排序方式： 共有26条查询结果，搜索用时 156 毫秒
1.
电感耦合等离子体质谱法测定铅合金中的微量杂质元素镉和锡 总被引：1，自引：1，他引：0
铅合金中的镉和锡由于含量较低,国家标准方法均为单一元素分析,步骤繁琐,检出限高,难以达到理想的检出要求。本文建立了应用电感耦合等离子体质谱法(ICP-MS)测定铅合金中微量级(μg/g级)杂质元素镉和锡的分析方法。采用单一的低浓度硝酸溶解铅合金,用低温慢溶的方式使样品溶解更加完全,减少了多离子对仪器的干扰;通过铅基体匹配和加入酒石酸保证了标准与样品介质的一致性,同时避免了锡的水解;以~(103)Rh作为内标元素,~(111)Cd和~(118)Sn作为测量同位素克服了质谱干扰。方法检出限为镉0.05 ng/g、锡0.04 ng/g,比国家标准方法的检出限(1~6μg/g)低,精密度小于4%。该方法试剂用量少,减少了处理样品的复杂性,实现了合金中微量级元素的准确测定。 相似文献
2.
详述数字电极的系统构成、电路结构、通信协议和其他关键技术。该系统的通信网络结构基于RS-485现场总线,通过环境测试和台站试验,发现数字电极技术适用于多极距电阻率系统。 相似文献
3.
4.
大地电磁测深需要采集正交的天然电磁场信号,其中大地电场信号微弱且易受环境噪声影响.为了提高大地电场的测量精度,本文通过试制新型Pb-PbCl2不极化电极和改变电极的掩埋方式,室内和野外对比实验结果表明:试制电极具有级差小、稳定时间长的优点;采用加桶加水的方式掩埋电极,不仅可以提高电极极差的稳定性,还有利于减小电极极差突变的机率;电极掩埋深度对电极的稳定性影响很大,深埋电极可以有效抑制电极极差的漂移.另外,野外大地电磁数据采集时难免会遇到了一些沙漠、河流等特殊地形,采用传统的测量方式无法采集到精确的大地电场信号,本文通过对比实验,总结了在特殊地形条件下大地电磁信号采集的技术要点,如在沙漠地区,电极坑中应加入大量泥浆以减小电极的接地电阻,当测点在河流附近时,电极对不应跨过河面,减小自然电位对大地电场的影响. 相似文献
5.
Electrogeochemical sampling with
Reinhard W. Leinz Donald B. Hoover David L. Fey David B. Smith Thaxson Patterson 《Journal of Geochemical Exploration》1998,61(1-3)
Electrogeochemical extraction methods are based on the migration of ions in an electric field. Ions present in soil moisture are transported by an applied current into fluids contained in special electrodes placed on the soil. The fluids are then collected and analyzed. Extractions are governed by Faraday's and Ohm's laws and are modeled by the operation of a simple Hittorf transference apparatus. Calculations show that the volume of soil sampled in an ideal electrogeochemical extraction can be orders of magnitude greater than the volumes used in more popular geochemical extraction methods, although this has not been verified experimentally.
is a method of in-situ electrogeochemical extraction that was developed in the former Soviet Union and has been tested and applied internationally to exploration for buried mineral deposits. Tests carried out at the United States Geological Survey (
) indicated that there were problems inherent in the use of
technology. The cause of the problems was determined to be the diffusion of acid from the conventional electrode into the soil. The
electrode incorporates two compartments and a salt bridge in a design that inhibits diffusion of acid and enables the collection of anions or cations. Tests over a gold-enriched vein in Colorado and over buried, Carlin-type, disseminated gold deposits in northern Nevada show that there are similarities and differences between
results and those by partial extractions of soils which include simple extractions with water, dilute acids and solutions of salts used as collector fluids in the electrodes. Results of both differ from the results obtained by total chemical digestion. The results indicate that
responds to mineralized faults associated with disseminated gold deposits whereas partial and total chemical extraction methods do not. This suggests that faults are favored channels for the upward migration of metals and that
may be more effective in exploration for the deposits. It defines anomalies that are often narrow and intense, an observation previously made by
researchers. The field tests show that
is less affected by surface contamination. A test over the Mike disseminated gold deposit indicates that the method may not be effective for locating deposits with impermeable cover. Faradaic extraction efficiencies of 20–30%, or more, are frequently achieved with
and the method generally shows good reproducibility, especially in extraction of major cations. However, ions of other metals that are useful in exploration, including Au and As, may be collected in low and temporally variable concentrations. The reason for this variability is unclear and requires further investigation. 相似文献
Full-size image
Full-size image
Full-size image
Full-size image
Full-size image
Full-size image
Full-size image
Full-size image
Full-size image
Full-size image
6.
7.
三维地电模型数值模拟中视电阻率真假异常特征分析 总被引：2，自引：0，他引：2
本文概要介绍了三维数值模拟中双网格系统的剖分方法,并通过几种典型模型的有限单元法三维数值模拟计算（网格单元电导率分块均匀、电位三线性变化）,充分揭示了对称四极电阻率测深法三维地电模型视电阻率真假异常的分布规律,分析了产生真假异常的原因,并研究了真异常的形态与引起真异常的地质体位置的关系。 相似文献
8.
9.
Carbon Capture Sequestration (CCS) projects require, for safety reasons, monitoring programmes focused on surveying gas leakage on the surface. Generally, these programmes include detection of chemical tracers that, once on the surface, could be associated with CO2 degassing. We take a different approach by analysing feasibility of applying electrical surface techniques, specifically Self-Potential. A laboratory-scale model, using water-sand, was built for simulating a leakage scenario being monitored with non-polarisable electrodes. Electrical potentials were measured before, during and after gas injection (CO2 and N2) to determine if gas leakage is detectable. Variations of settings were done for assessing how the electrical potentials changed according to size of electrodes, distance from electrodes to the gas source, and type of gas. Results indicated that a degassing event is indeed detectable on electrodes located above injection source. Although the amount of gas could not be quantified from signals, injection timespan and increasing of injection rate were identified. Even though conditions of experiments were highly controlled contrasting to those usually found at field scale, we project that Self-Potential is a promising tool for detecting CO2 leakage if electrodes are properly placed. 相似文献
10.
George W. Luther III Brian T. Glazer Shufen Ma Robert E. Trouwborst Tommy S. Moore Edouard Metzger Chareonkwan Kraiya Tim J. Waite Gregory Druschel Bjrn Sundby Martial Taillefert Donald B. Nuzzio Timothy M. Shank Brent L. Lewis Paul J. Brendel 《Marine Chemistry》2008,108(3-4):221-235
Solid-state voltammetric (micro)electrodes have been used in a variety of environments to study biogeochemical processes. Here we show the wealth of information that has been obtained in the study of sediments, microbial mats, cultures and the water column including hydrothermal vents. Voltammetric analyzers have been developed to function with operator guidance and in unattended mode for temporal studies with an in situ electrochemical analyzer (ISEA). The electrodes can detect the presence (or absence) of a host of redox species and trace metals simultaneously. The multi-species capacity of the voltammetric electrode can be used to examine complex heterogeneous environments such as the root zone of salt marsh sediments. The data obtained with these systems clearly show that O2 and Mn2+ profiles in marine sedimentary porewaters and in microbial biofilms on metal surfaces rarely overlap indicating that O2 is not a direct oxidant for Mn2+. This lack of overlap was suggested originally by Joris Gieskes' group. In waters emanating from hydrothermal vents, Fe2+, H2S and soluble molecular FeS clusters (FeSaq) are detected indicating that the reactants for the pyrite formation reaction are H2S and soluble molecular FeS clusters. Using the ISEA with electrodes at fixed positions, data collected continuously over three days near a Riftia pachyptila tubeworm field generally show that O2 and H2S anti-correlate and that H2S and temperature generally correlate. Unlike sedimentary environments, the data clearly show that Riftia live in areas where both O2 and H2S co-exist so that its endosymbiont bacteria can perform chemosynthesis. However, physical mixing of diffuse flow vent waters with oceanic bottom waters above or to the side of the tubeworm field can dampen these correlations or even reverse them. Voltammetry is a powerful technique because it provides chemical speciation data (e.g.; oxidation state and different elemental compounds/ions) as well as quantitative data. Because (micro)organisms occupy environmental niches due to the system's chemistry, it is necessary to know chemical speciation. Voltammetric methods allow us to study how chemistry drives biology and how biology can affect chemistry for its own benefit. 相似文献