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1.
Abstract— Calculations of the formation of seven types of chondrules in Semarkona from a gas of solar composition were performed with the FACT computer program to predict the chemistries of oxides (including silicates), developed by the authors and their colleagues. The constrained equilibrium theory was used in the calculations with two nucleation constraints suggested by nucleation theory. The first constraint was the blocking of Fe and other metal gaseous atoms from condensing to form solids or liquids because of very high surface free energies and high surface tensions of the solid and liquid metals, respectively. The second constraint was the blocking of the condensation of solids and the formation of metastable liquid oxides (including silicates) well below their liquidus temperatures. Our laboratory experiments suggested subcooling of type IIA chondrule compositions of 400 degrees or more below the liquidus temperature. The blocking of iron leads to a supersaturation of Fe atoms, so that the partial pressure of Fe (pFe) is larger than the partial pressure at equilibrium (pFe(eq)). The supersaturation ratio S = pFe/pFe(eq) becomes larger than 1 and increases rapidly with a decrease in temperature. This drives the reaction Fe + H2O ? H2 + FeO to the right. With S = 100, the activity of FeO in the liquid droplet is 100 times as large as the value at equilibrium. The FeO activities are a function of temperature and provide relative average temperatures of the crystallization of chondrules. Our calculations for the LL3.0 chondrite Semarkona and our study of some non‐equilibrium effects lead to accurate representations of the compositions of chondrules of types IA, IAB, IB, IIA, IIAB, IIB, and CC. Our concepts readily explain both the variety of FeO concentrations in the different chondrule types and the entire process of chondrule formation. Our theory is unified and could possibly explain the formation of chondrules in all chondritic meteorites as well as provide a simple explanation for the complex chemistries of chondrites, and especially for type 3 chondrites.  相似文献   
2.
Spencer  John  Buie  Marc  Young  Leslie  Guo  Yanping  Stern  Alan 《Earth, Moon, and Planets》2003,92(1-4):483-491
Development of the New Horizons mission to Pluto and the Kuiper Belt is now fully funded by NASA (Stern and Spencer, this volume). If all goes well, New Horizons will be launched in January 2006, followed by a Jupiter gravity assist in 2007, with Pluto arrival expected in either 2015 or 2016, depending on the launch vehicle chosen. A backup launch date of early 2007, without a Jupiter flyby, would give a Pluto arrival in 2019 or 2020. In either case, a flyby of at least one Kuiper Belt object (KBO) is planned following the Pluto encounter, sometime before the spacecraft reaches a heliocentric distance of 50 AU, in 2021 or 2023 for the 2006 launch, and 2027 or 2029 for the 2007 launch. However, none of the almost 1000 currently-known KBOs will pass close enough to the spacecraft trajectory to be targeted by New Horizons, so the KBO flyby depends on finding a suitable target among the estimated 500,000 KBOs larger than 40 km in diameter. This paper discusses the issues involved in finding one or more KBO targets for New Horizons. The New Horizons team plans its own searches for mission KBOs but will welcome other U.S, or international team who wish to become involved in exchange for mission participation at the KBO.  相似文献   
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Photometric observations of Pluto in the BVR filter system were obtained in 1999 and in 1990-1993, and observations in the 0.89-μm methane absorption band were obtained in 2000. Our 1999 observations yield lightcurve amplitudes of 0.30 ± 0.01, 0.26 ± 0.01, and 0.21 ± 0.02 and geometric albedos of 0.44 ± 0.04, 0.52 ± 0.03, and 0.58 ± 0.02 in the B, V, and R filters, respectively. The low-albedo hemisphere of Pluto is slightly redder than the higher albedo hemisphere. A comparison of our results and those from previous epochs shows that the lightcurve of Pluto changes substantially through time. We developed a model that fully accounts for changes in the lightcurve caused by changes in the viewing geometry between the Earth, Pluto, and the Sun. We find that the observed changes in the amplitude of Pluto’s lightcurve can be explained by viewing geometry rather than by volatile transport. We also discovered a measurable decrease since 1992 of ∼0.03 magnitudes in the amplitude of Pluto’s lightcurve, as the model predicts. Pluto’s geometric albedo does not appear to be currently increasing, as our model predicts, although given the uncertainties in both the model and the measurements of geometric albedo, this result is not firm evidence for volatile transport. The maximum of methane-absorption lightcurve occurs near the minimum of the BVR lightcurves. This result suggests that methane is more abundant in the brightest regions of Pluto. Pluto’s phase coefficient exhibits a color dependence, ranging from 0.037 ± 0.01 in the B filter to 0.032 ± 0.01 in the R filter. Pluto’s phase curve is most like those of the bright, recently resurfaced satellites Triton and Europa. Although Pluto shows no strong evidence for volatile transport now (unlike Triton), it is important to continue to observe Pluto as it moves away from perihelion.  相似文献   
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6.
The Cassini plasma spectrometer (CAPS) instrument made measurements of Titan's plasma environment when the Cassini Orbiter flew through the moon's plasma wake October 26, 2004 (flyby TA). Initial CAPS ion and electron measurements from this encounter will be compared with measurements made by the Voyager 1 plasma science instrument (PLS). The comparisons will be used to evaluate previous interpretations and predictions of the Titan plasma environment that have been made using PLS measurements. The plasma wake trajectories of flyby TA and Voyager 1 are similar because they occurred when Titan was near Saturn's local noon. These similarities make possible direct, meaningful comparisons between the various plasma wake measurements. They lead to the following: (A) The light and heavy ions, H+and N+/O+, were observed by PLS in Saturn's magnetosphere in the vicinity of Titan while the higher mass resolution of CAPS yielded H+ and H2+as the light constituents and O+/CH4+ as the heavy ions. (B) Finite gyroradius effects were apparent in PLS and CAPS measurements of ambient O+ ions as a result of their absorption by Titan's extended atmosphere. (C) The principal pickup ions inferred from both PLS and CAPS measurements are H+, H2+, N+, CH4+ and N2+. (D) The inference that heavy pickup ions, observed by PLS, were in narrow beam distributions was empirically established by the CAPS measurements. (E) Slowing down of the ambient plasma due to pickup ion mass loading was observed by both instruments on the anti-Saturn side of Titan. (F) Strong mass loading just outside the ionotail by a heavy ion such as N2+ is apparent in PLS and CAPS measurements. (G) Except for the expected differences due to the differing trajectories, the magnitudes and structures of the electron densities and temperatures observed by both instruments are similar. The high-energy electron bite-out observed by PLS in the magnetotail is consistent with that observed by CAPS.  相似文献   
7.
In this paper the second order characteristic (discontinuous bifurcation) condition is derived for the granular flow (fully plastic) equations. This second order bifurcation equation is shown to be formally identical to the first order localization requirement during steady elastoplastic deformation provided the elastic compliance tensor is substituted for the product of the plastic multiplier with the flow Hessian. For isotropic yield and flow functions the invariant form of the characteristic condition is given in detail, as well as an alternative expression in adapted co‐ordinates. The characteristic condition can be regarded as defining a hardening function which is maximized to identify the critical angles. When the method is applied to 3D Coulomb flow, Mohr's 3D fracture plane conditions are obtained uniquely. Copyright © 2003 John Wiley & Sons, Ltd.  相似文献   
8.
The microorganism model of interstellar grains is investigated by spectroscopy from the infrared (IR), visible to the ultraviolet (UV) wave regions.E. coli, yeast and spores ofBacillus subtilis exhibit absorption bands at =3.1 and 9.7 m; they also exhibit several absorptions at 68 m which are in agreement with the observed IS extinction curves.To obtain the extinction curves in the visible and UV regions, dry films of microorganism are prepared on a MgF2 plate or synthesized quartz plate and their spectra measured. In the wavelength region 190400 nm, conventional spectrophotometers are adopted for the measurement. The extinction curve of the film ofE. coli is similar to the observed IS curve.For the wave-range 100<<400 nm, a vacuum UV spectrometer is adopted to avoid absorptions due to O2 in the atmosphere. The extinction spectra by this method are in agreement with the result obtained by the conventional method where comparison is possible. The extinction curves ofE. coli and yeast are such that they incrase towards the short wavelength and exhibit a peak at -190 nm, which is different from the well-known IS peak at =220 nm. It remains to be seen whether interstellar low temperatures (1040 K) can shift the peak position in the extinction curve of biochemical materials.  相似文献   
9.
A 4.96-m-long sediment core from the Hanon paleo-maar in Jeju Island, Korea was studied to investigate the paleoclimatic change and East Asian monsoon variations during the latest Pleistocene to early Holocene (23,000-9000 cal yr BP). High-resolution TOC content, magnetic susceptibility, and major element composition data indicate that Jeju Island experienced the coldest climate around 18,000 cal yr BP, which corresponds to the last glacial maximum (LGM). Further, these multi-proxy data show an abrupt shift in climatic regime from cold and arid to warm and humid conditions at around 14,000 cal yr BP, which represents the commencement of the last major deglaciation. After the last major deglaciation, the TOC content decreased from 13,300 to 12,000 cal yr BP and from 11,500 to 9800 cal yr BP, thereby reflecting the weakening of the summer monsoon. The LGM in Jeju Island occurred later in comparison with the Chinese Loess Plateau. Such a disparity in climatic change events between central China and Jeju Island appears to be caused by the asynchrony between the coldest temperature event and the minimum precipitation event in central China and by the buffering effect of the Pacific Ocean.  相似文献   
10.
A detailed investigation of the fluvial geochemistry of the Han River system allows to estimate the rates of chemical weathering and the consumption of CO2. The Han River drains approximately 26,000 km2 and is the largest river system in South Korea in terms of both water discharge and total river length. It consists of two major tributaries: the North Han River (NHR) and the South Han River (SHR). Distinct differences in basin lithology (silicate vs. carbonate) between the NHR and SHR provide a good natural laboratory in which to examine weathering processes and the influence of basin geology on water quality. The concentrations of major elements and the Sr isotopic compositions were obtained from 58 samples collected in both summer and winter along the Han River system in both 2000 and 2006. The concentrations of dissolved loads differed considerably between the NHR and SHR; compared with the SHR, the NHR had much lower total dissolved solids (TDS), Sr, and major ion concentrations but a higher Si concentration and 87Sr/86Sr ratio. A forward model showed that the dissolved loads in the NHR came primarily from silicate weathering (55 ± 11%), with a relatively small portion from carbonates (30 ± 14%), whereas the main contribution to the dissolved loads in the SHR was carbonate weathering (82 ± 3%), with only 11 ± 4% from silicates. These results are consistent with the different lithologies of the two drainage basins: silicate rocks in the NHR versus carbonate rocks in the SHR. Sulfuric acid derived from sulfide dissolution in coal-containing sedimentary strata has played an important role in carbonate weathering in the SHR basin, unlike in the NHR basin. The silicate weathering rate (SWR) was similar between the NHR and SHR basins, but the rate of CO2 consumption in the SHR basin was lower than in the NHR basin due to an important role of sulfuric acid derived from pyrite oxidation.  相似文献   
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