Preparation of filter aids based on diatomites   总被引：1，自引：1，他引：1  

Sanja Martinovic  Milica Vlahovic  Tamara Boljanac  Ljubica Pavlovic 《International Journal of Mineral Processing》2006,80(2-4):255-260

Two major deposits of diatomaceous earth (diatomite) in the region of the Balkan Peninsula, the Kolubara basin (Serbia and Montenegro) and the Vesje deposit (Former Yugoslav Republic of Macedonia), were selected for detailed investigation of their possible application in preparation of beer filter aids. Chemical, mineralogical and structural properties of diatomite samples were analyzed with the aim of predicting the filtration efficiency. Results of beer filtering compounds preparation are presented in this paper. The parameters of crushing, drying, calcination and classification are also defined. Beer filtration tests proved diatomites to be satisfactory and not causing any degradation of filtration process or beer quality. Technological flow scheme for obtaining the beer filter aids is proposed in the paper.  相似文献   

Use of fallout 137Cs for documenting the chronology of overbank sediments from the river Sava, Croatia, and interpreting their geochemical patterns     

Gordana Pavlovic  Delko Barisic  Ivanka Lovrencic  Visnja Orescanin  Esad Prohic 《Environmental Geology》2005,47(4):475-481

This paper attempts to determine the impact of former Pb-Zn-Ba mining activities in Slovenian drainage basin on overbank sediments of the Sava river (West Croatia). Among the four studied sequences (S7, S8, S9, S10), the most upstream profile S7 showed the most pronounced impact of ore mining. Mercury was enriched more than 100-fold; Pb and Zn had a strong positive correlation (r > 0.99). Two factor models clearly revealed the Pb-Ba-Hg association in the lower-lying carbonate (CA) population of all four profiles, but only in the overlying silicate (SI) population of profile S7. Factor analysis confirmed this association in the total sediment (90 samples) as well as separately in the CA (33 samples) and SI (57 samples) populations. Based on a comparison with an undisturbed soil profile, the vertical distribution of ¹³⁷Cs in profile S7 was interpreted to be the combination of caesium deposition caused by a flood in 1964 and by post-depositional redistribution.  相似文献   

Granulometric and chemical composition of the Sava River sediments upstream and downstream of the Krsko nuclear power plant   总被引：2，自引：2，他引：0  

Visnja?OrescaninEmail author  Stipe?Lulic  Gordana?Pavlovic  Luka?Mikelic 《Environmental Geology》2004,46(5):605-614

Total concentrations of 13 elements (K, Ca, Ti, Cr, Mn, Fe, Cu, Zn, Rb, Sr, Y, Zr, Pb) in the size-fractionated Sava River sediments upstream and downstream of the Krsko nuclear power plant together with metal speciation within bulk sediment have been investigated. Trace metals generally increase with decreasing particle size, however, because of entrapment of organic matter in the 0.63–1 mm fraction, concentrations in the coarser sediment fraction are higher than expected. Exchangeable Pb, Zn, Cu, Mn, Cr and Fe are generally found to represent a negligible fraction of the total metal concentration of the bulk sediment. Seasonal variations of the Pb, Zn and Cu concentrations in the <0.5 mm fraction reflect decreased values during the spring period. Heavy metal concentrations in the 2003 waste water discharges from the Krsko nuclear power plant released into the Sava River were much lower than their maximum allowed values. Combined rubidium and organic matter normalization of the Zn, Pb and Cu concentrations, which was applied on the minus 0.063 mm fraction, indicated three potential sources of contaminants.  相似文献   

Detection of radical species formed by the ozonolysis of α-pinene     

Jelica Pavlovic  Philip K. Hopke 《Journal of Atmospheric Chemistry》2010,66(3):137-155

Highly reactive free radical species have been subject of many toxicological in vivo and in vitro studies because of the oxidative cell damage they cause. Similar species have been postulated to be the key intermediates formed during many environmental chamber reactions and atmospheric oxidation of organic species present in the troposphere. Thus, detection and characterization of these transient radical species are important steps in understanding the atmospheric chemistry and confirming the reaction pathways involved in secondary organic aerosol formation. Study of these species is particularly difficult because of their short life-times. To facilitate such studies, 5,5-dimethyl-1-pyrroline-N-oxide (DMPO) and diethyl-(2-methyl-1-oxido-3,4-dihydro-2H-pyrrol-2-yl) phosphonate (DEPMPO) nitrone spin traps were used to capture radicals formed from the α-pinene/ozone reaction. Electrospray ionization/tandem mass spectrometry (ESI/MSⁿ) was applied to elucidate their structures. Characteristic fragments with m/z 114, m/z 130 and m/z 148 with the DMPO trap, and m/z 236, m/z 252, and m/z 270 with the DEPMPO trap indicated the existence of alkyl, alkoxyl and peroxyl radicals, respectively.  相似文献   

Vibration of beams on partial elastic foundations     

Paul F. Doyle  Milija N. Pavlovic 《地震工程与结构动力学》1982,10(5):663-674

The natural response of a beam or pile having only a portion of its span supported by an elastic foundation is investigated for the two cases when both ends are either simply supported or free. The derivation of the shape functions and the computed natural frequencies are compared with the extreme cases where the element is either completely supported by, or fully detached from, the elastic foundation.  相似文献   

The influence of fly and bottom ash deposition on the quality of Kastela Bay sediments     

Visnja Orescanin  Delko Barisic  Ivanka Lovrencic  Luka Mikelic  Martina Rozmaric-Macefat  Gordana Pavlovic  Stipe Lulic 《Environmental Geology》2005,49(1):53-64

The objective of this study was chemical and radiological characterization of Kastela Bay sediments exposed to numerous anthropogenic sources like deposition of fly and bottom ash enriched in radionuclides and heavy metals, chemical plant, cement plant, iron plant, shipyard, electroplating facility, untreated industrial and domestic waste waters as well as heavy traffic. Totally, 33 samples of the mixture of fly and bottom ash, 12 sediment cores ranging from 0 to 40 cm and nine surface sediment samples were analyzed. Enrichment in heavy metals in the mixture of fly and bottom ash was ranging from 1.5 to 36 times compared to flysch soil while ²²⁶Ra and ²³⁸U were up to 50 times enriched compared to average activities characteristic for surrounding soils developed on the Middle and Upper Eocene flysch. Maximum ²³⁸U activity was approximately 32 times higher and ²²⁶Ra approximately 40 times higher in the Kastela Bay sediment compared to mean value determined for Adriatic sediments. The highest enrichment in sediment cores compared to background values were found for Zn (35.6 times), Pb (16 times), Cr (9.1 times) and Ni (4 times)  相似文献   

The Holocene history of West Basin Lake,Victoria, Australia; chemical changes based on fossil biota and sediment mineralogy   总被引：4，自引：0，他引：4  

Peter A. Gell  Philip A. Barker  Patrick De Deckker  William M. Last  Ljubica Jelicic 《Journal of Paleolimnology》1994,12(3):235-258

Analyses of diatoms, ostracods, pollen and sediment mineralogy from a 524 cm core from a stratified, hypersaline crater lake, West Basin, Victoria, has revealed clear shifts in the lake's water balance and chemistry and the region's climate over the last 10 000 years. Diatom and ostracod analyses reveal lake water salinity changes which are consistent with the conditions suitable for the precipitation of the carbonate and other minerals identified using x-ray diffraction analysis. The fluctuations in lake water balance deduced from diatom and ostracod inferred lake salinity suggest that the lake began to fill at the beginning of the Holocene and was saline and shallow. Toward the mid-Holocene the water levels rose and yet the lake remained largely saline. The late Holocene is marked by a return to more shallow but fluctuating, water conditions. Through the whole period, the regional dryland vegetation was dominated by open sclerophyll woodland. Both the lacustrine and regional environments interpreted here are consistent with those from Holocene records elsewhere in the region.This is the fourth in a series of papers published in this issue on the paleolimnology of arid regions. These papers were presented at the Sixth International Palaeolimnology Symposium held 19–21 April, 1993 at the Australian National University, Canberra, Australia. Dr A. R. Chivas served as guest editor for these papers.  相似文献