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1.
Studies on the Arabian Sea coastal anoxia have been of immense interest, but despite its ecological significance there is sparse understanding of the microbes involved. Hence, observations were carried out off Goa (15 degrees 30'N, 72 degrees 40'E to 15 degrees 30'N, 72 degrees 59'E) to understand the processes that mediate the changes in various inorganic nitrogen species in the water column during anoxia. Water column chemistry showed a clear distinct oxic environment in the month of April and anoxic condition in October. Our study based on microbial signatures indicated that oxygen deficit appeared as a well-defined nucleus almost 40 km away from the coast during the oxic period (April) and spreads there after to the entire water column synchronizing with the water chemistry. Striking results of net changes in inorganic nitrogen species in nitrification blocked and unblocked experimental systems show that denitrification is the predominant process in the water column consuming available nitrate ( approximately 0.5 microM) to near zero levels within approximately 72 h of incubation. These observations have been supported by concomitant increase in nitrite concentration ( approximately 4 microM). Similar studies on denitrification-blocked incubations, demonstrate the potential of nitrification to feed denitrification. Nitrification could contribute almost 4.5 microM to the total nitrate pool. It was found that the relation between ammonium and total dissolved inorganic nitrogen (DIN) pool (r=0.98, p<0.001, n=122) was significant compared to the latter with nitrite and nitrate. The occurrence of high ammonium under low phosphate conditions corroborates our observations that ammonium does not appear to be locked under low oxygen regimes. It is suggested that ammonium actively produced by detrital breakdown (ammonification) is efficiently consumed through nitrification process. The three processes in concert viz. ammonification, nitrification and denitrification appear to operate in more temporal and spatial proximity than hitherto appreciated in these systems and this gives additional cues on the absence of measurable nitrate at surface waters, which was earlier attributed only to efficient algal uptake. Hence we hypothesize that the alarming nitrous oxide input into the atmosphere could be due to high productivity driven tighter nitrification-denitrification coupling, rather than denitrification driven by extraneous nitrate.  相似文献   
2.
Accurately mapping a region’s ground water quality depends upon the spatial sampling strategies employed, including where and how often field data are collected. This study compares the relative values of three field sampling strategies for mapping a known migrating plume of volcanic ground water in Sierra Valley, California. The first strategy sampled wells once each year during 1957, 1972, and 1980 (n=63, 45, and 57, respectively) and portrayed spatial–temporal changes in ground water quality more clearly on maps than did two alternative sampling strategies. One of these alternatives, Strategy 2, sampled one well per township per year during 1957, 1972, and 1980 (n=11) and did not detect the migrating plume, despite being a recommended strategy. The other alternative, Strategy 3, frequently sampled in time a small, fixed group of indicator wells (n=13) every four years for the same period, again producing maps with little correlation to the original pattern detected by Strategy 1.  相似文献   
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In the Maya Lowlands of Mexico, Belize, and Guatemala two main types of wetlands have played important roles in human history: bajos or intermittently wet environments of the upland, interior Yucatán and perennial wetlands of the coastal plains. Many of the most important Maya sites encircle the bajos, though our growing evidence for human–wetland interactions is still sparse. The deposits of these wetlands record two main eras of slope instability and wetland aggradation: the Pleistocene–Holocene transition as rainfall increased and forests eclipsed savannas and the Maya Preclassic to Classic as deforestation, land-use intensity, and drying increased. The ancient Maya adapted with terraces around these bajo margins but retracted in the Late Preclassic in some areas. The perennial wetlands of the coastal plains have different histories, and the first conceptual model of human–wetland interaction described intensive wetland agriculture in the Preclassic through Classic based on raised fields and canals. But a second model arose that interpreted the wetland stratigraphy and canals as more indicative of natural aggradation by accelerated erosion and gypsum precipitation that buried Archaic and Preclassic fields and there was little Classic era use. We present new data on a third and fourth model in this study. The third is a hybrid of the models one and two, including the Archaic to Preclassic aggradation of the second model, and the first model's Classic period fields and canals as piecemeal attempts by the Maya to adapt to these and other environmental changes. The fourth conceptual model describes a very Late/Terminal Classic, preplanned project on a floodplain. These wetland fields were short-lived, aggraded rapidly but with some reoccupation in the Postclassic. All of these new models display the burgeoning evidence for intricate Maya interactions with wetlands, and the diversity of evidence from the relatively few studies underscores the infancy of our understanding of Maya interaction with tropical wetlands.  相似文献   
5.
In 1995 and 1996 we undertook surveys to identify the status, perspectives, and contributions of women and men in physical geography and geosciences/geology, and to study the evolution of our fields. This paper presents the results of the physical geography survey, and considers the following questions: How have academic men and women physical geographers' professional development experiences differed? Do men and women in physical geography emphasize different research areas? Do their research methods differ from one another? Gender differences were identified most strikingly in rank and tenure status, research topics and methodologies, and professional satisfaction. Generational differences by academic rank were identified in professional satisfaction and in pull factors. Minor gender differences were found in dual career couple status, but this status had major effects on career choices and opportunities for both men and women. This paper is part of our larger project aimed at comparing and contrasting geoscience/geology and physical geography, and at including the earth sciences in gender and science studies that have long focused on mathematics, chemistry, biology, and physics.  相似文献   
6.
ABSTRACT. Chunchucmil, on the Yucatán Peninsula, was densely populated in the Maya Late Classic period (ca. a.d. 550–830), even though it depends principally on groundwater. In the 1990s, hydrologic investigations were conducted to determine whether groundwater could have met domestic and agricultural needs. The region's groundwater is near the surface and is influenced by sea‐level fluctuations; however, geochemical analysis revealed that groundwater quality is not affected by mixing with seawater. The potential exists for high and spatially extensive nitrate contamination in this karstic area, yet water‐quality analyses revealed only moderate levels of nitrate in the groundwater. Agricultural limitations are imposed by chloride, total dissolved solids, and salinity, as indicated by electrical conductivity; domestic water use is limited by the presence of nitrate, sulfate, and chloride. Throughflow in the ring of cenotes (sinkholes) around the Chicxulub impact crater may explain the movement and spatial distribution of water‐quality constituents in Chunchucmil's groundwater.  相似文献   
7.
The Mandovi and Chapora are two tropical estuaries lying in close geographic proximity on the west coast of India. Seasonal changes in down core variation of Fe, Mn and Total Organic Carbon (TOC) in the mangrove sediments adjoining these estuaries were studied to assess their influence on some of the representative benthic bacteria belonging to heterotrophic and autotrophic groups. Heterotrophic bacteria (HB) cultured on different nutrient concentrations (0.01%, 0.1% and 25%) together with nitrifiers (NtB; representating autotroph) were chosen to assess the influence of the above-mentioned abiotic parameters on the former. The experimental site located along the Mandovi is under the influence of extensive ferromanganese ore mining, while the control site at Chapora is relatively free from such influences. Geoaccumulation index computed for Mandovi showed that sediments (0-10cm) were 'uncontaminated to moderately contaminated' by Fe during the pre monsoon and monsoon seasons, while in the post monsoon season the 4-10cm fraction was almost completely restored from contamination. Similar computations for Mn showed that in pre monsoon, sediments fell in the 'moderately contaminated' and 'moderately to strongly contaminated' categories, while in the monsoon and post monsoon seasons all the sections were 'Uncontaminated'. The difference observed in correlation between Fe and Mn with the various fractions of heterotrophs and nitrifiers indicated that though these two elements shared a similar chemistry in the environment, microbes involved in biogeochemical processes might prefer them differentially. The relationship between TOC and HB enumerated on 0.01% dilute nutrient agar remained at r=0.50, p<0.05 throughout the year. Hence, it could be apparently linked to their preferred concentration of organic carbon requirement. A relationship of r=0.61, p<0.01 between manganese concentration and heterotrophs recovered on different strengths of nutrient agar is suggestive of their response to the metal enrichment. They could thus contribute towards maintaining the level of Mn at par with reference levels at Chapora. A positive correlation between Mn with NtB (n=10, p<0.05, r=0.58) at the experimental site during the non-monsoon months is suggestive of the latter's contribution to regulation of the metal concentration in the sediment probably through anaerobic nitrification at the expense of manganese. The study therefore supports our hypothesis that both autochthonous autotrophs and heterotrophs work in tandem to mitigate concentration of Mn and related metals in mangrove sediments.  相似文献   
8.
Propane biosparging and bioaugmentation were applied to promote in situ biodegradation of 1,4‐dioxane at Site 24, Vandenberg Air Force Base (VAFB), CA. Laboratory microcosm and enrichment culture testing demonstrated that although native propanotrophs appeared abundant in the shallow water‐bearing unit of the aquifer (8 to 23 ft below ground surface [bgs]), they were difficult to be enriched from a deeper water‐bearing unit (82 to 90 feet bgs). Bioaugmentation with the propanotroph Rhodococcus ruber ENV425, however, supported 1,4‐dioxane biodegradation in microcosms constructed with samples from the deep aquifer. For field testing, a propane‐biosparging system consisting of a single sparging well and four performance monitoring wells was constructed in the deep aquifer. 1,4‐dioxane biodegradation began immediately after bioaugmentation with R. ruber ENV425 (36 L; 4 × 109 cells/mL), and apparent first‐order decay rates for 1,4‐dioxane ranged from 0.021 day?1 to 0.036 day?1. First‐order propane consumption rates increased from 0.01 to 0.05 min?1 during treatment. 1,4‐dioxane concentrations in the sparging well and two of the performance monitoring wells were reduced from as high as 1090 µg/L to <2 µg/L, while 1,4‐dioxane concentration was reduced from 135 µg/L to 7.3 µg/L in a more distal third monitoring well. No 1,4‐dioxane degradation was observed in the intermediate aquifer control well even though propane and oxygen were present. The demonstration showed that propane biosparging and bioaugmentation can be used for in situ treatment of 1,4‐dioxane to regulatory levels.  相似文献   
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10.
The spatial and temporal abundances of limno-tolerant and halo-tolerant bacteria were investigated in the tide-dominated Mandovi estuary along the west coast of India. These investigations were carried out in relation to various environmental parameters on a monthly basis at three fixed stations for a year. On an annual basis, the estuary showed an average salinity of 28.2, 17.4, and 12.6 at the mouth, midstream and upstream region. Halo-tolerant retrievable count (HTRC) and limno-tolerant retrievable count (LTRC) of bacteria were in the order of 106 L−1. Among the environmental parameters, a strong negative relationship between salinity and nitrate (r = −0.806; p < 0.001) suggested that 64% of the variation could be due to fresh water influence in the estuary. The limno-tolerant retrievable count (LTRC) brought about 23% variations in nitrate concentration. This influence was maximum during the monsoon (r = 0.522; p < 0.05) especially in the surface waters (r = 0.624; p < 0.001) suggesting nitrate reduction by LTRC. Measurements of nitrate reducing activity (NRA) in whole-water samples along the salinity gradient in the estuary also revealed higher reduction rates at lower salinity upstream. This was further confirmed by culture experiments where the limno-tolerant bacteria showed higher NRA than halo-tolerant forms. It is therefore suggested that LTRC is more actively involved in the variation of nitrate that enters the Mandovi estuary particularly during the monsoon.  相似文献   
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