A POORLY GRAPHITISED CARBON CONTAMINANT IN STUDIES OF EXTRATERRESTRIAL MATERIALS     

Frans J.M. Rietmeijer 《Meteoritics & planetary science》1985,20(1):43-48

Poorly-graphitised carbon particles are formed during manufacture of sample substrates (holey carbon films) for Analytical Electron Microscopy studies of small particles. The particles form during heat treatment of cellulose acetobutyrate at about 975 °C and 1050 °C. In AEM studies of fine-grained carbonaceous extraterrestrial materials, these particles are easily recognised.  相似文献   

Depths of Partial Crystallization of H2O-bearing MORB: Phase Equilibria Simulations of Basalts at the MAR near Ascension Island (7 11{degrees}S)     

Almeev  Renat; Holtz  Francois; Koepke  Jurgen; Haase  Karsten; Devey  Colin 《Journal of Petrology》2008,49(1):25-45

Phase equilibria simulations were performed on naturally quenchedbasaltic glasses to determine crystallization conditions priorto eruption of magmas at the Mid-Atlantic Ridge (MAR) east ofAscension Island (7–11°S). The results indicate thatmid-ocean ridge basalt (MORB) magmas beneath different segmentsof the MAR have crystallized over a wide range of pressures(100–900 MPa). However, each segment seems to have a specificcrystallization history. Nearly isobaric crystallization conditions(100–300 MPa) were obtained for the geochemically enrichedMORB magmas of the central segments, whereas normal (N)-MORBmagmas of the bounding segments are characterized by polybariccrystallization conditions (200–900 MPa). In addition,our results demonstrate close to anhydrous crystallization conditionsof N-MORBs, whereas geochemically enriched MORBs were successfullymodeled in the presence of 0·4–1 wt% H₂O in theparental melts. These estimates are in agreement with direct(Fourier transform IR) measurements of H₂O abundances in basalticglasses and melt inclusions for selected samples. Water contentsdetermined in the parental melts are in the range 0·04–0·09and 0·30–0·55 wt% H₂O for depleted and enrichedMORBs, respectively. Our results are in general agreement (within±200 MPa) with previous approaches used to evaluate pressureestimates in MORB. However, the determination of pre-eruptiveconditions of MORBs, including temperature and water contentin addition to pressure, requires the improvement of magma crystallizationmodels to simulate liquid lines of descent in the presence ofsmall amounts of water. KEY WORDS: MORB; Mid-Atlantic Ridge; depth of crystallization; water abundances; phase equilibria calculations; cotectic crystallization; pressure estimates; polybaric fractionation  相似文献   

Imposing Age and Spatial Structures on Inadequate Migration‐Flow Datasets*     

Andrei Rogers  Frans Willekens  James Raymer 《The Professional geographer》2003,55(1):56-68

With the elimination of the long‐form questionnaire from future decennial censuses and its replacement by a much smaller continuous monthly sampling survey (the American Community Survey), students of territorial mobility may find it necessary to deal with inadequate, missing, or inaccurate sample data on migration by adopting an approach that “improves” such data using information from different geographical areas, time periods, and data sources. We develop such an approach in this article and illustrate it with interregional migration flow data reported by the U.S. decennial censuses of 1980 and 1990 and by the 1985 Current Population Survey.  相似文献   

Correction of the paper “A study of meteorite falls”     

Frans E Wickman  Carl D Palmer 《Journal of Earth System Science》1985,94(2):185-186

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Understanding the mechanisms of formation of nanophase compounds from Stardust: Combined experimental and observational approach     

Neyda M. ABREU  Frans J. M. RIETMEIJER  Joseph A. NUTH III 《Meteoritics & planetary science》2011,46(8):1082-1096

Abstract– We have experimentally produced nanophase sulfide compounds and magnetite embedded in Si‐rich amorphous materials by flash‐cooling of a gas stream. Similar assemblages are ubiquitous, and often dominant components of samples of impact‐processed silica aerogel tiles and submicron grains from comet 81P/Wild 2 were retrieved by NASA’s Stardust mission. Although the texture and compositions of nanosulfide compounds have been reproduced experimentally, the mechanisms of formation of these minerals and their relationship with the surrounding amorphous materials have not been established. In this study, we present evidence that both of these materials may not only be produced through cooling of a superheated liquid but they may have also been formed simultaneously by flash‐cooling and subsequent deposition of a gas dominated by Fe‐S‐SiO‐O₂. In a dust generator at the Goddard Space Flight Center, samples are produced by direct gas‐phase condensation from gaseous precursors followed by deposition, which effectively isolates the effects of gas‐phase reactions from the effects of melting and condensation. High‐resolution transmission electron microscopy images and energy‐dispersive spectroscopy analysis show that these experiments replicate key features of materials from type B and type C Stardust tracks, including textures, distribution of inclusions, nanophase size, and compositional diversity. We argue that gas‐phase reactions may have played a significant role in the capture environment for nanophase materials. Our results are consistent with a potential progenitor assemblage of micron and submicron‐sized sulfides and submicron silica‐bearing phases, which are commonly observed in chondritic interplanetary dust particles and in the matrices of the most pristine chondritic meteorites.  相似文献   

CM-like interplanetary dust particles in lower stratosphere during 1989 October and 1991 June/July     

Frans J. M. Rietmeijer 《Meteoritics & planetary science》1996,31(2):278-288

Abstract— The stratospheric interplanetary dust particles L2005T12 and L2011O3 are linked to CM chondrite matrix. Particle L2005T12 is dominated by tabular grains of partially dehydrated greenalite-rich serpentine. Its amorphous matrix contains abundant smectite nanocrystals and annular Fe, Ni, S units. A uniquely stratified (partial) maghémite rim occurs only on S-rich parts of the matrix. Formation of this rim and Mg depletions in the matrix occurred during atmospheric entry heating of this particle. Particle L2011O3 has large iron sulfide and magnesiowüstite grains in an amorphous low-Al, ferromagnesiosilica matrix. Hydrous crystallisation of this matrix produced ultrafine-grained smectites and disseminated iron sulfides. Atmospheric entry heating of both particles is indicated by the partial iron oxide rim, vesicular sulfides, and the scatter of matrix compositions due to loss of Mg. While many uncertainties remain, the high incidence of chondritic rough particles, which include an unknown amount of CM-like particles, in the lower stratosphere during 1984, 1989, and 1991 suggests annual variations in their abundances. The timing of lower stratospheric dust samplings is critical to collect these particles.  相似文献   

Measuring channel and gully cross-sections with an airborne laser altimeter     

Jerry C. Ritchie  Earl H. Grissinger  Joseph B. Murphey  Jurgen D. Garbrecht 《水文研究》1994,8(3):237-243

A laser altimeter, making 4000 measurements per second, was used to measure channel and gully morphology. The laser measurements provide quick, accurate and readily obtained data on the cross-section and morphology of channels and gullies in relation to the adjacent landscape. Although ground based techniques can be used to make these measurements, using a laser altimeter mounted in an aircraft allows data to be collected faster, with greater density and detail, and in areas with limited access for ground surveys. The laser altimeter data are valuable for measuring channel and gully cross-sections and roughness in relation to the surrounding landscape, for assessing soil loss from gullies and channels, and for providing input to the understanding of gully and channel dynamics in the landscape.  相似文献   

Are crystalline C-(H-O-N) carbons the elusive meteoritic carbynes?     

Frans J. M. Rietmeijer 《Meteoritics & planetary science》1993,28(2):242-245

Abstract I present an internally consistent reinterpretation of carbyne diffraction data making a few plausible assumptions. The results support that carbynes could be crystalline, randomly interstratified (or mixed-layered) carbons with variable C/(C+H+O+N) ratios rather than thermodynamically stable carbon allotropes. The metastable carbynes are likely the result of incomplete, kinetically-inhibited, low-temperature pyrolysis of precursor material. A renewed interest in meteoritic carbynes should seek to combine light-element chemistry and crystallography of these elusive carbons.  相似文献   

The ultrafine mineralogy of a molten interplanetary dust particle as an example of the quench regime of atmospheric entry heating     

Frans J. M. Rietmeijer 《Meteoritics & planetary science》1996,31(2):237-242

Abstract— Melting and degassing of interplanetary dust particle L2005B22 at ～1200 °C was due to flash heating during atmospheric entry. Preservation of the porous particle texture supports rapid quenching from the peak heating temperature whereby olivine and pyroxene nanocrystals (3 nm-26 nm) show partial devitrification of the quenched melt at T ? 450 °C–740 °C. The implied ultrahigh cooling rates are calculated at ～105 °C/h–106 °C/h, which is consistent with quench rates inferred from the temperature-time profiles based on atmospheric entry heating models. A vesicular rim on a nonstoichiometric relic forsterite grain in this particle represents either evaporative magnesium loss during flash heating or thermally annealed ion implantation texture.  相似文献   

Tin in a chondritic interplanetary dust particle     

Frans J. M. Rietmeijer 《Meteoritics & planetary science》1989,24(1):43-47

Abstract— Submicron platey Sn-rich grains are present in chondritic porous interplanetary dust particle (IDP) W7029^*A and it is the second occurrence of a tin mineral in a stratospheric micrometeorite. Selected Area Electron Diffraction data for the Snrich grains match with Sn₂O₃ and Sn₃O₄. The oxide(s) may have formed in the solar nebula when tin metal catalytically supported reduction of CO or during flash heating on atmospheric entry of the IDP. The presence of tin is consistent with enrichments for other volatile trace elements in chondritic IDPs and may signal an emerging trend towards non-chondritic volatile element abundances in chondritic IDPs. The observation confirms small-scale mineralogical heterogeneity in fine-grained chondritic porous interplanetary dust.  相似文献