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Timon F. Fliervoet Stanley H. White Martyn R. Drury 《Journal of Structural Geology》1997,19(12):1495-1520
Microstructural and textural investigations by scanning (SEM) and transmission electron microscopy (TEM) techniques have been performed on samples taken across two quartzo-feldspathic mylonite zones from the Redbank Deformed Zone, Central Australia. One has been deformed at greenschist-facies (GS), the second at amphibolite-facies (Am), conditions. With increasing strain the rock type changes from protomylonite to mylonite to ultramylonite. The protomylonites and mylonites consist of alternating quartz and polymineralic quartz-feldspar bands. At the highest strains a homogeneous, fine-grained polymineralic ultramylonite occurs. Shear-zone geometry and microscale structures indicate that these ultramylonites experienced higher strains and were weaker than the encapsulating protomylonites and mylonites. TEM and SEM studies of the ultramylonites reveal a rectangular to square grain shape, a continuous alignment of grain and interphase boundaries across several grain diameters, a grain size (GS 0.5 μm; Am 5–11 μm) less than the equilibrium subgrain size, and open and void-containing grain and interphase boundaries. Analysis of local textures by electron back-scatter diffraction (EBSD) in the SEM showed a very weak crystallographic preferred orientation (CPO) for the quartz. The grain misorientation relationships are not consistent, with dislocation creep being the dominant deformation mechanism. All structures are of the type expected if grain-boundary sliding processes had contributed significantly to the deformation. Consequently, the deformation of such quartzo-feldspathic rocks, and by implication the rheology of the Redbank Deformed Zone, must have been controlled by the mechanical properties of these fine-grained polymineralic ultramylonites, deforming by grain-boundary sliding processes. This is in contrast to the pure quartz bands which deformed by dislocation-creep mechanisms and were less important in the rheology of the Redbank Deformed Zone. 相似文献
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V.?Botella V.?Timon E.?Escamilla-Roa A.?Hernández-Languna C.I.?Sainz-DíazEmail author 《Physics and Chemistry of Minerals》2004,31(8):475-486
The hydroxy groups of the crystal lattice of dioctahedral 2:1 phyllosilicates were investigated by means of quantum-mechanical calculation. The standard Kohn-Sham self-consistent density functional theory (DFT) method was applied using the generalized gradient approximation (GGA) with numerical atomic orbitals and double-zeta polarized functions as basis set. Isomorphous cation substitution of different cations in the octahedral and tetrahedral sheet was included along with several interlayer cations reproducing experimental crystal lattice parameters. The effect of these substitutions and the interlayer charge on the hydroxyl group properties was also studied. These structures represent different cation pairs among Al3+, Fe3+ and Mg2+ in the octahedral sheet of clays joined to OH groups. The geometrical disposition of the OH bond in the crystal lattice and the hydrogen bonds and other electrostatic interactions of this group were analyzed. The frequencies of different vibrational modes of the OH group [(OH), (OH) and (OH)] were calculated and compared with experimental data, finding a good agreement. These frequencies depend significantly on the nature of cations which are joined with, and the electrostatic interactions with, the interlayer cations. Besides, hydrogen-bonding interactions with tetrahedral oxygens are important for the vibrational properties of the OH groups; however, also the electrostatic interactions of these OH groups with the rest of tetrahedral oxygens within the tetrahedral cavity should be taken into account. The cation substitution effect on the vibration modes of the OH groups was analyzed reproducing the experimental behaviour.Dr. V. Botella passed away last February 相似文献
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Ahead of the Conference of Parties (COP) 24 where countries will first take stock of climate action post Paris, this paper assesses India’s progress on its nationally determined contribution (NDC) targets and future energy plans. We find that, although India is well on track to meet its NDC pledges, these targets were extremely modest given previous context. Furthermore, there is considerable uncertainty around India’s energy policy post 2030 and if current plans for energy futures materialise, the Paris Agreement’s 2 degrees goal will be almost certainly unachievable. India’s role in international climate politics has shifted from obstructionism to leadership particularly following the announcement of withdrawal by the United States from the Paris Agreement, but analysis reveals that India’s ‘hard’ actions on the domestic front are inconsistent with its ‘soft’ actions in the international climate policy arena. Going forward, India is likely to face increasing calls for stronger mitigation action and we suggest that this gap can be bridged by strengthening the links between India’s foreign policy ambitions, international climate commitments, and domestic energy realities.
Key policy insights
India’s NDC pledges on carbon intensity and share of non-fossil fuel capacity are relatively modest given domestic context and offer plenty of room to increase ambition of action.
India’s ‘soft’ leadership in global climate policy can be matched by ‘hard’ commitments by bringing NDC pledges in line with domestic policy realities.
There is significant uncertainty around future plans for coal power in India which have the potential to exceed the remaining global carbon budget for 2 degrees.
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