Disentangling Turbulent Gas Diffusion from Non-diffusive Transport in the Boundary Layer     

Kowalski  Andrew S.  Serrano-Ortiz  Penélope  Miranda-García  Gabriela  Fratini  Gerardo 《Boundary-Layer Meteorology》2021,179(3):347-367

Boundary-Layer Meteorology - An analysis based on the law of linear momentum conservation demonstrates unequivocally that the mass fraction is the scalar whose gradient determines gas diffusion,...  相似文献   

Mg-enriched erythrite from Bou Azzer,Anti-Atlas Mountains,Morocco: geochemical and spectroscopic characteristics     

Dumańska-Słowik  Magdalena  Pieczka  Adam  Natkaniec-Nowak  Lucyna  Kunecki  Piotr  Gaweł  Adam  Heflik  Wiesław  Smoliński  Wojciech  Kozub-Budzyń  Gabriela 《Mineralogy and Petrology》2018,112(3):381-392

Mineralogy and Petrology - Supergene Mg-enriched erythrite, with an average composition (Co2.25Mg0.58Ni0.14Fe0.04Mn0.02 Zn0.02) (As1.97P<0.01O8)·8H2O, accompanied by skutterudite,...  相似文献   

Post-cyclone emergency services: a cost–benefit analysis for Cairns,Australia     

Leo Dobes  Gabriela Scheufele  Jeff Bennett 《Natural Hazards》2015,75(1):869-886

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Taxonomic analysis of the Quaternary archaeofauna found at The Lapa do Santo site,Lagoa Santa region,Brazil     

Artur Chahud  Gisele Ferreira Figueiredo  Gabriela Sartori Mingatos  Mercedes Okumura 《第四纪科学杂志》2021,36(7):1268-1278

The Lapa do Santo archaeological site, located in the Lagoa Santa region, Brazil, represents an important hunter-gatherer occupation dated from the Early and Middle Holocene. Prior studies of archaeofauna dating to this period are few and most of them only provide basic faunal identification with limited information on taphonomic processes. The main goal of this study is to identify the archaeofauna, record the taphonomic processes, and make inferences about its natural (interpreted as the death of the animal in the rockshelter area due to natural causes or due to predation) or anthropic origins. No extinct species (including megamastofauna) were identified. Taxonomic analysis indicated that most faunal remains consist of taxa that may be of mixed origin (natural or anthropic), such as microvertebrates and carnivorous mammals. The Cervidae are the main vertebrate family found in the studied material and these are likely the result of hunting. The Cervidae Ozotoceros support the presence of a fauna that is typical of savannah environments, although the assemblage contains mostly generalist fauna that can thrive in a variety of environments. Very few remains showed clear evidence for taphonomic processes related to human interaction, such as burnt bones.  相似文献   

A global model study of natural bromine sources and the effects on tropospheric chemistry using MOZART4     

Gabriela Sousa Santos  Sebastian Rast 《Journal of Atmospheric Chemistry》2013,70(1):69-89

Halogens in the atmosphere chemically destroy ozone. In the troposphere, bromine has higher ozone destruction efficiency than chlorine and is the halogen species with the widest geographical spread of natural sources. We investigate the relative strength of various sources of reactive tropospheric bromine and the influence of bromine on tropospheric chemistry using a 6-year simulation with the global chemistry transport model MOZART4. We consider the following sources: short-lived bromocarbons (CHBr₃, CH₂BrCl, CHBr₂Cl, CHBrCl₂, and CH₂Br₂) and CH₃Br, bromine from airborne sea salt particles, and frost flowers and sea salt on or in the snowpack in polar regions. The total bromine emissions in our simulations add up to 31.7 Gmol(Br)/yr: 63 % from polar sources, 24.6 % from short-lived bromocarbons and 12.4 % from airborne sea salt particles. We conclude from our analysis that our global bromine emission is likely to be on the lower end of the range, because of too low emissions from airborne sea salt. Bromine chemistry has an effect on the oxidation capacity of the troposphere, not only due to its direct influence on ozone concentrations, but also by reactions with other key chemical species like HO _x and NO _x . Globally, the impact of bromine chemistry on tropospheric O₃ is comparable to the impact of gas-phase sulfur chemistry, since the inclusion of bromine chemistry in MOZART4 leads to a decrease of the O₃ burden in the troposphere by 6 Tg, while we get an increase by 5 Tg if gas-phase sulfur chemistry is switched off in the standard model. With decreased ozone burden, the simulated oxidizing capacity of the atmosphere decreases thus affecting species associated with the oxidation capacity of the atmosphere (CH₃OOH, H₂O₂).  相似文献   

Analysis of three-component ambient vibration array measurements   总被引：1，自引：0，他引：1  

Donat Fäh  Gabriela Stamm  Hans-Balder Havenith 《Geophysical Journal International》2008,172(1):199-213

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The Seashell Wastes as Biosorbent for Reactive Dye Removal from Textile Effluents     

Daniela Suteu  Doina Bilba  Magdalena Aflori  Florica Doroftei  Gabriela Lisa  Marinela Badeanu  Teodor Malutan 《洁净——土壤、空气、水》2012,40(2):198-205

This study investigates structural and adsorption properties of the powdered waste shells of Rapana gastropod and their use as a new cheap adsorbent to remove reactive dye Brilliant Red HE‐3B from aqueous solutions under batch conditions. For the powder shells characterization, solubility tests in acidic solutions and X‐ray diffraction (XRD), scanning electron microscopy (SEM), energy‐dispersive X‐ray spectroscopy (EDX), Fourier transform IR spectroscopy (FT‐IR) and thermogravimetric analyses were performed. The results revealed that the adsorbent surface is heterogeneous consisting mainly from calcium carbonate layers (either calcite or aragonite) and a small amount of organic macromolecules (proteins and polysaccharides). The dye adsorptive potential of gastropod shells powder was evaluated as function of initial solution pH (1–5), adsorbent dose (6–40 g L^?1), dye concentration (50–300 mg L^?1), temperature (5–60°C), and contact time (0–24 h). It was observed that the maximum values of dye percentage removal were obtained at the initial pH of solution 1.2, shells dose of 40 g L^?1, dye initial concentration of 50–50 mg L^?1 and higher temperatures; the equilibrium time decreases with increasing of dye concentration. It is proved that the waste seashell powder can be used as low cost bioinorganic adsorbent for dyes removal from textile wastewaters.  相似文献   

Groundwater geochemistry of the Chihuahua City region in the Rio Conchos Basin (northern Mexico) and implications for water resources management     

Jürgen Mahlknecht  Axel Horst  Gabriela Hernández-Limón  Ramon Aravena 《水文研究》2008,22(24):4736-4751

The Chihuahua City region, located in the semiarid-arid northern highlands of Mexico, has experienced intensive groundwater abstraction during the last 40 years to meet water demands in the region. A geochemical survey was carried out to investigate the evolution from baseline to modern conditions of a 130-km flow path including the El Sauz–Chihuahua–Aldama–San Diego de Alcalá regions. The research approach included the use of major chemical elements, chlorofluorocarbons and environmental isotope (¹⁸O, ²H, ¹³C and ¹⁴C) tracers. Stable isotopes indicate that groundwater evolves from the evaporation of local rainfall and surface water. Groundwater located at the lower end of the flow section is up to 6000 years old and older groundwater in the order of 9000 years BP was found in a deep well located in the upper part of the flow system, implying contribution from a neighbour basin. The background groundwater chemistry upstream of Chihuahua City results from feldspar weathering. Beyond Chihuahua City the chemical conditions are strongly modified owing to disposal of sewage from public and industrial water supplies into the Rio Chuviscar, subsequent allocation of this water to agricultural irrigation areas and direct infiltration under the river bed. As a consequence, anions like chloride and sulphate are mainly related to surface sources. Nitrate is controlled in part by sewage from public supply and industry and in part by agricultural practices. Arsenic and fluoride are related to weathering of rock formations of local mineralized ranges and subsequent enrichment of the basin-fill by magmatic processes. The results of this study have implications for groundwater management in an arid region that depends entirely on groundwater for domestic, industrial and agricultural water consumption. Copyright © 2008 John Wiley & Sons, Ltd.  相似文献   

A GIS-based WFD oriented typology of shallow micro-tidal soft bottom using wave exposure and turbidity mapping     

Jacek Andrzej Urbański  Gabriela GruszaNatalia Chlebus  Lucyna Kryla 《Estuarine, Coastal and Shelf Science》2008

Our GIS based project aims at producing a classification scheme to develop a typology of the bottom of the Bay of Gdansk in the southern Baltic. The typology was based on the abiotic factors which are used to define water body types by the European Water Framework Directive (WFD). Significance analysis of particular factors has shown that within the discussed area wave exposure seems to play the most important role. All other factors are to a greater or lesser degree correlated with these two. Taking into consideration the shallows and the varied coastline of the investigated area it was decided to make use of the SWAN numerical wave model to determine the influence of wave impact upon the bottom. The model was used to produce raster maps of orbital velocity near the bottom for each wind scenario. With the help of the GIS analysis the maps were turned into layers: the mean velocity and the maximum velocity at the bottom. To produce the layer of yearly amount of solar radiation a GIS model was built which main parameters were the layer of depth and three layers of turbidity for three seasons. The layers of the maximum orbital velocity and of the solar radiation at the bottom were then used in a classificatory procedure consisted in an iterative sequence of the three following steps: cluster formation, dendrogram analysis and classification using the maximum likelihood method. Ecological importance of the classification has been obtained by means of the aggregation of a part of classes based upon the statistics calculated for them within the GIS system with the help of the zonal function out of the following parameters: salinity, depth, mean and maximum orbital velocity at the bottom, temperature differences between warm and cold seasons, solar radiation, and type of sediments. The method proposed here makes it possible to produce high resolution thematic maps of the bottom even with incomplete data cover of the investigated area.  相似文献   

Continuous fluorescence assessment of organic matter variability on the Bournbrook River,Birmingham, UK     

Elfrida M. Carstea  Andy Baker  Gabriela Pavelescu  Ian Boomer 《水文研究》2009,23(13):1937-1946

Continuous monitoring of dissolved organic matter (DOM) character and concentration at hourly resolution is rare, despite the importance of analysing organic matter variability at high‐temporal resolution to evaluate river carbon budgeting, river water health by detecting episodic pollution and to determine short‐term variations in chemical and ecological function. The authors report a 2‐week experiment performed on DOM sampled from Bournbrook, Birmingham, UK, an urban river for which spectrophotometric (fluorescence, absorbance), physiochemical (dissolved organic carbon [DOC], electrical conductivity, pH) and isotopic (D/H) parameters have been measured at hourly frequency. Our results show that the river had sub‐daily variations in both organic matter concentration and characteristics. In particular, after relatively high‐magnitude precipitation events, organic carbon concentration increased, with an associated increase in intensity of both humic‐like and tryptophan‐like fluorescence. D/H isotopic ratio demonstrates different hydrological responses to different rainfall events, and organic matter character reflects this difference. Events with precipitation < 2 mm typically yielded isotopically heavy water with relatively hydrophilic DOM and relatively low specific absorbance. Events with precipitation > 2 mm had isotopically lighter water with higher specific absorbance and a decrease in the proportion of microbially derived to humic‐like fluorescence. In our heavily urbanized catchment, we interpret these signals as one where riverine DOM is dominated by storm sewer‐derived ‘old’ organic matter at low‐rainfall amounts and a mixed signal at high‐precipitation amounts where ‘event’ surface runoff‐derived organic matter dominate during storm sewer and combined sewer overflow routed DOM. Copyright © 2009 John Wiley & Sons, Ltd.  相似文献