Optimization of the Sampling Technique for the Determination of Dissolved Hydrogen in Groundwater     

Axel Heimann  Silke Marczinek  Karin Kloosb  Stefan Peiffer 《洁净——土壤、空气、水》2003,31(6):491-500

In this study a field‐sampling technique for dissolved hydrogen (H₂) in groundwater will be presented which allows the transport of gaseous samples into the laboratory for further analysis. The method consists of transferring the headspace trapped in a gas‐sampling bulb which is continuously purged by groundwater into previously evacuated vials using a gas‐tight syringe. Three transfer steps with preceding evacuation of the vial led to a H₂‐recovery of 100 % in laboratory experiments. The method has been applied to determine H₂ concentrations in an aquifer contaminated with chlorinated solvents. Tests concerning the effect of different pumping techniques on H₂ concentrations revealed that most reliable values were obtained with a bladder pump, while an electrically driven submersible pump generated considerable amounts of hydrogen due to electrochemical interactions with the sampled water. Concentrations of dissolved hydrogen in field and laboratory samples were about two orders of magnitude higher when sampling was performed with the electrically driven submersible pump compared to sampling with the bladder pump and a peristaltic pump. Lab experiments with a Plexiglas reservoir to produce H₂‐enriched water were used to study the effect of two tubing materials (PVC, polyamide) on H₂ losses. PVC tubing turned out to allow transfer of H₂‐enriched water over 25 m without significant losses, while PA‐tubing was not suitable for sampling of H₂.  相似文献   

水电解制氢设备在使用中应注意的问题     

刘希林  黄伟成  王永林  黎桂发 《气象研究与应用》2003,24(3):57-58

介绍GX-2型水电解制氢设备在使用过程中,对电解液的配制与氢气纯度分析应注意的问题。  相似文献   

ICP—AES法同时测定高纯氧化钇中稀土及非稀土杂质元素方法研究     

吕宝源  裘丽雯 《高校地质学报》1997,3(1):106-110

本文提出了用ＩＣＰ－ＡＥＳ法直接同时测定高纯氧化钇中１４个稀土和１６个非稀土杂质元素的分析方法，对被测元素的 谱线、氧化钇基本及背景影响进行了研究，用标准加入法测出氧化钇基准中的微量杂质元素，消除了由于忽略基准中的杂质元素含量给高纯氧化钇分析测定带来的误差，同时对工作条件进行了优化。方法中各被测元素的检出限为0.003～1.31ug/g，能够满足生产过程中的质量控制及进出口商品检验  相似文献   

Screening the current soil drainage class map of Flanders (Belgium) for its predictive quality     

J. Van de Wauw  P.A. Finke 《水文研究》2012,26(20):3003-3011

The predictive quality of the current drainage class map of Flanders was evaluated using data from two monitoring networks: one with good spatial coverage but poor temporal coverage and another with better temporal but poor spatial coverage. We combine both networks to obtain 1678 point predictions for mean highest water (MHW) and mean lowest water (MLW) tables by applying time series modelling and total least squares regression. The resulting MHW and MLW point data set was used to evaluate the currency of the existing map and to identify regional differences. The quality of the current map is moderate, and large differences occur between regions. Especially the Campine region shows large and systematic differences, whereas the southeastern hills and chalk–loam region is relatively accurate. If more weight is given to errors in the wetter drainage classes, about 50% of the area of Flanders would benefit from remapping. Copyright © 2011 John Wiley & Sons, Ltd.  相似文献   

茶皂甙纯化及其初步鉴定   总被引：5，自引：0，他引：5  

王廷吉  魏俊峰 《华东地质学院学报》1991,14(1):88-92

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光石沟花岗伟晶岩型铀矿小型重选试验及技术经济初步评价     

孙志富  冯明月 《铀矿地质》1994,10(6):334-342

光石沟花岗伟晶岩型铀矿小型重选试验为工业利用花岗伟晶岩铀矿床的矿石，特别是低品位矿石方面开拓了新的途径。试验证明重选法在回收花岗伟晶岩型铀矿床矿石的铀以及回收副产品和防止环境污染等方面均优于湿法冶炼，并有好的经济效益。  相似文献   

国内氢氧化镁阻燃剂的研究现状   总被引：6，自引：0，他引：6       下载免费PDF全文

姬连敏  李丽娟  聂锋  曾忠民 《盐湖研究》2007,15(2):62-72

综述了国内氢氧化镁阻燃剂的合成、表面改性及其应用,主要论述了近20年来国内在氢氧化镁阻燃剂研发方面取得的成果及发展方向,简单概述氢氧化镁阻燃剂的发展前景。  相似文献   

锂同位素质谱法测定及其样品制备研究进展   总被引：3，自引：0，他引：3       下载免费PDF全文

孙爱德  肖应凯 《盐湖研究》2001,9(4):64-71

近几十年来，锂同位素比值的测量得到了快速的发展。影响锂同位素比值测定因素很多，特别是在测定过程中分馏现象和记忆效应等都会引起锂同位素测定比值很大的误差。简要总结了锂同位素组成的质谱测定以及从天然样品（主要是固体样品）中提取纯化锂的方法。着重介绍了锂同位素测定中样品带使用的进展，从单带涂样发展到三带涂样，大大降低了测定中的锂同位素分馏。本文还对各种涂样形式的使用进行了比较。  相似文献   

柔性断层错动产物的微观研究方法初探   总被引：2，自引：0，他引：2  

姚大全  汤有标 《地震研究》1992,15(1):63-69

柔性断层错动产物一般尚未固结,难以对其进行定向取样,固化和磨制薄片,笔者经过长期努力提出解决这个问题的方法并将其应用于郯—庐断裂带赤山段晚更新世以来活动性的研究中。笔者按总结出的方法定向采取断层泥,对其固化并磨制定向薄片,在镜下仔细观测,发现众多变形现象和由其反映的运动学和动力学方面的重要信息。属脆性变形的有:长英质矿物颗粒被错移并形成棋盘格式构造,脆—塑或塑性变形发生在粘土和云母类的矿物中,尤其是“帚”状扭折和先扭后错现象在云母中非常普遍。恢复薄片的自然产状后,宏微观构造具统一性。据变形产物赋存的地质时代,它们应是断裂晚更新世以来活动的微观证据。文中笔者除系统介绍了柔性断层产物的采样、固结、磨片和应用此种技术的实例外,还探讨了显微构造分析在活断层研究中应有的地位和作用。  相似文献   

高纯球形-准球形亚微米晶质SiO2材料的制备与表征     

林金辉  周世一  康秀英 《矿物岩石》2007,27(1):7-10

以天然粉石英为基本原料,通过氢氟酸与盐酸混合酸溶蚀技术和机械强力搅拌处理,制备了高纯球形-准球形亚微米晶质SiO2材料。XRD,SEM表征结果表明,制备的高纯球形亚微米晶质SiO2材料为纯结晶SiO2相,粒子呈球形-准球形,球化-准球化率达80%～90%,粒径一般为300 nm～800 nm;其化学组成为:w(SiO2)99.90%,w(Al2O3)192×10-6,w(Fe2O3)33×10-6,w(Mg)1×10-6,w(Ca)2×10-6,w(Cl-)20×10-6。  相似文献