Surficial and Deep Earth Material Prediction from Geochemical Compositions     

Talebi  Hassan  Mueller  Ute  Tolosana-Delgado  Raimon  Grunsky  Eric C.  McKinley  Jennifer M.  Caritat  Patrice de 《Natural Resources Research》2019,28(3):869-891

Prediction of true classes of surficial and deep earth materials using multivariate spatial data is a common challenge for geoscience modelers. Most geological processes leave a footprint that can be explored by geochemical data analysis. These footprints are normally complex statistical and spatial patterns buried deep in the high-dimensional compositional space. This paper proposes a spatial predictive model for classification of surficial and deep earth materials derived from the geochemical composition of surface regolith. The model is based on a combination of geostatistical simulation and machine learning approaches. A random forest predictive model is trained, and features are ranked based on their contribution to the predictive model. To generate potential and uncertainty maps, compositional data are simulated at unsampled locations via a chain of transformations (isometric log-ratio transformation followed by the flow anamorphosis) and geostatistical simulation. The simulated results are subsequently back-transformed to the original compositional space. The trained predictive model is used to estimate the probability of classes for simulated compositions. The proposed approach is illustrated through two case studies. In the first case study, the major crustal blocks of the Australian continent are predicted from the surface regolith geochemistry of the National Geochemical Survey of Australia project. The aim of the second case study is to discover the superficial deposits (peat) from the regional-scale soil geochemical data of the Tellus Project. The accuracy of the results in these two case studies confirms the usefulness of the proposed method for geological class prediction and geological process discovery.

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Development of an In Situ Ion-Exchange Technique for the Determination of Free Cd,Co, Ni,and Zn Concentrations in Freshwaters     

A. Crémazy  S. Leclair  K. K. Mueller  B. Vigneault  P. G. C. Campbell  C. Fortin 《Aquatic Geochemistry》2015,21(2-4):259-279

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In-flight calibration of the HIFI diplexers     

Michael Mueller  Willem Jellema  Bertrand Delforge  David Teyssier  Martin Eggens  Robert Huisman  Geert Keizer 《Experimental Astronomy》2014,37(2):369-379

HIFI is a heterodyne spectrometer aboard the Herschel Space Observatory, providing high-spectral-resolution capabilities. Of its seven frequency bands, four (bands 3, 4, 6, and 7) employ Martin-Puplett diplexers to combine sky signal and local oscillator at the two linear polarizations H and V, prior to feeding them into the mixers (receivers). The optical path difference in each of these 8 diplexers must be tuned to the observed frequency. The required actuator currents were determined in flight before the start of routine science observations. We here report on regular (roughly quarterly) engineering test observations to validate the repeatability of the HIFI diplexers during the routine phase of Herschel operations. We find the optical path difference to be stable to within 0.4 % of the relevant wavelength, typically at the sub-micron level. We conclude that the repeatability and precision of the diplexer tuning mechanism are so high that science data are in no way negatively affected. With the diplexer calibration established and validated, this line of reasoning can be reversed, and the diplexers can be used as relative spectrometers to measure the local-oscillator frequency, i.e., to check the spectral purity of the local oscillator across the diplexer bands. This was done from before launch out to the last months of cryogenic operations in space.  相似文献   

Stream nitrate uptake and transient storage over a gradient of geomorphic complexity,north‐central Colorado,USA     

Daniel W. Baker  Brian P. Bledsoe  Jennifer Mueller Price 《水文研究》2012,26(21):3241-3252

The understanding of nutrient uptake in streams is impeded by a limited understanding of how geomorphic setting and flow regime interact with biogeochemical processing. This study investigated these interactions as they relate to transient storage and nitrate uptake in small agricultural and urban streams. Sites were selected across a gradient of channel conditions and management modifications and included three 180‐m long geomorphically distinct reaches on each of two streams in north‐central Colorado. The agricultural stream has been subject to historically variable cattle‐grazing practices, and the urban stream exhibits various levels of stabilisation and planform alteration. Reach‐scale geomorphic complexity was characterised using highly detailed surveys of channel morphology, substrate, hydraulics and habitat units. Breakthrough‐curve modelling of conservative bromide (Br^?) and nonconservative nitrate (NO₃^?) tracer injections characterised transient storage and nitrate uptake along each reach. Longitudinal roughness and flow depth were positively associated with transient storage, which was related to nitrate uptake, thus underscoring the importance of geomorphic influences on stream biogeochemical processes. In addition, changes in geomorphic characteristics due to temporal discharge variation led to complex responses in nitrate uptake. Copyright © 2011 John Wiley & Sons, Ltd.  相似文献   

Environmental Monitoring and Peat Assessment Using Multivariate Analysis of Regional-Scale Geochemical Data     

Jennifer M. McKinley  Eric Grunsky  Ute Mueller 《Mathematical Geosciences》2018,50(2):235-246

A compositional multivariate approach was used to analyse regional-scale soil geochemical data obtained as part of the Tellus Project generated by the Geological Survey of Northern Ireland. The multi-element total concentration data presented comprise X-ray fluorescence (XRF) analyses of 6862 rural soil samples collected at 20-cm depth on a non-aligned grid at one site per \(2\,\hbox {km}^{2}\). Censored data were imputed using published detection limits. Each soil sample site was assigned to the regional geology map, resulting in spatial data for one categorical variable and 35 continuous variables comprised of individual and amalgamated elements. This paper examines the extent to which soil geochemistry reflects the underlying geology or superficial deposits. Since the soil geochemistry is compositional, log-ratios were computed to adequately evaluate the data using multivariate statistical methods. Principal component analysis (PCA) and minimum/maximum autocorrelation factors (MAF) were used to carry out linear discriminant analysis (LDA) as a means to discover and validate processes related to the geologic assemblages coded as age bracket. Peat cover was introduced as an additional category to measure the ability to predict and monitor fragile ecosystems. Overall prediction accuracies for the age bracket categories were 68.4 % using PCA and 74.7 % using MAF. With inclusion of peat, the accuracy for LDA classification decreased to 65.0 and 69.9 %, respectively. The increase in misclassification due to the presence of peat may reflect degradation of peat-covered areas since the creation of superficial deposit classification.  相似文献   

Spatial Variation in the Optical Properties of Dissolved Organic Matter (DOM) in Lakes on the Canadian Precambrian Shield and Links to Watershed Characteristics   总被引：1，自引：0，他引：1  

Kristin K. Mueller  Claude Fortin  Peter G. C. Campbell 《Aquatic Geochemistry》2012,18(1):21-44

In the present study, we explored the use of various optical parameters to detect differences in the composition of the dissolved organic matter (DOM) in a set of lakes that are all located on the Canadian Precambrian Shield, but within which Cu and Ni speciation predictions were previously shown to diverge from measured values in some lakes but not in others. Water samples were collected with in situ diffusion samplers in 2007 (N = 18 lakes) and 2008 (N = 8 lakes). Significant differences in DOM quality were identified between the sampling regions (Rouyn-Noranda, Québec and Sudbury, Ontario) and among lakes, based on dissolved organic carbon concentrations ([DOC]), specific UV absorbance (SUVA₂₅₄), fluorescence indices (FI), and excitation–emission matrix (EEM) fluorescence measurements. Parallel factor analysis (PARAFAC) of the EEM spectra revealed four components, two of which (C3, oxidized quinone fluorophore of allochthonous origin, and C4, tryptophan-like protein fluorescence of autochthonous origin) showed the greatest inter-regional variation. The inter-lake differences in DOM quality were consistent with the regional watershed characteristics as determined from satellite imagery (e.g., watershed-to-lake surface area ratios and relative percentages of surface water, rock outcrops vegetative cover and urban development). Source apportionment plots, built upon PARAFAC components ratios calculated for our lakes, were used to discriminate among DOM sources and to compare them to sources identified in the literature. These results have implications for other areas of research, such as quantifying lake-to-lake variations in the influence of organic matter on the speciation of trace elements in natural aquatic environments.  相似文献   

R- and J-band photometry of Comets 2P/Encke and 9P/Tempel 1     

Carl W. Hergenrother  Beatrice E.A. Mueller  N.H. Samarasinha 《Icarus》2006,181(1):156-161

Near-simultaneous R- and J-band photometric measurements of the short-period Comets 2P/Encke and the Deep Impact mission target 9P/Tempel 1 were obtained. The resulting R-J colors are +0.82±0.08 mag and +1.46±0.13 mag for Encke and Tempel 1, respectively. Tempel 1's color is redder than the solar R-J color index of +0.76. The Tempel 1 observations directly detected the nucleus while the Encke observations likely suffered from coma contamination.  相似文献   

Discovery of the 'missing' mode in HR 1217 by the Whole Earth Telescope     

D. W.Kurtz  S. D.Kawaler  R. L.Riddle  M. D.Reed †  M. S.Cunha  M.Wood  N.Silvestri  T. K.Watson  N.Dolez  P.Moskalik  S.Zola  E.Pallier  J. A.Guzik  T. S.Metcalfe  A. S.Mukadam  R. E.Nather  D. E.Winget  D. J.Sullivan  T.Sullivan  K.Sekiguchi  X.Jiang  R.Shobbrook  B. N.Ashoka  S.Seetha  S.Joshi  D.O'Donoghue  G.Handler  M.Mueller  J. M.Gonzalez Perez  J.-E.Solheim  F.Johannessen  A.Ulla  S. O.Kepler  A.Kanaan  A.da Costa  L.Fraga  O.Giovannini  J. M.Matthews 《Monthly notices of the Royal Astronomical Society》2002,330(3):57-61

HR 1217 is a prototypical rapidly oscillating Ap star that has presented a test to the theory of non-radial stellar pulsation. Prior observations showed a clear pattern of five modes with alternating frequency spacings of 33.3 and 34.6 μHz, with a sixth mode at a problematic spacing of 50.0 μHz (which equals  1.5×33.3 μHz)  to the high-frequency side. Asymptotic pulsation theory allowed for a frequency spacing of 34 μHz, but Hipparcos observations rule out such a spacing. Theoretical calculations of magnetoacoustic modes in Ap stars by Cunha predicted that there should be a previously undetected mode 34 μHz higher than the main group, with a smaller spacing between it and the highest one. In this Letter, we present preliminary results from a multisite photometric campaign on the rapidly oscillating Ap star HR 1217 using the 'Whole Earth Telescope'. While a complete analysis of the data will appear in a later paper, one outstanding result from this run is the discovery of a newly detected frequency in the pulsation spectrum of this star, at the frequency predicted by Cunha.  相似文献   

Spin Axis Direction of Comet 19p/Borrelly Based on Observations from 2000 and 2001     

Samarasinha  Nalin H.  Mueller  Béatrice E. A. 《Earth, Moon, and Planets》2002,90(1-4):473-482

We calculate the direction of the rotational angular momentum vector,M, of comet 19P/Borrelly based on rotational lightcurve data from 2000, groundbased imaging of the coma during the Deep Space 1encounter, and the basic near-nucleus coma morphology as revealed by the Deep Space 1 spacecraft. For the most likely direction, we derivea family of solutions (with center at RA = 221°, Dec = -7°) if the direction of M is towards the sunward hemisphere during the Deep Space 1 encounter, whereas if the rotation is of opposite sense, the diametrically opposite family of solutions (with center at RA = 41°, Dec = 7°) would result. We argue that the coma morphology in September 2001 is consistent with the nucleus being a principal axis rotator or one observationally indistinguishable from it. Therefore, for all practical purposes, the direction of the rotational angular momentum vector coincides with the spin axis. We also discuss why the determination of the spin axis direction based on observations from the last apparition is in disagreement with the current result.  相似文献   

Archean high-Mg monzodiorite–syenite,epidote skarn,and biotite–sericite gold lodes in the Granny Smith–Wallaby district,Australia: U–Pb and Re–Os chronometry of two intrusion-related hydrothermal systems     

Andreas G. Mueller  Gregory C. Hall  Alexander A. Nemchin  Holly J. Stein  Robert A. Creaser  Douglas R. Mason 《Mineralium Deposita》2008,43(3):337-362

The Granny Smith (37 t Au production) and Wallaby deposits (38 t out of a 180 t Au resource) are located northeast of Kalgoorlie, in 2.7 Ga greenstones of the Eastern Goldfields Province, the youngest orogenic belt of the Yilgarn craton, Western Australia. At Granny Smith, a zoned monzodiorite–granodiorite stock, dated by a concordant titanite–zircon U–Pb age of 2,665 ± 3 Ma, cuts across east-dipping thrust faults. The stock is fractured but not displaced and sets a minimum age for large-scale (1 km) thrust faulting (D2), regional folding (D1), and dynamothermal metamorphism in the mining district. The local gold–pyrite mineralization, controlled by fractured fault zones, is younger than 2,665 ± 3 Ma. In augite–hornblende monzodiorite, alteration progressed from a hematite-stained alkali feldspar–quartz–calcite assemblage and quartz–molybdenite–pyrite veins to a late reduced sericite–dolomite–albite assemblage. Gold-related monazite and xenotime define a U–Pb age of 2,660 ± 5 Ma, and molybdenite from veins a Re–Os isochron age of 2,661 ± 6 Ma, indicating that mineralization took place shortly after the emplacement of the main stock, perhaps coincident with the intrusion of late alkali granite dikes. At Wallaby, a NE-trending swarm of porphyry dikes comprising augite monzonite, monzodiorite, and minor kersantite intrudes folded and thrust-faulted molasse. The conglomerate and the dikes are overprinted by barren (<0.01 g/t Au) anhydrite-bearing epidote–actinolite–calcite skarn, forming a 600-m-wide and >1,600-m-long replacement pipe, which is intruded by a younger ring dike of syenite porphyry pervasively altered to muscovite + calcite + pyrite. Skarn and syenite are cut by pink biotite–calcite veins, containing magnetite + pyrite and subeconomic gold–silver mineralization (Au/Ag = 0.2). The veins are associated with red biotite–sericite–calcite–albite alteration in adjacent monzonite dikes. Structural relations and the concordant titanite U–Pb age of the skarn constrain intrusion-related mineralization to 2,662 ± 3 Ma. The main-stage gold–pyrite ore (Au/Ag >10) forms hematite-stained sericite–dolomite–albite lodes in stacked D2 reverse faults, which offset skarn, syenite, and the biotite–calcite veins by up to 25 m. The molybdenite Re–Os age (2,661 ± 10 Ma) of the ore suggests a genetic link to intrusive activity but is in apparent conflict with a monazite–xenotime U–Pb age (2,651 ± 6 Ma), which differs from that of the skarn at the 95% confidence level. The time relationships at both gold deposits are inconsistent with orogenic models invoking a principal role for metamorphic fluids released during the main phase of compression in the fold belt. Instead, mineralization is related in space and time to late-orogenic, magnetite-series, high-Mg monzodiorite–syenite intrusions of mantle origin, characterized by Mg/(Mg + Fe_TOTAL) = 0.31–0.57, high Cr (34–96 ppm), Ni (22–63 ppm), Ba (1,056–2,321 ppm), Sr (1,268–2,457 ppm), Th (15–36 ppm), and rare earth elements (total REE: 343–523 ppm). At Wallaby, shared Ca–K–CO₂ metasomatism and Th-REE enrichment (in allanite) link Au–Ag mineralization in biotite–calcite veins to the formation of the giant epidote skarn, implicating a Th + REE-rich syenite pluton at depth as the source of the oxidized hydrothermal fluid. At Granny Smith, lead isotope data and the Rb–Th–U signature of early hematite-bearing wall-rock alteration point to fluid released by the source pluton of the differentiated alkali granite dikes.  相似文献