Chemical Procedures for Rhenium Extraction from Geological Samples: Optimising the Anion Resin Bead Clean‐up Step     

Gang Yang  Aaron Zimmerman  Nicole C. Hurtig  Svetoslav V. Georgiev  Vineet Goswami  Judith L. Hannah  Holly J. Stein 《Geostandards and Geoanalytical Research》2020,44(2):231-242

Rhenium–osmium geochronometry for samples with low Re and complex matrices requires improved Re extraction methods. Here, we investigate plausible controls on efficiency and efficacy of Re extraction during our anion resin bead purification. Four different protocols are compared, each isolating a single variable to test. Rhenium concentrations for solutions at each step of each protocol document differences in chemical recovery/yield. The negative‐thermal ionisation mass spectrometry (N‐TIMS) signal intensity serves as a proxy for Re yield and purity. These data document correlations between the N‐TIMS signal intensity and (a) the duration of anion resin bead conditioning prior to loading with Re‐bearing solution, and (b) both duration and strength of nitric acid used during rinsing of the Re‐loaded anion resin bead. The optimal protocol improved Re signal intensity around fourteen times compared with our current Re extraction protocol, an aggregate of 2.4 times improvement in chemical recovery (yield) and 5.8 times improvement in emission efficiency (purity). Repeated N‐TIMS isotopic measurements on our in‐house Re standard solution (1407) verify that our optimal protocol‐3 does not fractionate Re isotopes. The improved anion resin bead method considerably lowers the Re detection limit and allows Re‐Os isotopic analysis of picogram‐level Re hosted in geological samples with complex matrices.  相似文献   

Holocene relative sea level history and Storegga tsunami run‐up in Lyngen,northern Norway          下载免费PDF全文

Henrik Rasmussen  Stein Bondevik  Geoffrey D. Corner 《第四纪科学杂志》2018,33(4):393-408

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Numerical modeling of cyclic mobility based on fuzzy-set concepts in plasticity theory     

Yu Bao  Stein Sture 《Computers and Geotechnics》2011

In this paper, the application of an efficient, transparent and accurate kinematic-cyclic constitutive model based on the fuzzy-set concepts and incremental plasticity theory is presented to show its capability in modeling cyclic mobility of saturated granular soil. The nature and kinematic mechanism of the membership functions in the fuzzy-set constitutive model are illustrated. The model’s capability of modeling soil dilatancy is investigated. Important features of volume change and pore water pressure build-up related to soil cyclic mobility are captured. The formulation of the proposed model is relatively simple and it can be readily implemented in finite element codes. The enhanced fuzzy-set model is capable of simulating ground motion problems particularly related to cyclic mobility, soil liquefaction, and spreading behavior.  相似文献   

Black dimensional stones: geology, technical properties and deposit characterization of the dolerites from Uruguay   总被引：1，自引：1，他引：0  

Manuela Morales Demarco  Pedro Oyhantçabal  Karl-Jochen Stein  Siegfried Siegesmund 《Environmental Earth Sciences》2011,63(7-8):1879-1909

Dimensional stones with a black color occupy a prominent place on the international market. Uruguayan dolerite dikes of andesitic and andesitic–basaltic composition are mined for commercial blocks of black dimensional stones. A total of 16 dikes of both compositions were studied and samples collected for geochemical and petrographical analysis. Color measurements were performed on different black dimensional stones in order to compare them with the Uruguayan dolerites. Samples of the two commercial varieties (Absolute Black and Moderate Black) were obtained for petrophysical analysis (e.g. density, porosity, uniaxial compressive strength, tensile strength, etc.). Detailed structural analyses were performed in several quarries. Geochemistry and petrography determines the intensity of the black color. The Uruguayan dolerite Absolute Black is the darkest black dimensional stone analyzed in this study. The petrophysical properties of Uruguayan dolerites make them one of the highest quality black dimensional stones. Structural analyses show that five joint sets have been recognized: two sub-vertical joints, one horizontal and two diagonal. These joint sets are one of the most important factors that control the deposits, since they control the block size distribution and the amount of waste material.  相似文献   

Timing of porphyry (Cu-Mo) and base metal (Zn-Pb-Ag-Cu) mineralisation in a magmatic-hydrothermal system—Morococha district,Peru     

Honza Catchpole  Kalin Kouzmanov  Aldo Bendezú  Maria Ovtcharova  Richard Spikings  Holly Stein  Lluís Fontboté 《Mineralium Deposita》2015,50(8):895-922

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Arctic sea ice and Eurasian climate: A review   总被引：12，自引：0，他引：12  

GAO Yongqi  SUN Jianqi  LI Fei  HE Shengping  Stein SANDVEN  YAN Qing  ZHANG Zhongshi  Katja LOHMANN  Noel KEENLYSIDE  Tore FUREVIK  SUO Lingling 《大气科学进展》2015,32(1):92-114

The Arctic plays a fundamental role in the climate system and has shown significant climate change in recent decades,including the Arctic warming and decline of Arctic sea-ice extent and thickness. In contrast to the Arctic warming and reduction of Arctic sea ice, Europe, East Asia and North America have experienced anomalously cold conditions, with record snowfall during recent years. In this paper, we review current understanding of the sea-ice impacts on the Eurasian climate.Paleo, observational and modelling studies are covered to summarize several major themes, including: the variability of Arctic sea ice and its controls; the likely causes and apparent impacts of the Arctic sea-ice decline during the satellite era,as well as past and projected future impacts and trends; the links and feedback mechanisms between the Arctic sea ice and the Arctic Oscillation/North Atlantic Oscillation, the recent Eurasian cooling, winter atmospheric circulation, summer precipitation in East Asia, spring snowfall over Eurasia, East Asian winter monsoon, and midlatitude extreme weather; and the remote climate response(e.g., atmospheric circulation, air temperature) to changes in Arctic sea ice. We conclude with a brief summary and suggestions for future research.  相似文献   

余震密度随距离的衰减不代表动态应力触发过程     

K.R.-Dinger  R.S.Stein  S.Toda  魏志恒  冯蔚 《世界地震译丛》2011,(3)

分辨多数余震和后续主震是由静态应力触发(Stein,1999;Todaetal,2005;Parsons,2002)还是动态应力触发(Hilletal,1993;kilb,2003;Brodsky and Prejean,2005;Gomberg and Johnson,2005;Hill and Prejean,2007),对理解地震内在作用和预测地震危险性是有必要的(Freed,2005)。Felzer和Brodsky(2006)分析了2≤M<3和3≤M<4级主震后5min内余震的空间分布情况,发现距主震50km范围内M≥2余震具有特定的幂律衰减关系,且衰减曲线的斜率为-1.35。据此,他们认为余震随距离的衰减只能用动态触发来解释。基于上述假设我们进行了一系列的检验,但没有一个可通过检验,进而,本文中对这种衰减关系提出了另外一种解释。在距离2≤M<3主震300m以外的地方,主震前5min内的地震活动性衰减与主震后5min内的衰减没有显著的区别,表明主震对它静态触发区域以外的地方没有影响。表征余震基本特性的大森随时间衰减关系在距离主震10km以外的地方是不存在的。最后,发现在主震波前未到达之前的余震中发现了...  相似文献   

Ejecta from impacts at 0.2-2.3 m/s in low gravity     

Joshua E. Colwell  Stein Sture  Dan Durda  Tyler Goudie  Daniel J. Ashcom  Thomas Keohane  Michael Lupton 《Icarus》2008,195(2):908-917

Collisions between planetary ring particles and in some protoplanetary disk environments occur at speeds below 10 m/s. The particles involved in these low-velocity collisions have negligible gravity and may be made of or coated with smaller dust grains and aggregates. We undertook microgravity impact experiments to better understand the dissipation of energy and production of ejecta in these collisions. Here we report the results of impact experiments of solid projectiles into beds of granular material at impact velocities from 0.2 to 2.3 m/s performed under near-weightless conditions on the NASA KC-135 Weightless Wonder V. Impactors of various densities and radii of 1 and 2 cm were launched into targets of quartz sand, JSC-1 lunar regolith simulant, and JSC-Mars-1 martian regolith simulant. Most impacts were at normal or near-normal incidence angles, though some impacts were at oblique angles. Oblique impacts led to much higher ejection velocities and ejecta masses than normal impacts. For normal incidence impacts, characteristic ejecta velocities increase with impactor kinetic energy, KE, as approximately KE^0.5. Ejecta masses could not be measured accurately due to the nature of the experiment, but qualitatively also increased with impactor kinetic energy. Some experiments were near the threshold velocity of 0.2 m/s identified in previous microgravity impact experiments as the minimum velocity needed to produce ejecta [Colwell, J.E., 2003. Icarus 164, 188-196], and the experimental scatter is large at these low speeds in the airplane experiment. A more precise exploration of the transition from low-ejecta-mass impacts to high-ejecta-mass impacts requires a longer and smoother period of reduced gravity. Coefficient of restitution measurements are not possible due to the varying acceleration of the airplane throughout the experiment.  相似文献   

Evaluation of bank filtration as a pretreatment method for the provision of hygienically safe drinking water in Norway: results from monitoring at two full-scale sites     

Hanne M. L. Kvitsand  Mette Myrmel  Liv Fiksdal  Stein W. Østerhus 《Hydrogeology Journal》2017,25(5):1257-1269

Two case studies were carried out in central Norway in order to assess the performance of bank filtration systems in cold-climate fluvial aquifers relying on recharge from humic-rich surface waters with moderate microbial contamination. Three municipal wells and two surface-water sources at operative bank filtration systems were monitored for naturally occurring bacteriophages, fecal indicators, natural organic matter (NOM) and physico-chemical water quality parameters during a 4-month period. Aquifer passage effectively reduced the microorganism and NOM concentrations at both study sites. Bacteriophages were detected in 13 of 16 (81%) surface-water samples and in 4 of 24 (17%) well-water samples, and underwent 3 ± 0.3 log₁₀ reduction after 50–80-m filtration and 20–30 days of subsurface passage. NOM reductions (color: 74–97%; dissolved organic carbon: 54–80%; very hydrophobic acids: 70%) were similar to those achieved by conventional water-treatment processes and no further treatment was needed. Both groundwater dilution and sediment filtration contributed to the hygienic water quality improvements, but sediment filtration appeared to be the most important process with regard to microbial and NOM reductions. A strengths-weaknesses-opportunities-threats analysis showed that bank filtration technology has a high potential as a pretreatment method for the provision of hygienically safe drinking water in Norway.  相似文献   

Late Quaternary growth and decay of the Svalbard/Barents Sea ice sheet and paleoceanographic evolution in the adjacent Arctic Ocean     

Jochen Knies  Christoph Vogt  Ruediger Stein 《Geo-Marine Letters》1998,18(3):195-202

The paleoceanography in the Nordic seas was characterized by apparently repeated switching on and off of Atlantic water advection. In contrast, a continous influx of Atlantic waters probably occurred along the northern Barents Sea margin during the last 150?ka. Temporary ice-free conditions enhanced by subsurface Atlantic water advection and coastal polynyas accelerated the final ice sheet build-up during glacial times. The virtually complete dissolution of biogenic calcite during interglacial intervals was controlled mainly by CO2-rich bottom waters and oxidation of higher levels of marine organic carbon and indicates intensive Atlantic water inflow and a stable ice margin.  相似文献