支撑能力差异显著，哈大沿线核心城市的支撑能力较强，西翼城市以及朝阳、七台河、绥化、葫芦岛、铁岭、双鸭山和鹤岗等资源型城市支撑能力较弱。因此未来东北地区在振兴政策的区域分布上应有所侧重，对不同地区施以不同的振兴或扶持政策。在创新、绿色、开放方面需要集中力量重点突破，而在体制机制改革和共享服务建设方面需要全面覆盖，并重点加强黑龙江北部和辽宁、吉林西翼城市的共享能力建设。  相似文献   

城市内涝灾害受灾人口评估方法与实证研究：以哈尔滨市道里区为例     

陈鹏  赵洪阳  张继权  张硕  鲍建华  刘晓静 《地理科学》2020,40(1):158-164

城市内涝灾害频发,对居民生命安全造成严重威胁,为提高城市内涝灾害受灾人口评估精度,提出一种更为精确的受灾人口评估方法。以哈尔滨市道里区为研究区,以城市内涝灾害受灾人口为研究对象,运用一、二维非恒定流为主控方程,构建城市内涝数值模拟模型,并结合受灾人口分布特点,综合构建基于土地利用的人口随时间变化的计算模型。实现在模拟内涝灾害影响范围基础上,利用受灾人口计算模型提取白天与夜晚受灾人口分布情况。结果表明：研究区在百年一遇降雨情景下,有25条街道会发生不同程度积水,积水深度范围值为0.10~1.42 m;此级别内涝灾害在白天11条街道受灾人口数量最大值达到3 500人,夜晚10条街道受灾人口数量最大值为720人。  相似文献   

乡土地理实践活动案例分析与应用——以“明光市女山古火山地质公园考察”为例     

孙玉林  陈荟 《地理教学》2020,(2):30-32

地理实践是地理科学的重要研究方法,也是中学地理学科的主要学习方式之一。中学地理实践活动应结合乡土地理资源,充分挖掘当地可供考察的自然、人文素材,形成丰富的乡土地理实践案例。本文以“女山古火山地质公园实践活动为案例”,探究乡土资源在地理实践活动中的应用。  相似文献   

贵州夜郎湖表层水体地球化学昼夜变化及其影响因素     

王家录  任娟  王勇  李维杰  娄昭  陈佳 《热带地理》2020,40(2):335-345

为探究岩溶水库水文地球化学行为过程,对贵州普定夜郎湖表层水体进行了为期3 d的高分辨率昼夜监测。结果表明：1）多变的天气和水文条件叠加导致水体离子指标昼夜变化不显著,规律性较差。而水温、DO、pH值、SpC、SIc、pCO₂等常规理化指标受水温变化和生物作用表现出明显的昼夜波动。2）利用亨利常数和主成分分析,得到温度变化、生物作用、人类活动、水库的蓄水与放水对夜郎湖水库水文地球化学特征变化的贡献率分别为21.66%、17.28%、14.08%和10.22%,说明作用于水库水文地球化学行为的因子具有多元性。3）δ ¹⁸O表现出与DO一致的波动趋势,即白天上升,晚上下降,反映在短时间尺度上,氢氧稳定同位素变化受控于生物过程（主要是呼吸作用过程）;而对比水库水体和大气降水的d-excess（d值）发现,水库水体的d值（8.21‰）显著偏低于当地大气降水的d值（9.64‰）,说明在长时间尺度上,主要受蒸发效应引起的不平衡分馏影响。  相似文献   

功能疏解背景下京津冀中部核心区产业投资网络演化研究     

刘骁啸  吴康 《地理科学进展》2020,39(12):1972-1984

非首都功能疏解作为京津冀协同发展战略的核心,对解决北京大城市病、实现京津冀可持续发展具有重要意义。论文构建了一个“四位一体”的产业投资网络演化分析框架,以京津冀中部核心区为研究对象,利用工商企业投资大数据测度了非首都功能的3类重点行业在2010、2014、2018年的资本流动特征,并从“节点—路径—格局”3个层面分析了功能疏解背景下产业投资网络演化过程。研究结果表明,非首都功能疏解背景下,北京市各行业对外投资增强,投资集聚中心逐渐向外围转移,但不同行业演化格局存在差异。制造业呈现由邻近扩散向等级扩散转变的演化路径,并向着多中心格局发展;批发零售业在资本净流动层面显示出扩散特征,在骨干路径层面呈现集聚现象,分布格局由北京单极放射状向京津双核联动演化;交通运输仓储和物流业向郊区物流园区所在地集聚,但网络整体发育滞后。研究结果能够为科学认识首都功能疏解情况、了解中部核心区产业结构及产业发展的变动态势提供参考。  相似文献   

Salinivibrio sp.YH4胞外丝氨酸蛋白酶EYHS耐盐性及生物信息学分析          下载免费PDF全文

武翠玲  宋英达  高慧芳  张廉芸  任晨霞 《盐湖研究》2020,28(1)

摘要：目的 探讨菌株Salinivibrio sp.YH4分泌的丝氨酸蛋白酶EYHS的耐盐性及结构特征。方法 明胶底物酶谱法分析EYHS的耐盐性。应用生物信息学手段对EYHS及6种耐盐的S8家族丝氨酸蛋白酶结构特征进行分析。结果 EYHS在4 mol/L的NaCl溶液中仍具有活性，属于耐盐蛋白酶。EYHS及6种S8家族丝氨酸蛋白酶分子表面的loop区等无规则卷曲所占比例较高，α-螺旋与β-片层则主要位于酶分子内部。EYHS分子表面酸性氨基酸含量较高，且具有弱疏水内核。多序列比对发现蛋白酶的催化三联体两侧存在高度保守的基序和保守的极性氨基酸及芳香族氨基酸，并存在多个保守的Gly与Ala。同源模建和表面电荷分布显示，α螺旋和β片层围成了蛋白酶的催化腔，EYHS活性中心包含由Asp32、His65与Ser215组成的催化三联体，且催化位点区域表面静电势为负。结论 上述结构特征可能有助于耐盐丝氨酸蛋白酶EYHS在高盐环境下维持其稳定性和适度柔性，并有助于其催化功能的发挥，为深入研究耐盐丝氨酸蛋白酶的高盐环境适应性提供了一定的理论依据。  相似文献