Potential eutrophication assessment in rivers; relationship between produced and exported loads     

D. Cluis  P. Couture  R. Bégin  S. A. Visser 《Aquatic Sciences - Research Across Boundaries》1988,50(2):166-181

In contrast with biological processes in lacustrine environments, the physical characteristics of river waters greatly complicate the relationship between nutrient input and primary productivity. In this paper a new approach to quantify this relationship is developed, linking land use within the watershed to the bioavailability of nutrients in the receiving waters. It estimates by two different ways an enrichment index derived from N/P ratios. A load model links land-use within the watershed area to nutrient export, and allows the estimation of the potential enrichment index from the ratio of calculated annual exports of nitrogen and phosphorus. This index value correlates well with the real enrichment index representing the annual mean value of the corresponding measured ratios in running waters. The latter index can then be related to nutrient availability expressed by chl-a and the algal growth potential. This model, established from 7 sampling stations on the Yamaska-North river, allowed assessment of nutrient bioavailability in the river water as a function of hydrological (low or high water flow) as well as of seasonal (summer or winter) events.  相似文献   

Interplay of S and As in Mekong Delta sediments during redox oscillations   总被引：1，自引：1，他引：0  

Van T.H.Phan  Fabrizio Bardelli  Pierre Le Pape  Raoul-Marie Couture  Alejandro Fernandez-Martinez  Delphine Tisserand  Rizlan Bernier-Latmani  Laurent Charlet 《地学前缘(英文版)》2019,10(5):1715-1729

The cumulative effects of periodic redox cycling on the mobility of As,Fe,and S from alluvial sediment to groundwater were investigated in bioreactor experiments.Two particular sediments from the alluvial floodplain of the Mekong Delta River were investigated:Matrix A(14 m deep)had a higher pyrite concentration than matrix B(7 m deep)sediments.Gypsum was present in matrix B but absent in matrix A.In the reactors,the sediment suspensions were supplemented with As(Ⅲ)and SO_4~(2-),and were subjected to three full-redox cycles entailing phases of nitrogen/CO_2,compressed air sparging,and cellobiose addition.Major differences in As concentration and speciation were observed upon redox cycling.Evidences support the fact that initial sediment composition is the main factor controlling arsenic release and its speciation during the redox cycles.Indeed,a high pyrite content associated with a low SO_4~(2-)content resulted in an increase in dissolved As concentrations,mainly in the form of As(Ⅲ),after anoxic half-cycles;whereas a decrease in As concentrations mainly in the form of As(Ⅴ),was instead observed after oxic half-cycles.In addition,oxic conditions were found to be responsible for pyrite and arsenian pyrite oxidation,increasing the As pool available for mobilization.The same processes seem to occur in sediment with the presence of gypsum,but,in this case,dissolved As were sequestered by biotic or abiotic redox reactions occurring in the Fe—S system,and by specific physico-chemical condition(e.g.pH).The contrasting results obtained for two sediments sampled from the same core show that many complexes and entangled factors are at work,and further refinement is needed to explain the spatial and temporal variability of As release to groundwater of the Mekong River Delta(Vietnam).  相似文献   

Arsenic, iron and sulfur co-diagenesis in lake sediments   总被引：3，自引：0，他引：3  

Raoul-Marie Couture  André Tessier 《Geochimica et cosmochimica acta》2010,74(4):1238-6788

Profiles of porewater pH and dissolved As, Fe, Mn, sulfate, total sulfide (ΣS^−II), total zero-valent sulfur (ΣS⁰), organic carbon and major ion concentrations, as well as those of solid As, acid-volatile sulfide (AVS), total S, Fe, Mn, Al, organic C, ²¹⁰Pb and ¹³⁷Cs were determined in the sediment of four lakes spanning a range of redox and geochemical conditions. An inverse modeling approach, based on a one-dimensional transport-reaction equation assuming steady-state, was applied to the porewater As profiles and used to constrain the net rates of reactions involving As (). The model defines depth intervals where As is either released to (positive ) or removed from (negative ) the porewaters.At two of the sites, whose bottom water were oxygenated at sampling time, a production zone ( = 12 × 10⁻¹⁸ mol cm⁻³ s⁻¹-71 × 10⁻¹⁸ mol cm⁻³ s⁻¹) is inferred a few cm below the sediment-water interface, coincident with sharp porewater As and Fe peaks that indicate an intense coupled recycling of As and Fe. This process is confirmed by solid As and Fe maxima just below the sediment surface. In these two lakes a zone of As consumption ( = −5 × 10⁻¹⁸ mol cm⁻³ s⁻¹ to −53 × 10⁻¹⁸ mol cm⁻³ s⁻¹), attributed to the slow adsorption of As to authigenic Fe oxyhydroxides, occurs just above the production zone. A second-order rate constant of 0.12 ± 0.03 cm³ mol⁻¹ s⁻¹ is estimated for this adsorption reaction.Such features in the porewater and solid profiles were absent from the two other lakes that develop a seasonally anoxic hypolimnion. Thermodynamic calculations indicate that the porewaters of the four lakes, when sulfidic (i.e., ΣS^−II ? 0.1 μM), were undersaturated with respect to all known solid As sulfides; the calculation also predicts the presence of As^V oxythioanions in the sulfidic waters, as suggested by a recent study. In the sulfidic waters, the removal of As ( = −1 × 10⁻¹⁸ mol cm⁻³ s⁻¹ to −23 × 10⁻¹⁸ mol cm⁻³ s⁻¹) consistently occurred when saturation, with respect to FeS_(s), was reached and when As^V oxythioanions were predicted to be significant components of total dissolved As. This finding has potential implications for As transport in other anoxic waters and should be tested in a wider variety of natural environments.  相似文献   

Structural and engineering geology of the East Gate Landslide, Purcell Mountains, British Columbia, Canada   总被引：3，自引：0，他引：3  

Marc-Andr Brideau  Doug Stead  Rjean Couture 《Engineering Geology》2006,84(3-4):183-206

The East Gate Landslide is a prehistoric landslide that was reactivated in January 1997. The slope failure took place in the lower greenschist metasedimentary units of the Precambrian Horsethief Creek Group. The Grizzly Creek Thrust is a regional overturned fault that coincides with the location of the headscarp of the East Gate Landslide. Four discontinuity sets were recognised from detailed engineering geological mapping of the headscarp and surrounding area. The main scarp of the section reactivated in 1997 was sub-divided into three structural domains based on its position within the landslide, lithology, and orientation of the discontinuity sets. Limit-equilibrium techniques, finite-difference (FLAC) and distinct-element (UDEC) codes were used to investigate the failure mechanism of the 1997 event. The results of the field observations and numerical models suggest that the 1997 failure involved a complex mechanism incorporating components of rock-slumping, bi-planar, and pseudo-circular failure that was controlled by both the orientation of the discontinuity sets and reduced rock-mass quality due to tectonic deformation.  相似文献   

Contents of Volume 26     

Réjean Couture  Stephen G. Evans  Jacques Locat 《Natural Hazards》2002,26(3):333-334

Table of Contents

Contents of Volume 26  相似文献   

The Arctic Coastal Dynamics Database: A New Classification Scheme and Statistics on Arctic Permafrost Coastlines     

Hugues Lantuit  Pier Paul Overduin  Nicole Couture  Sebastian Wetterich  Felix Aré  David Atkinson  Jerry Brown  Georgy Cherkashov  Dmitry Drozdov  Donald Lawrence Forbes  Allison Graves-Gaylord  Mikhail Grigoriev  Hans-Wolfgang Hubberten  James Jordan  Torre Jorgenson  Rune Strand ?deg?rd  Stanislav Ogorodov  Wayne H. Pollard  Volker Rachold  Sergey Sedenko  Steve Solomon  Frits Steenhuisen  Irina Streletskaya  Alexander Vasiliev 《Estuaries and Coasts》2012,35(2):383-400

Arctic permafrost coasts are sensitive to changing climate. The lengthening open water season and the increasing open water area are likely to induce greater erosion and threaten community and industry infrastructure as well as dramatically change nutrient pathways in the near-shore zone. The shallow, mediterranean Arctic Ocean is likely to be strongly affected by changes in currently poorly observed arctic coastal dynamics. We present a geomorphological classification scheme for the arctic coast, with 101,447?km of coastline in 1,315 segments. The average rate of erosion for the arctic coast is 0.5?m? year^?1 with high local and regional variability. Highest rates are observed in the Laptev, East Siberian, and Beaufort Seas. Strong spatial variability in associated database bluff height, ground carbon and ice content, and coastline movement highlights the need to estimate the relative importance of shifting coastal fluxes to the Arctic Ocean at multiple spatial scales.  相似文献   

Past and future changes to acidified eastern Canadian lakes: A geochemical modeling approach     

T.A. Clair  J. Aherne  I.F. Dennis  M. Gilliss  S. Couture  D. McNicol  R. Weeber  P.J. Dillon  W. Keller  D.S. Jeffries  S. Page  K. Timoffee  B.J. Cosby 《Applied Geochemistry》2007

As SO₂ emissions are being reduced in North America, it has become important to know how rapidly the surface water chemistry of aquatic systems will recover. The authors applied the model of acidification of groundwater in catchments (MAGIC) to 410 acid-sensitive lakes located in a 3000 km east–west gradient in eastern Canada. The goal was to estimate the water chemistry from pre-acidification times, under worst case conditions (mid 1970s) and what it should be in the year 2030 after proposed acid emission reduction levels agreed-to or planned by Canada and the United States are in place. In eastern Canada, large decreases in pH and ANC are shown between pre-acidification and 1975, the year of greatest historical deposition. Current-day conditions are much improved from 1975. Under the most likely future acid deposition reduction scenarios, an improvement of pH and ANC is shown in all the regions from current-day levels, but not to pre-acidification levels. Dissolved Ca levels were considerably higher at the height of acidification than under pristine conditions, but will return to pre-acidification levels at most of the sites by the year 2030. The results also show that under proposed control programs, a large number of sites in eastern Canada will not return to ANC values >40 μeq L⁻¹, thought to be suitable for healthy aquatic communities.  相似文献   

Introduction     

Couture  Réjean  Evans  Stephen G.  Locat  Jacques 《Natural Hazards》2002,26(1):1-6

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X-ray fluorescence analysis of silicate rocks using fused glass discs and a side-window Rh source tube: accuracy, precision and reproducibility     

Rex A. Couture  Michael S. Smith  Robert F. Dymek 《Chemical Geology》1993,110(4):315-328

In this paper, we provide a detailed account of our sample fusion, calibration and instrumentation methods for major-element whole-rock analysis by XRF, and we discuss several aspects of sample preparation and instrument performance that are important considerations for accurate analysis. The fusion procedure involves moderate capital costs and is easy to apply, yielding flat, polished, homogeneous glass discs as cast. The calibration method utilizes a least-squares procedure that rigorously fits data according to both compositional and counting statistical uncertainties. We use a side-window Rh tube for analyzing major elements (including Na) and employ real-time testing for constant count rate to reject spurious results.

The methods result in excellent analytical precision and reproducibility. The standards used for calibration lie within compositional and counting statistical uncertainties of best-fit straight lines. Analyses of replicate discs and repeated analyses of single discs show excellent long-term reproducibility over several months, approaching counting statistical uncertainties in several cases. Comparison with independent measurements made by other laboratories using instrumental neutron activation and X-ray fluorescence analyses shows excellent agreement with our results.

A side-window Rh tube gives increased detection limits for most major elements, but otherwise shows little difference in precision compared to a Cr tube. This means that major and trace elements can be analyzed without changing X-ray sources, which provides saving in terms of time and money, as well as being a convenience to the analyst.  相似文献   

Contribution durant des épisodes hydrologiques extrêmes des apports atmosphériques et souterrains en ions majeurs à la qualité des eaux de surface*     

Daniel Cluis  René Langis  Pierre Couture 《大气与海洋》2013,51(3):437-448

Résumé

Le comportement des ions majeurs (Ca⁺², Mg⁺², Na⁺, K⁺, Cl^?, SO₄ ^?2) et de la conductivité en rivière en fonction des épisodes hydrologiques extrêmes est examiné. Plus précisément, les concentrations moyennes de chaque ion majeur, de même que la composition chimique globale des eaux en étiage et en crue sont confrontées aux valeurs obtenues dans les eaux de précipitation et les eaux souterraines. Il en ressort que, dans les eaux de la rivière Sainte‐Anne, même pour les épisodes d'étiage les plus sévères, la concentration des ions majeurs diffère sensiblement de celle des eaux souterraines. Par ailleurs, on observe que les concentrations sont significativement plus élevées en étiage qu'en crue pour l'ensemble des paramètres, ce qui est également mis en évidence par les relations concentration‐débit. Un bilan massique chimique par épisode a été esquissé, mais la contribution des eaux souterraines y apparaît généralement trop forte; on en déduit qu'une fraction seulement des eaux souterraines possède la concentration typique des eaux de puits ou que la nappe superficielle alimentant principalement l'écoulement en étiage, est bien moins chargée. Ces résultats mettent en évidence la complexité de l'évolution de la qualité même pour les éléments de comportement réputé simple.  相似文献