Isotope Characteristics of Carbonates from Rocks of Greenstone Belts as an Indicator of a Possible Source of Fluids in Precambrian Granulite Complexes: An Example from the Giyani Greenstone Belt and the Limpopo Granulite Complex,South Africa     

Mityaev  A. S.  Safonov  O. G.  Reutsky  V. N.  Izokh  O. P.  Varlamov  D. A.  Kozlovskii  V. M.  van Reenen  D. D.  Aranovich  L. Y. 《Doklady Earth Sciences》2020,492(1):342-345

Doklady Earth Sciences - Data on the carbon and oxygen isotopic composition of carbonates from the rocks of the Giyani greenstone belt, Kaapvaal craton, South Africa are presented. This belt is...  相似文献   

Carbon Isotope Characteristics as Evidence of an External Source of High-Temperature Granitoids in Granulite Complexes     

Safonov  O. G.  Reutsky  V. N.  Shcherbakov  V. D.  Golunova  M. A.  Varlamov  D. A.  Yapaskurt  V. O.  van Reenen  D. D. 《Doklady Earth Sciences》2018,483(2):1515-1518

Doklady Earth Sciences - Data on the carbon isotope composition of graphite and CO2 from inclusions in quartz of granitoids of the Southern Marginal Zone (SMZ) of the Limpopo granulite belt, South...  相似文献   

Carbon Isotope Composition of Diamond Crystals Grown Via Redox Mechanism     

V. N. Reutsky  Yu. N. Palyanov  M. Wiedenbeck 《Geochemistry International》2018,56(13):1398-1404

  相似文献   

Geochemical controls on the formation of unconformity-type Au–U deposits (Northern Transbaikalia)     

A. E. Budyak  A. V. Parshin  A. M. Spiridonov  V. N. Reutsky  B. B. Damdinov  M. G. Volkova  Yu. I. Tarasova  V. A. Abramova  N. N. Bryukhanova  O. V. Zarubina 《Geochemistry International》2017,55(2):184-194

This study provides geochemical, mineralogical, and isotope data for rocks and ores from Lower Proterozoic black shale formations of the Kodar–Udokan structural and formational zone, which host the Khadatkanda gold—uranium deposit. The results indicate that the uranium and gold mineralizations were formed at different times in relation to different geodynamic settings. The gold mineralization is associated with the inception of the Syulban fault and has a juvenile source. The later Th–U mineralization originated during tectonic rejuvenation of the Syulban fault zone, while the sources of radioactive elements were presumably the underlying sediments of the Kodar Group, which are widespread throughout the area of the Baikal mountain region (BMR). Based on the above results, the Au–U mineralization in the study area can be recognized as unconformity-type deposits, analogous to the well-known deposits of Australia and Canada. In this connection, the Baikal mountain region has a good potential for the discovery of Au—U deposits.  相似文献   

Upper Triassic pyritized bivalve mollusks from the Sentachan orogenic gold–antimony deposit,eastern Yakutia: Mineralogy and sulfur isotopic composition     

G. A. Pal’yanova  E. S. Sobolev  V. N. Reutsky  N. S. Bortnikov 《Geology of Ore Deposits》2016,58(6):456-464

Pyritized bivalve mollusks have been revealed for the first time in upper Norian sedimentary rocks at the large orogenic Sentachan gold–antimony deposit in eastern Yakutia. It has been established that they are related to species of the genus Monotis (M. ex gr. jacutica (Teller) (specimen no. 2077/1, CSGM) and M. pachypleura (Teller) (specimen no. 2077/2, CSGM), which existed during the Monotis densistriata phase of the Norian Age of the Triassic Epoch presumably 211.5–214 Ma ago. The occurrence of two pyrite generations differing in morphology, sulfur impurity, and isotopic compositions corroborates the suggestion that pyritization of fauna was a discrete process. It has been shown that sulfur that formed owing to bacterial sulfate reduction and interaction with organic matter was involved in the pyritization of bivalve mollusks, whereas mixing of magmatic sulfur and sulfur derived from host sedimentary rocks participated in deposition of Au–Sb ore.  相似文献   

Crystalline inclusions and C isotope ratios in diamonds from the Snap Lake/King Lake kimberlite dyke system: evidence of ultradeep and enriched lithospheric mantle   总被引：5，自引：0，他引：5  

N.P. Pokhilenko  N.V. Sobolev  V.N. Reutsky  A.E. Hall  L.A. Taylor 《Lithos》2004,77(1-4):57-67

U-type paragenesis inclusions predominate (94.7%) among the crystalline inclusion suite of 115 diamonds (−4+2 mm) obtained from the recently discovered Snap Lake/King Lake (SKL) kimberlite dyke system, Southern Slave, Canada. The most common inclusions are olivine (90) and enstatite (22). Sulfide, Cr-pyrope, chromite and Cr-diopside inclusion are less abundant (15, 10, 5 and 1, respectively). Results of the inclusion composition study demonstrate the following. (a) The relatively enriched character of the mantle parent rocks of the U-type diamonds. The average Mg# of olivine inclusions is 92.1, and of enstatite inclusions average 93.3. CaO content in Cr-pyrope inclusions is relatively high (3.73–5.75 wt.%). (b) Four of ten U-type Cr-rich pyrope inclusions contain a majoritic component up to 16.8 mol.% which requires pressures of 110 kbar. Carbon isotopes compositions for 34 diamonds with U-type inclusions have a δ¹³C range from −3.2‰ to −9‰ with a strong peak around −3.5‰. This is much heavier than the ratios of U-type diamonds from Siberia and South Africa (4.5‰). Diamonds with olivine inclusions can be divided into two groups based on their δ¹³C values as well as the Mg# and Ni/Fe ratio in the olivines. Most show a narrow range of δ¹³C values from −3.2‰ to −4.8‰ (average −3.72‰) and have olivine inclusions with Mg# less than 92.3 and relatively high Fe/Ni ratios. A second group is characterized by a much wider variation of C isotope composition (δ¹³C varies from −3.8‰ to −9.0‰, average −5.97‰), and the olivine inclusions having a higher Mg# (up to 93.6) and relatively low Fe/Ni ratios. This difference in the C isotope composition may have several explanations: (a) peculiarities of asthenosphere degassing coupled with an abnormal thickness of lithosphere; (b) the abnormal thickness and enriched character of lithospheric mantle; (c) involvement of subducted C of crustal origin in the processes of the diamond formation. The presence of subcalcic Cr-rich majorite (up to 17 mol.%) pyropes of low-Ca harzburgite paragenesis among the crystalline inclusion suite of SKL diamonds is strong evidence for the existence of diamondiferous depleted peridotite in lithospheric mantle at depth near 300 km beneath Southern Slave area and is postulated to be one of the main reasons for the much heavier C isotope composition of SKL U-type diamonds in comparison with those from Siberian and South African kimberlites.  相似文献   

Carbon isotope fractionation during experimental crystallisation of diamond from carbonate fluid at mantle conditions     

Vadim Reutsky  Yuri Borzdov  Yuri Palyanov  Alexander Sokol  Olga Izokh 《Contributions to Mineralogy and Petrology》2015,170(5-6):1-9

  相似文献   

Evidence for large scale fractionation of carbon isotopes and of nitrogen impurity during crystallization of gem quality cubic diamonds from placers of North Yakutia     

V. N. Reutsky  A. A. Shiryaev  S. V. Titkov  M. Wiedenbeck  N. N. Zudina 《Geochemistry International》2017,55(11):988-999

The spatial distribution of carbon and nitrogen isotopes and of nitrogen concentrations is studied in detail in three gem quality cubic diamonds of variety II according to Orlov’s classification. Combined with the data on composition of fluid inclusions our results point to the crystallization of the diamonds from a presumably oxidized carbonate fluid. It is shown that in the growth direction δ¹³C of the diamond becomes systematically lighter by 2–3‰ (from –13.7 to –15.6‰ for one profile and from –11.7 to –14.1‰ for a second profile). Simultaneously, we observe substantial decrease in the nitrogen concentration (from 400–1000 to 10–30 at ppm) and a previously unrecognized enrichment of nitrogen in light isotope, exceeding 30‰. The systematic and substantial changes of the chemical and isotopic composition can be explained using the Burton-Prim-Slichter model, which relates partition coefficients of an impurity with the crystal growth rate. It is shown that changes in effective partition coefficients due to a gradual decrease in crystal growth rate describes fairly well the observed scale of the chemical and isotopic variations if the diamond-fluid partition coefficient for nitrogen is significantly smaller than unity. This model shows that nitrogen isotopic composition in diamond may result from isotopic fractionation during growth and not reflect isotopic composition of the mantle fluid. Furthermore, it is shown that the infra-red absorption at 1332 сm^-1 is an integral part of the Y-defect spectrum. In the studied natural diamonds the 1290 сm^-1 IR absorption band does not correlate with boron concentration.  相似文献