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1.
We show how the Yarkovsky effect can be understood as a heat engine. The output of the engine, manifested in the rate of change in semimajor axis of the body, has a maximum at an intermediate heat capacity, depending on the rotation rate of the body. This maximum arises because the work output depends on the product of the solar heat absorbed by the body and transported from its morning to evening side (this am-pm heat flux increases with heat capacity) and the Carnot efficiency (which declines with heat capacity). 相似文献
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对自20世纪80年代以来的大气热力学发展进行了综合评述, 阐述了如城市热岛效应、全球增暖等非传统大气热力学问题; 基于大气非平衡态热力学的非线性理论, 提出应发展突显热力学作用的数值模式, 并阐述其必要性和可能性。 相似文献
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《Chemie der Erde / Geochemistry》2016,76(3):419-428
Tooeleite, nominally Fe63+(As3+O3)4(SO4)(OH)4·4H2O, is a relatively uncommon mineral of some acid-mine drainage systems. Yet, if it does occur, it does so in large quantities, indicating that some specific conditions favor the formation of this mineral in the system Fe-As-S-O-H. In this contribution, we report the thermodynamic properties of synthetic tooeleite. The sample was characterized by powder X-ray diffraction, scanning electron microscopy, extended X-ray absorption fine-structure spectroscopy, and Mössbauer spectroscopy. These methods confirmed that the sample is pure, devoid of amorphous impurities of iron oxides, and that the oxidation state of arsenic is 3+. Using acid-solution calorimetry, the enthalpy of formation of this mineral from the elements at the standard conditions was determined as −6196.6 ± 8.6 kJ mol−1. The entropy of tooeleite, calculated from low-temperature heat capacity data measured by relaxation calorimetry, is 899.0 ± 10.8 J mol−1 K−1. The calculated standard Gibbs free energy of formation is −5396.3 ± 9.3 kJ mol−1. The log Ksp value, calculated for the reaction Fe6(AsO3)4(SO4)(OH)4·4H2O + 16H+ = 6Fe3+ + 4H3AsO3 + SO42− + 8H2O, is −17.25 ± 1.80. Tooeleite has stability field only at very high activities of aqueous sulfate and arsenate. As such, it does not appear to be a good candidate for arsenic immobilization at polluted sites. An inspection of speciation diagrams shows that the predominance field of Fe3+ and As3+ overlap only at strongly basic conditions. The formation of tooeleite, therefore, requires strictly selective oxidation of Fe2+ to Fe3+ and, at the same time, firm conservation of the trivalent oxidation state of arsenic. Such conditions can be realized only by biological systems (microorganisms) which can selectively oxidize one redox-active element but leave the other ones untouched. Hence, tooeleite is the first example of an “obligatory” biomineral under the conditions prevailing at or near the Earth's surface because its formation under these conditions necessitates the action of microorganisms. 相似文献
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本文从热力学基本定律出发，将复杂的成岩作用过程归结为各种不同的化学反应，从而建立了一套利用反应自由能定量确定成岩作用顺序的方法。该方法将沉积岩成岩作用历史研究从定性引向定量，使其更具理论依据，结果更可靠。利用本方法对国内外两个不同碎屑岩定量研究结果表明，这种方法获得的结果与传统方法的顺序完全一致，从而说明了该方法的良好实用性。 相似文献
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The magnetosphere dynamics shows fast relaxation events following power-law distribution for many observable quantities during magnetic substorms. The emergence of such power-law distributions has been widely discussed in the framework of self-organized criticality and/or turbulence. Here, a different approach to the statistical features of these impulsive dynamical events is proposed in the framework of the thermodynamics of rare events [Lavenda, B.H., Florio, A., 1992. Thermodynamics of rare events, Int. J. Theor. Phys. 31, 1455–1475; Lavenda, B.H., 1995. Thermodynamics of Extremes. Albion]. In detail, an application of such a novel approach to the magnetospheric substorm avalanching dynamics as monitored by the auroral electroject index is discussed. 相似文献
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霰粒子下落速度对云系及降水发展影响的数值研究 总被引：1，自引：0，他引：1
云和降水的形成是动力过程与微物理过程相瓦作用的产物,云数值模式中的微物理过程参数化方案对云和降水发展过程有直接影响.在云数值模式中,粒子群体的下落速度都足用质量加权下落末速度公式来表达,而且不同的模式采用的公式存在差异,质量加权下落末速度中参数取值不同,引起的粒子下落末速度不同.为了了解粒子下落末速度变化对云系和降水发展的影响,对2004年8月12日一次冷锋降水过程,利用中尺度ARPS模式做模拟研究.在分析降水机制的基础上,对霰这一下落末速度较大的降水粒子,做下落末速度(Vg)的敏感性试验,从动力、热力、微物理的角度,通过数值模拟对比分析了霰下落末速度减小对降水分布和强度、云系的移动、云系的宏观热力和动力场的影响,并给出了影响的途径和机理.结果表明:Vg变化对云的厚度和含水量有影响,下落末速度减小对冰晶、雪、霰的含水量垂直分布及分布随时间变化影响较大,其中,霰的含水量显著减少,雪的含水量增加,并调整了云中水质粒的空间分布;Vg减小对地面累积总降水量的分布影响较小,但对降水强度的分布影响较大.Vg减小时,降水强度减小,降水时间延迟,因此,霰下落末速度变化将调整底层降水分布;对于云系的移动情况基本上没有影响,但对云中水质粒的空间分布有影响;霰下落末速度变化影响云中霰的融化和撞冻增长从而影响热力场.末速度减小时,霰和雪的融化罱明显减小,导致非绝热冷却率的减小,引起下沉气流的减小. 相似文献
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