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1.
The role of different minerals in base cation release and thus the increase of buffering capacity of groundwater against acid deposition is controversially discussed in the literature. The 87Sr/86Sr ratios and base cation concentration were investigated in whole rock leachates, mineral separates, precipitation, soil solution, groundwater and stream water samples in the Lehstenbach catchment (Germany) to identify the weathering sequence of the granite bedrock. Three different approaches were followed in parallel. It was assumed that the contribution of different minerals to base cation supply of the groundwater with increasing weathering intensity would be observed by investigating (1) unweathered rock leachates, deep groundwater and shallow groundwater, (2) groundwater samples from new groundwater wells, reflecting the initial weathering of the drilled bedrock, and groundwater from wells that were drilled in 1988, (3) stream water during baseflow, dominated by deep groundwater, and stream water during high flow, being predominantly shallow groundwater. Whereas the first approach yielded consistent patterns, there was some evidence that groundwater from the new wells initially reflected contamination by the filter gravel rather than cation release in an initial stage of weathering. Time series samples of stream water and groundwater solute concentrations and isotope ratios turned out to reflect varying fractions of soil water and precipitation water at baseflow and high flow conditions rather than varying contributions of different minerals that prevail at different stages of granite weathering.  相似文献   
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A two-layered model is considered in which the upper layer is continuously stratified and the lower layer is homogeneous. The system is driven by atmospheric forces. Bottom stress and topography are included in the model. The linear three-dimensional hydrodynamical equations are used to describe the system. Taking the eddy viscosity in the upper layer as inversely proportional to the static stability, the dependent variables are expanded in terms of continuous functions in the vertical (eigenfunctions). Using this method it is possible to compute currents and internal displacements at any depth in the upper layer. The three-dimensional structure of the lower layer is not considered in this model. The equations describing the lower layer are integrated over depth to give depth mean currents. Using a staggered finite-difference grid in the horizontal and a forward time-stepping procedure, numerical test experiments are carried out for a cross section and for a closed rectangular basin.  相似文献   
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Lacustrine groundwater discharge (LGD) transports nutrients from a catchment to a lake, which may fuel eutrophication, one of the major threats to our fresh waters. Unfortunately, LGD has often been disregarded in lake nutrient studies. Most measurement techniques are based on separate determinations of volume and nutrient concentration of LGD: Loads are calculated by multiplying seepage volumes by concentrations of exfiltrating water. Typically low phosphorus (P) concentrations of pristine groundwater often are increased due to anthropogenic sources such as fertilizer, manure or sewage. Mineralization of naturally present organic matter might also increase groundwater P. Reducing redox conditions favour P transport through the aquifer to the reactive aquifer‐lake interface. In some cases, large decreases of P concentrations may occur at the interface, for example, due to increased oxygen availability, while in other cases, there is nearly no decrease in P. The high reactivity of the interface complicates quantification of groundwater‐borne P loads to the lake, making difficult clear differentiation of internal and external P loads to surface water. Anthropogenic sources of nitrogen (N) in groundwater are similar to those of phosphate. However, the environmental fate of N differs fundamentally from P because N occurs in several different redox states, each with different mobility. While nitrate behaves essentially conservatively in most oxic aquifers, ammonium's mobility is similar to that of phosphate. Nitrate may be transformed to gaseous N2 in reducing conditions and permanently removed from the system. Biogeochemical turnover of N is common at the reactive aquifer‐lake interface. Nutrient loads from LGD were compiled from the literature. Groundwater‐borne P loads vary from 0.74 to 2900 mg PO4‐P m?2 year?1; for N, these loads vary from 0.001 to 640 g m?2 year?1. Even small amounts of seepage can carry large nutrient loads due to often high nutrient concentrations in groundwater. Large spatial heterogeneity, uncertain areal extent of the interface and difficult accessibility make every determination of LGD a challenge. However, determinations of LGD are essential to effective lake management. Copyright © 2014 John Wiley & Sons, Ltd.  相似文献   
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Like almost all fields of science, hydrology has benefited to a large extent from the tremendous improvements in scientific instruments that are able to collect long-time data series and an increase in available computational power and storage capabilities over the last decades. Many model applications and statistical analyses (e.g., extreme value analysis) are based on these time series. Consequently, the quality and the completeness of these time series are essential. Preprocessing of raw data sets by filling data gaps is thus a necessary procedure. Several interpolation techniques with different complexity are available ranging from rather simple to extremely challenging approaches. In this paper, various imputation methods available to the hydrological researchers are reviewed with regard to their suitability for filling gaps in the context of solving hydrological questions. The methodological approaches include arithmetic mean imputation, principal component analysis, regression-based methods and multiple imputation methods. In particular, autoregressive conditional heteroscedasticity (ARCH) models which originate from finance and econometrics will be discussed regarding their applicability to data series characterized by non-constant volatility and heteroscedasticity in hydrological contexts. The review shows that methodological advances driven by other fields of research bear relevance for a more intensive use of these methods in hydrology. Up to now, the hydrological community has paid little attention to the imputation ability of time series models in general and ARCH models in particular.  相似文献   
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The Holocence paleolimnology of Lake Sämbosjön is described using geochemical and diatom analyses. The objective of this study is the reconstruction of major changes in trophic state and productivity, and to interpret the major causative processes. The accumulation of organic matter indicates a relatively high productivity in early Holocene, and the diatom analysis indicates a relatively high trophic state and pH. A succeeding decrease in productivity and trophic state and lowering in pH is recorded from about 8000 BP. If lake development had been primarily edaphically conditioned, viz. determined by nutrient supply from catchment soils, such a progressive oligotrophication would represent the common development of temperate lakes. Between about 6000 BP and 4000 BP Lake Sämbosjön was characterized by relatively stable productivity and pH. From about 4000 BP the analyses reveal an increase again in trophic state, productivity, and in pH. This eutrophication, which continued throughout the late Holocene, was caused by an exceptionally strong human influence on the catchment of Lake Sämbosjön. The increased supply of nutrients from cleared and deforested catchment soils changed the trophic state and provided the basis for increased lake productivity.  相似文献   
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Archive aerial photos have been used to create a skeletal history for several toxic waste sites currently under investigation in the United States. Because many of the sites are very small in area, and the majority of the historical aerial photography is not large scale, specialized methods have, through experience, been developed to do this work. The result of the work is a series of standard format film stereograms and a detailed report. The report includes several unique methods for presenting the airphoto findings.  相似文献   
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