Early solar system aqueous activity: K isotope evidence from Allende     

Yun Jiang  Piers Koefoed  Olga Pravdivtseva  Heng Chen  Chun‐Hui Li  Fang Huang  Li‐Ping Qin  Jia Liu  Kun Wang 《Meteoritics & planetary science》2021,56(1):61-76

The alkali element K is moderately volatile and fluid mobile; thus, it can be influenced by both primary processes (evaporation and recondensation) in the solar nebula and secondary processes (thermal and aqueous alteration) in the parent body. Since these primary and secondary processes would induce different isotopic fractionations, K isotopes could become a potential tracer to distinguish them. Using recently developed methods with improved precision (0.05‰, 95% confidence interval), we systematically measured the K isotopic compositions and major/trace elemental compositions of chondritic components (18 chondrules, 3 CAIs, 2 matrices, and 5 bulks) in the carbonaceous chondrite fall Allende. Among all the components analyzed in this study, CAIs, which formed initially under high‐temperature conditions in the solar nebula and were dominated by nominally K‐free refractory minerals, have the highest K₂O content (average 0.53 wt%) and have K isotope compositions most enriched in heavy isotopes (δ⁴¹K: ?0.30 to ?0.25‰). Such an observation is consistent with previous petrologic studies that show CAIs in Allende have undergone alkali enrichment during metasomatism. In contrast, chondrules contain lower K₂O content (0.003–0.17 wt%) and generally lighter K isotope compositions (δ⁴¹K: ?0.87‰ to ?0.24‰). The matrix and bulks are nearly identical in K₂O content and K isotope compositions (0.02–0.05 wt%; δ⁴¹K: ?0.62 to ? 0.46‰), which are, as expected, right in the middle of CAIs and chondrules. This strongly indicates that most of the chondritic components of Allende suffered aqueous alteration and their K isotopic compositions are the ramification of Allende parent‐body processing instead of primary nebular signatures. Nevertheless, we propose the small K isotope fractionations observed (< 1‰) among Allende components are likely similar to the overall range of K isotopic fractionation that occurred in nebular environment. Furthermore, the K isotope compositions seen in the components of Allende in this study are consistent with MC‐ICP‐MS analyses of the components in ordinary chondrites, which also show an absence of large (10‰) isotope fractionations. This is not expected as evaporation experiments in nebular conditions suggest there should be large K isotopic fractionations. Nevertheless, possible nebular processes such as chondrules back exchanging with ambient gas when they formed could explain this lack of large K isotopic variation.  相似文献   

Runoff response of a small agricultural basin in the argentine Pampas considering connectivity aspects     

María Guadalupe Ares  Marcelo Varni  Celio Chagas 《水文研究》2020,34(14):3102-3119

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High‐resolution quantification of earthworm calcite granules from western European loess sequences reveals stadial–interstadial climatic variability during the Last Glacial     

Charlotte Prud'homme  Olivier Moine  Jerome Mathieu  Segolene Saulnier‐Copard  Pierre Antoine 《Boreas: An International Journal of Quaternary Research》2019,48(1):257-268

High concentrations of calcite fossil granules produced by earthworms (ECG) have been identified in most of the stratigraphical units along the loess‐palaeosol reference sequence of Nussloch (Germany). They are particularly abundant in interstadial brown soils and in tundra gley horizons, the latter reflecting short‐term phases of aggradation then degradation of permafrost. These granules are characterized by a radial crystalline structure produced in the earthworms by specific bio‐mineralization processes. In our study, we used this biological indicator combined with ¹⁴C and OSL dating, and sedimentological parameters to characterize millennial‐time scale climatic variations recorded in loess sequences. The approach is based on high‐resolution counts of ECG throughout a 17‐m‐thick loess sequence (332 samples). Strong increases in granule and mollusc concentrations suggest warmer climate conditions during palaeosol formation phases, associated with increasing biodiversity, biological activity and vegetation cover. Decreased granule concentrations occur within primary loess deposits, indicating a strong correlation with palaeoenvironmental conditions and demonstrating the reliability of ECG concentration variations as a new palaeoenvironmental proxy. Finally, this pattern is also recorded in loess sequences located about 600 km westward in northern France demonstrating the large‐scale validity of this new palaeoclimatic proxy.  相似文献   

Northwest Africa 11024—A heated and dehydrated unique carbonaceous (CM) chondrite     

Samuel Ebert  Addi Bischoff  Dennis Harries  Sarah Lentfort  Jean‐Alix Barrat  Andreas Pack  Jrme Gattacceca  Robbin Visser  Peter Schmid‐Beurmann  Stephan Kimpel 《Meteoritics & planetary science》2019,54(2):328-356

Based on the high abundance of fine‐grained material and its dark appearance, NWA 11024 was recognized as a CM chondrite, which is also confirmed by oxygen isotope measurements. But contrary to known CM chondrites, the typical phases indicating aqueous alteration (e.g., phyllosilicates, carbonates) are missing. Using multiple analytical techniques, this study reveals the differences and similarities to known CM chondrites and will discuss the possibility that NWA 11024 is the first type 3 CM chondrite. During the investigation, two texturally apparent tochilinite–cronstedtite intergrowths were identified within two thin sections. However, the former phyllosilicates were recrystallized to Fe‐rich olivine during a heating event without changing the textural appearance. A peak temperature of 400–600 °C is estimated, which is not high enough to destroy or recrystallize calcite grains. Thus, calcites were never constituents of the mineral paragenesis. Another remarkable feature of NWA 11024 is the occurrence of unknown clot‐like inclusions (UCLIs) within fine‐grained rims, which are unique in this clarity. Their density and S concentration are significantly higher than of the surrounding fine‐grained rim and UCLIs can be seen as primary objects that were not formed by secondary alteration processes inside the rims. Similarities to chondritic and cometary interplanetary dust particles suggest an ice‐rich first‐generation planetesimal for their origin. In the earliest evolution, NWA 11024 experienced the lowest degree of aqueous alteration of all known CM chondrites and subsequently, a heating event dehydrated the sample. We suggest to classify the meteorite NWA 11024 as the first type 3 CM chondrite similar to the classification of CV3 chondrites (like Allende) that could also have lost their matrix phyllosilicates by thermal dehydration.  相似文献   

Evaluation of Sludge Digester Effluent as Feeding Solution for the Enrichment of Anammox Bacteria     

&#x;pek elen‐Erdem 《洁净——土壤、空气、水》2020,48(3)

The aim of this study is to evaluate the feasibility of sludge digester effluent as feeding solution to enrich anaerobic ammonium oxidation (anammox) bacteria. The performance of the two parallel pilot scale‐upflow packed bed anammox reactors (UPBAn1 and UPBAn2) are examined in terms of the enrichment of anammox bacteria. The control experiment is set up conducting synthetic wastewater as feeding solution in the UPBAn1 reactor whereas, the sludge digester effluent is fed to the nitritation reactor and then the partially nitrated digester effluent to the UPBAn2 reactor. Anammox activities are evaluated by mass balances based on ammonium (NH₄⁺), nitrite (NO₂^?), and nitrate (NO₃^?) analysis and NRR. Microbial community of anammox bacteria is analyzed using real‐time polymerase chain reaction (PCR). The results demonstrate that UPBAn 1 and UPBAn2 reactors are successfully enriched on days 64 and 40 with NRRs of 19.54 and 19.43 g N m^?3 per day, respectively. This study reveals that both synthetic wastewater and digester effluent are suitable for the enrichment of anammox bacteria; however, digester effluent as feeding solution for enrichment of anammox bacteria based on the ease of process control and process stability is more advisable.  相似文献   

Reanalysing strong-convective wind damage paths using high-resolution aerial images     

Rodríguez  Oriol  Bech  Joan 《Natural Hazards》2020,104(1):1021-1038

Natural Hazards - High-resolution aerial imagery may provide very detailed information about strong-convective wind events, which can be very useful to enhance and make more robust severe weather...  相似文献   

An extreme wave event in eastern Yucatán,Mexico: Evidence of a palaeotsunami event during the Mayan times     

Javier Lario  Chris Spencer  Teresa Bardají  Ángel Marchante  Victor H. Garduño-monroy  Jorge Macias  Sergio Ortega 《Sedimentology》2020,67(3):1481-1504

The Yucatán Peninsula, Mexico, has typically been considered a tectonically stable region with little significant seismic activity. The region though, is one that is regularly affected by hurricanes. A detailed survey of ca 100 km of the eastern Yucatán and Cozumel coast identified the presence of ridges containing individual boulders measuring >1 m in length. The boulder ridges reach 5 m in height and their origin is associated with extreme wave event activity. Previously modelled tsunami waves from known seismically active zones in the region (Muertos Thrust Belt and South Caribbean Deformed Belt) are not of sufficient scale in the area of the Yucatán Peninsula to have produced the boulder ridges recorded in this study. The occurrence of hurricanes in this region is more common, but two of the most destructive (Hurricane Gilbert 1988 and Hurricane Wilma 2005) produced coastal waves too small to have created the ridges recorded here. In this paper, a new tsunami model with a source area located on the Motagua/Swan Island Fault System has been generated that indicates a tsunami event may have caused the extreme wave events that resulted in the deposition of the boulder ridges.  相似文献   

Temporal and spatial variation of soil erosion in wooded rangelands of southwest Spain     

Judit Rubio-Delgado  Susanne Schnabel  Álvaro Gómez-Gutiérrez  Joaquín Francisco Lavado-Contador 《地球表面变化过程与地形》2019,44(11):2141-2155

Changes in land use are common in Mediterranean areas and are reported as having produced changes in the intensity of soil erosion. Dehesas are rangelands with a disperse tree cover, widespread in the south-western part of the Iberian Peninsula and similar ecosystems are also common in other areas with a Mediterranean climate. The aim of the present study is to analyse temporal and spatial variations of soil erosion rates estimated along three hillsides, located in two farms (Buitrera and Parapuños) in southwest Spain. To understand the temporal variation, soil erosion rates were studied in light of land use-management changes that took place during the last few centuries. Results indicate very low erosion rates prior to the 18^th century in both farms. In Buitrera, a first increase of soil loss rates was identified during the period 1831-1897, amounting to 7.4 t ha^-1 y^-1. A further increase took place during the 20^th century, reaching a mean erosion rate of 29.1 t ha^-1 y^-1. In Parapuños, data points to a significant increase from 1881 onwards, with an estimated mean erosion rate of 18.5 t ha^-1 y^-1. Those increases were presumably connected with an intensification of land use, such as cultivation and excessive livestock populations. Regarding spatial variation, the bare surface and the erosive power of run-off along the hillsides accounts for 76% of the soil erosion rates dispersion. At a local scale, the variability of erosion rates could not be explained, because of (i) uncertainty related to the micromorphology of the past soil surface and (ii) the role of tillage erosion in the past. However, the results obtained offer valuable data on the temporal and spatial variation of erosion rates in dehesas at the hillslope scale and a similar approach could be used for other rangelands with a disperse tree cover. © 2019 John Wiley & Sons, Ltd.  相似文献   

Clinoform architecture and along‐strike facies variability through an exhumed erosional to accretionary basin margin transition     

Miquel Poyatos‐Mor  George D. Jones  Rufus L. Brunt  Daniel E. Tek  David M. Hodgson  Stephen S. Flint 《Basin Research》2019,31(5):920-947

Exhumed basin margin‐scale clinothems provide important archives for understanding process interactions and reconstructing the physiography of sedimentary basins. However, studies of coeval shelf through slope to basin‐floor deposits are rarely documented, mainly due to outcrop or subsurface dataset limitations. Unit G from the Laingsburg depocentre (Karoo Basin, South Africa) is a rare example of a complete basin margin scale clinothem (>60 km long, 200 m‐high), with >10 km of depositional strike control, which allows a quasi‐3D study of a preserved shelf‐slope‐basin floor transition over a ca. 1,200 km² area. Sand‐prone, wave‐influenced topset deposits close to the shelf‐edge rollover zone can be physically mapped down dip for ca. 10 km as they thicken and transition into heterolithic foreset/slope deposits. These deposits progressively fine and thin over tens of km farther down dip into sand‐starved bottomset/basin‐floor deposits. Only a few km along strike, the coeval foreset/slope deposits are bypass‐dominated with incisional features interpreted as minor slope conduits/gullies. The margin here is steeper, more channelized and records a stepped profile with evidence of sand‐filled intraslope topography, a preserved base‐of‐slope transition zone and sand‐rich bottomset/basin‐floor deposits. Unit G is interpreted as part of a composite depositional sequence that records a change in basin margin style from an underlying incised slope with large sand‐rich basin‐floor fans to an overlying accretion‐dominated shelf with limited sand supply to the slope and basin floor. The change in margin style is accompanied with decreased clinoform height/slope and increased shelf width. This is interpreted to reflect a transition in subsidence style from regional sag, driven by dynamic topography/inherited basement configuration, to early foreland basin flexural loading. Results of this study caution against reconstructing basin margin successions from partial datasets without accounting for temporal and spatial physiographic changes, with potential implications on predictive basin evolution models.  相似文献   

Phycoremediation of Hazardous Mixed Industrial Effluent by a Marine Strain of Phormidium sp     

Naseera Kottangodan  Cindrella Das  Anirudh Ram  Ram Murti Meena  Nagappa Ramaiah 《洁净——土壤、空气、水》2019,47(6)

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