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Astrid Holzheid Marina V. Charykova Vladimir G. Krivovichev Brendan Ledwig Elena L. Fokina Ksenia L. Poroshina Natalia V. Platonova Vladislav V. Gurzhiy 《Chemie der Erde / Geochemistry》2018,78(2):228-240
Any progress in our understanding of low-temperature mineral assemblages and of quantitative physico-chemical modeling of stability conditions of mineral phases, especially those containing toxic elements like selenium, strongly depends on the knowledge of structural and thermodynamic properties of coexisting mineral phases. Interrelation of crystal chemistry/structure and thermodynamic properties of selenium-containing minerals is not systematically studied so far and thus any essential generalization might be difficult, inaccurate or even impossible and erroneous. Disagreement even exists regarding the crystal chemistry of some natural and synthetic selenium-containing phases. Hence, a systematic study was performed by synthesizing ferric selenite hydrates and subsequent thermal analysis to examine the thermal stability of synthetic analogues of the natural hydrous ferric selenite mandarinoite and its dehydration and dissociation to unravel controversial issues regarding the crystal chemistry. Dehydration of synthesized analogues of mandarinoite starts at 56–87?°C and ends at 226–237?°C. The dehydration happens in two stages and two possible schemes of dehydration exist: (a) mandarinoite loses three molecules of water in the first stage of the dehydration (up to 180?°C) and the remaining two molecules of water will be lost in the second stage (>180?°C) or (b) four molecules of water will be lost in the first stage up to 180?°C and the last molecule of water will be lost at a temperature above 180?°C. Based on XRD measurements and thermal analyses we were able to deduce Fe2(SeO3)3·(6-x)H2O (x?=?0.0–1.0) as formula of the hydrous ferric selenite mandarinoite. The total amount of water apparently affects the crystallinity, and possibly the stability of crystals: the less the x value, the higher crystallinity could be expected. 相似文献
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G. A. Cherkashev V. N. Ivanov V. I. Bel’tenev L. I. Lazareva I. I. Rozhdestvenskaya M. L. Samovarov I. M. Poroshina M. B. Sergeev T. V. Stepanova I. G. Dobretsova V. Yu. Kuznetsov 《Oceanology》2013,53(5):607-619
The optimal set of prospecting methods, including geophysical (geoelectrical), geological (mineralogical-geochemical), and hydrological observations, was developed during the long-term investigations of the sulfide mineralization in the northern equatorial zone of the Mid-Atlantic Ridge. The application of these methods made it possible to discover six massive sulfide deposits and considerably extend the boundaries of another two ore objects. The ores associated with ultramafic rocks are characterized by elevated Cu, Au, and Co concentrations. It is established that the ore formation was a multistage process that resulted in the accumulation of large deposits (over 10 million tons). 相似文献
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The role of the Spitsbergen shear zone in determining morphology,segmentation and evolution of the Knipovich Ridge 总被引：1，自引：1，他引：1
Crane Kathleen Doss Hany Vogt Peter Sundvor Eirik Cherkashov Georgy Poroshina Irina Joseph Devorah 《Marine Geophysical Researches》2001,22(3):153-205
In 1989–1990 the SeaMARC II side-looking sonar and swath bathymetric system imaged more than 80 000 km2 of the seafloor in the Norwegian-Greenland Sea and southern Arctic Ocean. One of our main goals was to investigate the morphotectonic
evolution of the ultra-slow spreading Knipovich Ridge from its oblique (115° ) intersection with the Mohns Ridge in the south
to its boundary with the Molloy Transform Fault in the north, and to determine whether or not the ancient Spitsbergen Shear
Zone continued to play any involvement in the rise axis evolution and segmentation.
Structural evidence for ongoing northward rift propagation of the Mohns Ridge into the ancient Spitsbergen Shear Zone (forming
the Knipovich Ridge in the process) includes ancient deactivated and migrated transforms, subtle V-shaped-oriented flank faults
which have their apex at the present day Molloy Transform, and rift related faults that extend north of the present Molloy
Transform Fault. The Knipovich Ridge is segmented into distinct elongate basins; the bathymetric inverse of the very-slow
spreading Reykjanes Ridge to the south. Three major fault directions are detected: the N-S oriented rift walls, the highly
oblique en-echelon faults, which reside in the rift valley, and the structures, defining the orientation of many of the axial
highs, which are oblique to both the rift walls and the faults in the axial rift valley.
The segmentation of this slow spreading center is dominated by quasi stationary, focused magma centers creating (axial highs)
located between long oblique rift basins. Present day segment discontinuities on the Knipovich Ridge are aligned along highly
oblique, probably strike-slip faults, which could have been created in response to rotating shear couples within zones of
transtension across the multiple faults of the Spitsbergen Shear Zone. Fault interaction between major strike slip shears
may have lead to the formation of en-echelon pull apart basins. The curved stress trajectories create arcuate faults and subsiding
elongate basins while focusing most of the volcanism through the boundary faults. As a result, the Knipovich Ridge is characterized
by Underlapping magma centers, with long oblique rifts.
This style of basin-dominated segmentation probably evolved in a simple shear detachment fault environment which led to the
extreme morphotectonic and geophysical asymmetries across the rise axis. The influence of the Spitsbergen Shear Zone on the
evolution of the Knipovich Ridge is the primary reason that the segment discontinuities are predominantly volcanic.
Fault orientation data suggest that different extension directions along the Knipovich Ridge and Mohns Ridge (280° vs. 330°,
respectively) cause the crust on the western side of the intersection of these two ridges to buckle and uplift via compression
as is evidenced by the uplifted western wall province and the large 60 mGal free air gravity anomalies in this area.
In addition, the structural data suggest that the northwards propagation of the spreading center is ongoing and that a `normal'
pure shear spreading regime has not evolved along this ridge.
This revised version was published online in November 2006 with corrections to the Cover Date. 相似文献
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A. L. Poroshina 《Astronomy Letters》2013,39(12):876-881
The ephemerides of satellites of major planets are needed in planning spacecraft missions both for studying the satellites themselves and for navigational support during the flights of spacecraft in the vicinity of planets. In addition, accurate numerical theories of motion of the natural satellites of major planets make it possible to increase the accuracy of the ephemerides of their central planets based on positional (photographic and CCD) observations of the satellites. Numerical theories of Neptune’s satellites, Triton and Nereid, constructed within the framework of the ERA software package developed at the Institute of Applied Astronomy of the Russian Academy of Sciences are presented. 相似文献
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Sergey Krasnov Irina Poroshina Georgiy Cherkashev Evgeniy Mikhalsky Mikhail Maslov 《Marine Geophysical Researches》1997,19(4):287-317
The morphotectonic setting of the East Pacific Rise (EPR) between21°12 and 22°40 S and its recent and past hydrothermalactivity were the focus of the Russian R/V Geolog Fersmans expeditionin 1987–1988.The EPR axial zone in the study area is comprised of three segmentsseparated by overlapping spreading centers (OSCs) near 21°44 and22°08 S. The northern segment is the shallowest of three and hasa distinct massive axial ridge, trapeziodal in cross-section, toppedby a very wide flat summit surface and cut by a well-developedcentral graben. These features testify to intense magmatism and to avoluminous crustal magmatic chamber underlying the whole segment.Fine-scale segmentation is most clearly revealed in the structure ofthe central graben within which several 4th-order segments can bedistinguished. This scale of segmentation is also reflected on flanks of theaxis by variations in the character and intensity of faulting.According to structural and petrologic data, the magmatism is mostintense in the central part of the segment which is probably locateddirectly over a magmatic diapir supplying the melt to the whole segment.Magma migration at the subcrustal level from the center towards the ends ofthe segment with discrete injection into the crustal magmatic chamber ispresumed.The central segment is broken into two morphologically distinct partsseparated by a deval. In the subsided northern part, the wide summit of theaxial ridge is cut by a well-developed, intensely fractured axialgraben. In the southern part, the axial ridge is relatively elevated, butnarrow with an ephemeral graben along its crest. The character and intensityof faulting on the axial flanks are also considerably different in thenorthern and southern parts of the segment. Thus, the magmatic supply tothese two parts is thought to originate from two different sources. If so,then at present the magma chamber underlying the southern part of thesegment is probably at the stage of replenishment, while in the north it isat the stage of deep cooling.The southern segment is structurally similar to the central one. Howeverthere is considerably less intensive magmatic activity in this region,especially south of 22°30 S where the axial ridge is narrow, andtriangular in cross-section.Both OSCs studied are marked by abrupt narrowing and sharp subsidence ofthe tips of axial ridges within the northern limbs. The southern OSC limbsare morphologically similar to normal sections of axial ridges. In bothcases the flanks are structurally and morphologically disrupted adjacent tothe OSCs and oblique structures can be traced far southward of the OSCflanks. Due to the spatial position of oblique structures on the the flanksit is presumed that the OSC near 22°07 S is migrating northward.The 21°44 S OSC zone has apparently undergone small spatialoscillations. In spite of the small amplitude of lateral displacement, thiszone is marked by prominent bathymetric anomalies.Numerous massive sulfide deposits were discovered atop the axial ridgealong the entire length of the uplifted and hydrothermally active northernsegment. Ore metal concentrations in near-bottom waters are maximumover the southern part of the northern segment, while maximum concentrationsof the same metals in surficial sediments are confined to the central partof the same segment. We surmise that there has been a recentalong-axis shift of the zone of maximum hydrothermal activity fromthe middle of the segment to its present position in the southern part ofthe segment. Considering sedimentation rates, the age of this shift can beapproximately estimated to be 5 to 10 thousand years before the present.The relatively Mg-enriched basalts of the middle part of thenorthern segment represent a tike of a more primitive pattern, while therelatively Fe-rich rocks of its southern part probably reflect alarge degree of fractionation at shallow crustal levels. Considering thistrend, in addition to morphotectonic data we presume that subaxial magmaflow from the middle to the southern part of the segment is responsible forthe along-axis shift of hydrothermal activity.In the central segment of the study area, massive sulfides have only beendiscovered south of the 21°55 S deval, where the axial ridgeshoals and where the existence of a subjacent magma chamber is presumed.The very weak manifestations of recent volcanism within the southernsegment explain the absence of hydrothermal activity and sulfide depositswithin this segment. 相似文献
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