Trace Element Analysis of NIST SRM 614 and 616 Glass Reference Materials by Laser Ablation Microprobe-Inductively Coupled Plasma-Mass Spectrometry   总被引：3，自引：0，他引：3  

Masanori Kurosawa  Simon E. Jackson  Shigeho Sueno 《Geostandards and Geoanalytical Research》2002,26(1):75-84

Fifty elements in NIST SRM 614 and 616 glass reference materials were determined by laser ablation microprobe-inductively coupled plasma-mass spectrometry (LAM-ICP-MS). The values determined for NIST SRM 614 agreed well with the NIST-certified and information values (mean relative difference ± 3.6%), except for B, Sc and Sb. The values determined for NIST SRM 616 agreed with the NIST-certified and information values within a mean relative difference of ± 1.5%, except for B, Sc and Ga. In addition, at an 80 μm sampling scale, NIST SRM 614 and 616 glass discs were homogeneous for trace elements within the observed precisions of 5 and 15% (mean), respectively. Detection limits were in the range 0.01 - 0.3 μg g⁻¹ for elements of lower mass numbers (amu < 80) and 1 - 10 ng g⁻¹ for heavy elements (amu > 80). Detection at the sub ng g⁻¹ level is possible for most of the heavy elements by using an ablation pit size larger than 10 0 μm.  相似文献   

岩体结构统计均质区的划分   总被引：6，自引：0，他引：6  

陈剑平  滕建仁 《地质灾害与环境保护》1996,7(1):19-24

本文介绍由Ｍｉｌｌｅｒ提出的基本概率统计理论的关联表分析，结合施密特投影图研究岩体统计均质区的划分方法。对该法进行了适当的修改，编写了相应的计算机程序。并对三峡永久船闸地区的岩体结构，进行了岩体结构统计均质区的划分，获得了良好的效果。  相似文献   

Characterizing rainfall–groundwater dynamics in a hard‐rock aquifer system using time series,geographic information system and geostatistical modelling          下载免费PDF全文

Deepesh Machiwal  Madan K. Jha 《水文研究》2014,28(5):2824-2843

The aim of this study was to investigate rainfall–groundwater dynamics over space and annual time scales in a hard‐rock aquifer system of India by employing time series, geographic information system and geostatistical modelling techniques. Trends in 43‐year (1965–2007) annual rainfall time series of ten rainfall stations and 16‐year (1991–2006) pre‐monsoon and post‐monsoon groundwater levels of 140 sites were identified by using Mann–Kendall, Spearman rank order correlation and Kendall rank correlation tests. Trends were quantified by Kendall slope method. Furthermore, the study involves novelty of examining homogeneity of pre‐monsoon and post‐monsoon groundwater levels, for the first time, by applying seven tests. Regression analysis between rainfall and post‐monsoon groundwater levels was performed. The pre‐monsoon and post‐monsoon groundwater levels for four periods – 1991–1994, 1995–1998, 1999–2002 and 2003–2006 – were subjected to geographic information system‐based geostatistical modelling. The rainfall showed considerable spatiotemporal variations, with a declining trend at the Mavli rainfall station (p‐value < 0.05). The Levene's tests revealed spatial homogeneity of rainfall at α = 0.05. Regression analyses indicated significant relationships (r² > 0.5) between groundwater level and rainfall for eight rainfall stations. Non‐homogeneity and declining trends in the groundwater level, attributed to anthropogenic and hydrologic factors, were found at 5–61 more sites in pre‐monsoon compared with post‐monsoon season. The groundwater declining rates in phyllite–schist, gneiss, schist and granite formations were found to be 0.18, 0.26, 0.21 and 0.14 m year^?1 and 0.13, 0.19, 0.16 and 0.02 m year^?1 during the pre‐monsoon and post‐monsoon seasons, respectively. The geostatistical analyses for four time periods revealed linkages between the rainfall and groundwater levels. Copyright © 2013 John Wiley & Sons, Ltd.  相似文献   

新疆地区年平均风速数据非均一影响研究     

周昊楠  华烨 《沙漠与绿洲气象(新疆气象)》2016,10(5):17-24

利用惩罚最大F检验(The Penized Maximal F Test,PMFT),对新疆地区105个国家级气象站点建站至2014年逐年平均风速资料进行了均一性检验,并通过订正得出新疆地区年平均风速均一化数据集合;通过对订正后数据与原始数据进行对比评估,讨论数据非均一性对新疆风速的影响,研究结论得出:(1)在95%的显著性水平下,检验出所有待检站点均出现非均一间断点,共计151个;(2)元数据中记录的人为影响因素,超过1/3对年平均风速序列产生了非均一影响,其中仪器换型对年平均风速序列影响最为显著,其次为环境变化;(3)仪器换型和站址迁移对年平均风速的非均一影响与台站风力大小成正比,其它人为因素对年平均风速的影响与台站风力大小成反比;(4)订正后,数据时间序列的均一性得到改善,数据序列明显的趋势拐点趋于缓和,下降趋势普遍增强,数据可用性进一步改善。  相似文献   

Automated Extraction of a Five‐Year LA‐ICP‐MS Trace Element Data Set of Ten Common Glass and Carbonate Reference Materials: Long‐Term Data Quality,Optimisation and Laser Cell Homogeneity          下载免费PDF全文

David Evans  Wolfgang Müller 《Geostandards and Geoanalytical Research》2018,42(2):159-188

LA‐ICP‐MS is increasingly applied to obtain quantitative multi‐element data with minimal sample preparation, usually achieved by calibration using reference materials (RMs). However, some ubiquitous RMs, for example the NIST SRM 61× series glasses, suffer from reported value uncertainties for certain elements. Moreover, no long‐term data set of analyses conducted over a range of ablation and tuning conditions exists. Thus, there has been little rigorous examination of the extent to which offsets between measured and reported values are the result of error in these values rather than analytically induced fractionation. We present new software (‘LA‐MINE’), capable of extracting LA‐ICP‐MS data with no user input, and apply this to our system, yielding over 5 years of data (~ 5700 analyses of ten glass and carbonate RMs). We examine the relative importance of systematic analytical bias and possible error in reported values through a mass‐specific breakdown of fourteen of the most commonly determined elements. Furthermore, these data, obtained under a wide range of different ablation conditions, enable specific recommendations of how data quality may be improved, for example the role of diatomic gas, the effect of differential inter‐glass fractionation factors and choice of transport tubing material. Finally, these data demonstrate that the two‐volume Laurin ablation cell is characterised by no discernible spatial heterogeneity in measured trace element ratios.  相似文献   

Automatic Interpretation of Magnetic Data Using Euler Deconvolution with Nonlinear Background   总被引：1，自引：0，他引：1  

Pawan Dewangan  T. Ramprasad  M. V. Ramana  M. Desa  B. Shailaja 《Pure and Applied Geophysics》2007,164(11):2359-2372

The voluminous gravity and magnetic data sets demand automatic interpretation techniques like Naudy, Euler and Werner deconvolution. Of these techniques, the Euler deconvolution has become a popular choice because the method assumes no particular geological model. However, the conventional approach to solving Euler equation requires tentative values of the structural index preventing it from being fully automatic and assumes a constant background that can be easily violated if the singular points are close to each other. We propose a possible solution to these problems by simultaneously estimating the source location, depth and structural index assuming nonlinear background. The Euler equation is solved in a nonlinear fashion using the optimization technique like conjugate gradient. This technique is applied to a published synthetic data set where the magnetic anomalies were modeled for a complex assemblage of simple magnetic bodies. The results for close by singular points are superior to those obtained by assuming linear background. We also applied the technique to a magnetic data set collected along the western continental margin of India. The results are in agreement with the regional magnetic interpretation and the bathymetric expressions.  相似文献   

Homogeneity of the Geochemical Reference Material BRP-1 (Paraná Basin Basalt) and Assessment of Minimum Mass     

Aloísio J.B. Cotta  Jacinta Enzweiler  Stephen A. Wilson  Carlos A. Pérez  Antonio J.R. Nardy  João H. Larizzatti 《Geostandards and Geoanalytical Research》2007,31(4):379-393

Reference materials (RM) are required for quantitative analyses and their successful use is associated with the degree of homogeneity, and the traceability and confidence limits of the values established by characterisation. During the production of a RM, the chemical characterisation can only commence after it has been demonstrated that the material has the required level of homogeneity. Here we describe the preparation of BRP-1, a proposed geochemical reference material, and the results of the tests to evaluate its degree of homogeneity between and within bottles. BRP-1 is the first of two geochemical RM being produced by Brazilian institutions in collaboration with the United States Geological Survey (USGS) and the International Association of Geoanalysts (IAG). Two test portions of twenty bottles of BRP-1 were analysed by wavelength dispersive-XRF spectrometry and major, minor and eighteen trace elements were determined. The results show that for most of the investigated elements, the units of BRP-1 were homogeneous at conditions approximately three times more rigorous than those strived for by the test of "sufficient homogeneity". Furthermore, the within bottle homogeneity of BRP-1 was evaluated using small beam (1 mm²) synchrotron radiation XRF spectrometry and, for comparison, the USGS reference materials BCR-2 and GSP-2 were also evaluated. From our data, it has been possible to assign representative minimum masses for some major constituents (1 mg) and for some trace elements (1-13 mg), except Zr in GSP-2, for which test portions of 74 mg are recommended.  相似文献   

Quality control and homogeneity of Turkish precipitation data     

Ozan Mert Göktürk  Deniz Bozkurt  Ömer Lütfi Şen  Mehmet Karaca 《水文研究》2008,22(16):3210-3218

Outlier trimming and homogeneity checking/correction were performed on the monthly precipitation time series of various lengths from 267 stations in Turkey. Outlier values are usually found during dry summer months, and are concentrated mostly over the southern parts of the country, where the dry period is most pronounced, implying natural extremes rather than wrong measurements. Homogeneity analysis was done using the Standard Normal Homogeneity Test, on an individual monthly basis, which led to many non‐testable series due to lack of reference stations, especially during summer months. Yet, remaining testable months were usually helpful for the assessment of homogenity, revealing a well distributed set of stations that proved to be homogeneous. There were still a number of stations which either could not be tested efficiently, or were classified as inhomogeneous. Lack of metadata is argued to be largely responsible for inefficient homogeneity testing. Copyright © 2008 John Wiley & Sons, Ltd.  相似文献   

Patterns of genetic and morphometric diversity in the marbled crab (Pachygrapsus marmoratus, Brachyura, Grapsidae) populations across the Tunisian coast   总被引：1，自引：1，他引：0  

Temim Deli  Hiba Bahles  Khaled Sai  Noureddine Chatti 《海洋学报(英文版)》2015,34(6):49-58

The present study reports on population structure analysis of the marbled crabPachygrapsus marmoratus (Fabricius, 1787) from the Tunisian coast, an appropriate location to study biogeographical process...  相似文献   

条斑紫菜SSU 中内含子分析     

李星辰  徐佳杰  林中姮  沈颂东 《海洋科学》2015,39(3):12-18

根据GenBank中已知的条斑紫菜(Porphyra yezoensis)SSU和LSU r RNA基因序列分别设计引物,分别以混合个体和单个个体的基因组DNA以及c DNA为模板进行扩增,测序分析后推测SSU r RNA基因中的内含子转录后加工可能仍被保留,而在LSU r RNA基因上游序列中没有发现内含子。长511bp的内含子位于SSU r RNA基因序列的上游,其插入位点为TCTGGTG-CCAGCAGCC,内含子5′和3′端的核苷酸序列分别为AAC-和-ATGG。该内含子的剪接位点以及保守区P,Q,R,S与I型内含子是不同的。研究发现,在同种紫菜中,不同个体SSU基因中内含子的有无、分布及结构特征是不同的,说明内含子对于分类是不太适合的。但是内含子的长度以及核苷酸序列在种间又具有一定的特异性,可以为红藻种间以及种内亲缘关系较远的亚种和不同地理群的区分和鉴定提供参考。  相似文献