A comparative study of the modelling of cement hydration and cement-rock laboratory experiments     

David Savage  Josep M. SolerKohei Yamaguchi  Colin WalkerAkira Honda  Manabu InagakiClaire Watson  James WilsonSteven Benbow  Irina GausJoerg Rueedi 《Applied Geochemistry》2011,26(7):1138-1152

The use of cement and concrete as fracture grouting or as tunnel seals in a geological disposal facility for radioactive wastes creates potential issues concerning chemical reactivity. From a long-term safety perspective, it is desirable to be able model these interactions and changes quantitatively. The ‘Long-term Cement Studies’ (LCS) project was formulated with an emphasis on in situ field experiments with more realistic boundary conditions and longer time scales compared with former experiments. As part of the project programme, a modelling inter-comparison has been conducted, involving the modelling of two experiments describing cement hydration on one hand and cement-rock reaction on the other, with teams representing the NDA (UK), Posiva (Finland), and JAEA (Japan).This modelling exercise showed that the dominant reaction pathways in the two experiments are fairly well understood and are consistent between the different modelling teams, although significant differences existed amongst the precise parameterisation (e.g. reactive surface areas, dependences of rate upon pH, types of secondary minerals), and in some instances, processes (e.g. partition of alkali elements between solids and liquid during cement hydration; kinetic models of cement hydration). It was not conclusive if certain processes such as surface complexation (preferred by some modellers, but not by others) played a role in the cement-rock experiment or not. These processes appear to be more relevant at early times in the experiment and the evolution at longer timescales was not affected. The observed permeability profile with time could not be matched. The fact that no secondary minerals could be observed and that the precipitated mass calculated during the simulations is minor might suggest that the permeability reduction does not have a chemical origin, although a small amount of precipitates at pore throats could have a large impact on permeability.The modelling exercises showed that there is an interest in keeping the numerical models as simple as possible and trying to obtain a reasonable fit with a minimum of processes, minerals and parameters. However, up-scaling processes and model parameterisation to the timescales appropriate to repository safety assessment are of considerable concern. Future modelling exercises of this type should focus on a suitable natural or industrial analogue that might aid assessing mineral-fluid reactions at these longer timescales.  相似文献   

Distribution of <Emphasis Type="Italic">Nemopilema nomurai</Emphasis> in the southwestern Sea of Japan related to meandering of the Tsushima Warm Current     

Satoshi?KitajimaEmail author  Naoki?Iguchi  Naoto?Honda  Tatsuro?Watanabe  Osamu?Katoh 《Journal of Oceanography》2015,71(3):287-296

We investigated the horizontal distribution of Nemopilema nomurai medusae using a midwater trawl in the southwestern Sea of Japan from September to October of each year from 2006 to 2012. Numerous medusae of this species found in 2006, 2007, and 2009 were mainly distributed far (>40 km) from the mainland of Japan in the western part of the survey area, but were distributed in the stations closest (<25 km) to the mainland in the eastern part, particularly in 2006 and 2009. These distribution patterns were associated with the path of the second branch of the Tsushima Warm Current (TWC) that flows offshore to the west of Oki Islands and usually approaches the mainland of Japan to the east of Oki Islands. Differences in jellyfish distribution across the survey periods were related to the distribution of the second branch being associated with types, position and intensity of eddies in the eastern part of the survey area. Hence, the formations of eddies and consequent variation in the path of the TWC would be responsible for transporting medusae from offshore to near the mainland to the east of Oki Islands. Individuals with large bells accumulated in the northwestern part of the survey area, where a cyclonic eddy was present downstream of the third branch of the TWC. This variation in bell size distribution may be ascribed to differences in the physical and/or biological factors among the three branches of the TWC.  相似文献   

Bidirectional shaking table tests of a low-cost friction sliding system with flat-inclined surfaces     

Miguel B. Brito  Mitsuyoshi Akiyama  Yoshitaka Ichikawa  Hiroki Yamaguchi  Riki Honda  Naomitsu Ishigaki 《地震工程与结构动力学》2020,49(8):817-837

A novel low-cost friction sliding system for bidirectional excitation is developed to improve the seismic performance of reinforced concrete (RC) bridge piers. The sliding system is a spherical prototype developed by combining a central flat surface with an inclined spherical segment, characterized by stable oscillation and a large reduction in response accelerations on the flat surface. The inclined part provides a restoring force that limits the residual displacements of the system. Conventional steel and concrete are employed to construct a flat-inclined spherical surface atop an RC pier. The seismic forces are dissipated through the frictions generated during the sliding movements; hence, the seismic resilience of bridges can be ensured with a low-cost design solution. The proposed system is fabricated utilizing a mold created by a three-dimensional printer, which facilitates the use of conventional concrete to construct spherical shapes. The concrete surface is lubricated with a resin material to prevent abrasion from multiple input ground motions. To demonstrate the effectiveness of the system, bidirectional shaking table tests are conducted in the longitudinal and transverse directions of a scaled bridge model. The effect of the inclination angle and the flat surface size is investigated. The results demonstrate a large decrease in response acceleration when the system exhibits circular sliding displacement. Furthermore, the inclination angle that generates the smallest residual displacement is identified experimentally.  相似文献   

Nankai Trough: A hot trench?     

M. Yamano  S. Honda  S. Uyeda 《Marine Geophysical Researches》1984,6(2):187-203

Heat flow estimated from the gas hydrate layers on the landward slope of the Nankai Trough reveals that heat flow increases downslope toward the trench floor. This data plus six new heat flow values obtained by a conventional probe and two values available from DSDP drill holes give a fairly detailed heat flow distribution in the Nankai Trough area, when combined with the already existing data set. There appears to be a zonal pattern parallel to the trough axis, with a high heat flow zone on the floor of the trough that is quite anomalous for a subduction zone. It might be explained as a result of subduction of the hot portion of the Philippine Sea plate, i.e. the Shikoku Basin, and/or of more local effects such as heating due to intrusion of hot water from subducted sediments to shallow depth beneath the trough floor. Surface heat flow patterns landward of the trough were calculated for a simple thermal model of subduction. Perfect reproduction of the observed zonal pattern is difficult to achieve by the simple model, suggesting the necessity for further heat flow and other observations.  相似文献   

Excess CO2 and pHexcess in the Intermediate Water Layer of the Northwestern Pacific     

Andrey Andreev  Makio Honda  Yuichiro Kumamoto  Masashi Kusakabe  Akihiko Murata 《Journal of Oceanography》2001,57(2):177-188

Excess CO₂ and pH_excess showing an increase in dissolved inorganic carbon and a decrease in pH from the beginning of the industrial epoch (middle of the 19th century) until the present time have been calculated in the intermediate water layer of the northwestern Pacific and the Okhotsk Sea. It is concluded that: (1) The Kuril Basin (Okhotsk Sea) and the Bussol' Strait areas are characterized by the greatest concentrations of excess CO₂ at isopycnal surfaces due to the processes of formation and transformation of intermediate water mass. (2) The largest difference in excess CO₂ concentration between the Okhotsk Sea and the western subarctic Pacific (about 8 µmol/kg) is found at the = 27.0. (3) The difference in excess CO₂ between the western subarctic Pacific and subtropical regions is significant only in the upper part of the intermediate water layer ( = 26.7–27.0). (4) About 10% of the excess CO₂ accumulation in the subtropical north Pacific is determined by water exchange with the subarctic Pacific and the Okhotsk Sea.  相似文献   

Regional 3-D heterogeneities by waveform inversion – application to the Atlantic area     

Satoru Honda  Toshiro Tanimoto 《Geophysical Journal International》1987,91(3):737-753

The waveform inversion method described in Woodhouse & Dziewonski (1984) was modified to retrieve regional scale 3-D heterogeneities by using the minor arc part of seismograms. The lateral heterogeneities are expanded horizontally into blocks (10°× 10°) and radially into Legendre polynomials up to order 3 (0–670 km), and thus the results show much fine details of lateral variation than previous global scale studies. We assumed that the heterogeneities produce the perturbation of eigenfrequencies which are the minor arc average of local eigenfrequency shift. We applied the method to the upper mantle beneath the Atlantic Ocean and its environments. Care was taken about the weighting of the data set. We found that the fit of each seismogram became better when the weighting of each seismogram is proportional to the inverse of initial data residuals. Resolution is good in the triangular region surrounded by South America, Europe, and North America. Resolution is not good in the South Atlantic because of the poor path coverage. Depth resolution is not clear, because of the use of Legendre polynomials, though the results suggest a broad half-width of the order of 200 km or more. We found some similarities between previous global studies and our results. For example, low velocities beneath the East Pacific Rise, Chile Rise and Azores triple junction and a high velocity Canadian shield are obtained. However, there are also differences; the high-velocity zone beneath the Brazilian shield at shallow depth is not a prominent feature in this study. Instead, we found a somewhat unexpected feature near the Romanche and Vema fracture zones where shallow positive anomalies exist. Smoothed results calculated by the spherical harmonic expansion are also shown for the purpose of comparison with global studies.  相似文献   

Real-time difference imaging analysis of MOA Galactic bulge observations during 2000     

I.A. Bond  F. Abe  R.J. Dodd  J.B. Hearnshaw  M. Honda  J. Jugaku  P.M. Kilmartin  A. Marles  K. Masuda  Y. Matsubara  Y. Muraki  T. Nakamura  G. Nankivell  S. Noda  C. Noguchi  K. Ohnishi  N.J. Rattenbury  M. Reid  To. Saito  H. Sato  M. Sekiguchi  J. Skuljan  D.J. Sullivan  T. Sumi  M. Takeuti  Y. Watase  S. Wilkinson  R. Yamada  T. Yanagisawa  P.C.M. Yock 《Monthly notices of the Royal Astronomical Society》2001,327(3):868-880

We describe observations carried out by the MOA group of the Galactic bulge during 2000 that were designed to detect efficiently gravitational microlensing of faint stars in which the magnification is high and/or of short duration. These events are particularly useful for studies of extrasolar planets and faint stars. Approximately 17 deg² were monitored at a sampling rate of up to six times per night. The images were analysed in real time using a difference imaging technique. 20 microlensing candidates were detected, of which eight were alerted to the microlensing community whilst in progress. Approximately half of the candidates had high magnifications (≳10), at least one had very high magnification (≳50), and one exhibited a clear parallax effect. The details of these events are reported here, together with details of the on-line difference imaging technique. Some nova-like events were also observed and these are described, together with one asteroid.  相似文献   

Coupled 1-D physical–biological model study of phytoplankton production at two contrasting time-series stations in the western North Pacific     

Yoshikazu Sasai  Chisato Yoshikawa  S. Lan Smith  Taketo Hashioka  Kazuhiko Matsumoto  Masahide Wakita  Kosei Sasaoka  Makio C. Honda 《Journal of Oceanography》2016,72(3):509-526

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Seasonal variations in the nitrogen isotopic composition of settling particles at station K2 in the western subarctic North Pacific     

Yoshihisa?MinoEmail author  Chiho?Sukigara  Makio?C.?Honda  Hajime?Kawakami  Kazuhiko?Matsumoto  Masahide?Wakita  Minoru?Kitamura  Tetsuichi?Fujiki  Kosei?Sasaoka  Osamu?Abe  Jan?Kaiser  Toshiro?Saino 《Journal of Oceanography》2016,72(6):819-836

Intensive observations using hydrographical cruises and moored sediment trap deployments during 2010 and 2012 at station K2 in the North Pacific Western Subarctic Gyre (WSG) revealed seasonal changes in δ ¹⁵N of both suspended and settling particles. Suspended particles (SUS) were collected from depths between the surface and 200 m; settling particles by drifting sediment traps (DST; 100–200 m) and moored sediment traps (MST; 200 and 500 m). All particles showed higher δ ¹⁵N values in winter and lower in summer, contrary to the expected by isotopic fractionation during phytoplankton nitrate consumption. We suggest that these observed isotopic patterns are due to ammonium consumption via light-controlled nitrification, which could induce variations in δ ¹⁵N(SUS) of 0.4–3.1 ‰ in the euphotic zone (EZ). The δ ¹⁵N(SUS) signature was reflected by δ ¹⁵N(DST) despite modifications during biogenic transformation from suspended particles in the EZ. δ ¹⁵N enrichment (average: 3.6 ‰) and the increase in C:N ratio (by 1.6) in settling particles suggests year-round contributions of metabolites from herbivorous zooplankton as well as TEPs produced by diatoms. Accordingly, seasonal δ ¹⁵N(DST) variations of 2.4–7.0 ‰ showed a significant correlation with primary productivity (PP) at K2. By applying the observed δ ¹⁵N(DST) vs. PP regression to δ ¹⁵N(MST) of 1.9–8.0 ‰, we constructed the first annual time-series of PP changes in the WSG. This new approach to estimate productivity can be a powerful tool for further understanding of the biological pump in the WSG, even though its validity needs to be examined carefully.  相似文献   

Isotope fractionation of neon during stepheating extraction?: a comment on ‘Re‐interpretation of the existence of a primitive plume under Australia based on neon isotope fractionation during step heating’ by Gautheron and Moreira (2003)     

Takuya Matsumoto  Masahiko Honda  Ian McDougall  Igor Yatsevich  Suzanne Y. O'Reilly 《地学学报》2004,16(1):23-26

Using a Rayleigh distillation fractionation model, we calculate that the maximum isotope fractionation potentially achievable is less than 5% during the early stages of gas release from a sample. Our calculation corrects the erroneous conclusions of Gautheron and Moreira (2003), who re‐interpreted the plume‐like neon isotopic compositions found in metasomatic apatite from a south‐eastern Australian xenolith (Matsumoto et al., 1997) to be the result of Rayleigh‐type isotope fractionation of originally MORB‐type neon during stepheating gas extraction. We stress that the modelling of neon isotopic fractionation by Gautheron and Moreira (2003) is incorrect, and that the finding of a plume‐like neon isotopic composition in the apatite by Matsumoto et al. (1997) remains a quite valid and robust conclusion.  相似文献