Geostatistical estimation of chemical contamination in stream sediments: The case study of Vale das Gatas mine (northern Portugal)     

A.R. Salgueiro  P. Freire vila  H. Garcia Pereira  J.M. Santos Oliveira 《Journal of Geochemical Exploration》2008,98(1-2):15

Based on an environmental geochemistry case study carried out in the neighbourhood of a W–Sn abandoned mine, the pollution in stream sediments was modelled through a Global Contamination Index. Such an index permits one to summarize the combination of deleterious elements in a single variable, obtained by the projection of samples onto the first axis of a PCASD (Principal Components Analysis of Standardized Data) applied to the entire n × p matrix containing the available concentrations of p = 16 elements in the set of n = 220 collected samples.In order to provide a sound basis for a coherent planning of the remediation process which will be put in operation in the affected area, it is necessary to balance the costs of reclaiming with the probabilities of exceeding the upper limits accepted for concentrations of environmentally harmful elements in sediments. Given these limits, they are back-transformed in the index values, providing a practical threshold between ‘clean’ and ‘contaminated’ samples. On the other hand, the minimum dimension of the cell to be reclaimed is restrained by the selected remediation process to be applied in the affected area. Hence, to meet the constraints of such a remediation process, it is required to estimate the probabilities of exceeding the index threshold in technologically meaningful sub-areas. For this end, the Indicator Block Kriging technique was applied, producing a series of maps where sub-areas to be reclaimed can be spotted for different probability levels. These maps, on which the decision making remediation agency can rely for its cost-benefit analysis, take into account both the spatial structure of ‘clean’ vs. ‘contaminated’ samples and the constraints of the reclaiming process.  相似文献   

拉萨地体东南缘的多期深熔作用及动力学   总被引：13，自引：7，他引：6  

王金丽  张泽明  石超 《岩石学报》2008,24(7)

位于青藏高原班公湖-怒江蛇绿岩带与印度-雅鲁藏布江蛇绿岩带之间拉萨地体东南缘的前寒武纪结晶基底经历了角闪岩相-麻粒岩相区域变质作用和强烈的混合岩化.研究区可识别出两期深熔作用,第一期为斜长角闪岩部分熔融形成的花岗闪长岩脉体,其与围岩一起发生了变质与变形再造,转变成了黑云斜长片麻岩.第二期为含夕线石石榴石片麻岩部分熔融形成的含石榴石斜长石花岗岩脉体.岩石化学成分显示,第一期深熔脉体具有埃达克岩的典型地球化学特征,其SiO2=63.81%,Al2O3=16,92%,MgO=1.86%,Na2O=4.22%,K2O=1.81%,K2O/Na2O=0.43,并显示出LREE富集、无Eu异常的BEE配分模型,同时明显富Sr(366×10-6),贫Y(12×10-6)和Yb(0.4×10-6),Sr/Y=30.舍石榴石斜长石花岗岩主要由斜长石、石英和石榴石组成,含少量白云母和黑云母,其全岩SiO2=71.14%,Al2O3=14.26%,K2O=0.26%,Na2O=2.79%.CaO=2.94%.过铝指数A/CNK=1.40,为典型的过铝花岗岩.黑云斜长片麻岩脉体中的大多数锆石具有同心韵律状结晶环带和较高的Th//U比值(0.433～1.167),为典型的岩浆结晶锆石.锆石岩浆结晶域U-Pb原位定年给出了64.0±1.0Ma(MSWD=8.7)加权平均年龄;个别锆石变质交生边给出了27.9 Ma的谐和年龄,同时具有较低的Th/U比值(0.019),应代表后期叠加的变质热事件年龄.含石榴石斜长石花岗岩中的锆石均发育同心韵律状环带,而且具有较高的Th/U比值(0.196～1.212).所获得的谐和年龄在27.0～34.1Ma之间(加权平均年龄为29.3±0.9 Ma),应代表过铝花岗岩的结晶年龄.因此,我们认为拉萨地体东南缘变质基底在古近纪经历了两期深熔作用,第一期发生在约65Ma,在特提斯洋壳俯冲和印度板块与拉萨地体碰撞的动力学体制下,拉萨地体下地壳加厚和升温,发生了麻粒岩相变质和部分熔融,形成了埃达克岩质的花岗闪长岩浆;第二期混合岩化作用发生在约30Ma,在印度板块与拉萨地体碰撞后伸展的动力学体制下,高角闪岩相泥质变质岩中的含水矿物脱水熔融形成了过铝质花岗闪长岩浆.  相似文献   

广东三水盆地晚自垩世—始新世古地磁研究及构造意义     

侯红明  袁友仁  张毅祥  汤贤赞  王保贵 《热带海洋学报》1994,(4)

对广东三水盆地上白垩统三水组、大　山组、古新统莘庄组及始新统　心组、宝月组的系统的古地磁研究结果表明：（１）旋转运动是该区构造运动的主要形式，顺时针旋转盆地拉张发育，这时针旋转盆地挤压衰亡，发育的程度与旋转角度有关；（２）始新世该区旋转方向由顺时针旋转变为道时针旋转，对应于太平洋－库拉板块对欧亚板块作用方向的改变，说明三水盆地的形成发育与太平洋－库拉板块对欧亚板块的作用密切相关；（３）三水盆地所在的华南地块从晚白垩世至始新世在纬向上不存在明显的运动，一直停留在略低于现今纬度的位置上。  相似文献   

鄂尔多斯地块早白垩世构造-热事件:杭锦旗玄武岩的Ar-Ar年代学证据   总被引：8，自引：3，他引：5  

邹和平  张珂  李刚 《大地构造与成矿学》2008,32(3)

在鄂尔多斯地块北部杭锦旗黑石头沟,于下白垩统砂岩之上发现了一层玄武岩。其SiO2(46.93%)较低而碱含量(K2O+Na2O=6.21%)较高,组合指数σ=8.0,含标准矿物Ne,属于碱性橄榄玄武岩。Ar-Ar激光阶段加热定年结果表明,该玄武岩具有126.2±0.4Ma的Ar-Ar年龄。年龄数据表明杭锦旗黑石头沟玄武岩形成于早白垩世,反映鄂尔多斯地块在早白垩世发生了一次构造-岩浆-热事件,这与华北、乃至整个中国东部在早白垩世发生了较普遍的构造-岩浆-热事件具有一致性。这次构造-岩浆-热事件可能引起深部流体自地下深部上涌及在地块内部运移,为各种成矿元素的迁移、沉淀、富集和成矿创造了合适条件。  相似文献   

Numerical simulation of a stratigraphic model     

Véronique Gervais  Roland Masson 《Computational Geosciences》2008,12(2):163-179

A multi-lithology diffusive stratigraphic model is considered, which simulates at large scales in space and time the infill of sedimentary basins governed by the interaction between tectonics displacements, eustatic variations, sediment supply, and sediment transport laws. The model accounts for the mass conservation of each sediment lithology resulting in a mixed parabolic, hyperbolic system of partial differential equations (PDEs) for the lithology concentrations and the sediment thickness. It also takes into account a limit on the rock alteration velocity modeled as a unilaterality constraint. To obtain a robust, fast, and accurate simulation, fully and semi-implicit finite volume discre tization schemes are derived for which the existence of stable solutions is proved. Then, the set of nonlinear equations is solved using a Newton algorithm adapted to the unilaterality constraint, and preconditioning strategies are defined for the solution of the linear system at each Newton iteration. They are based on an algebraic approximate decoupling of the sediment thickness and the concentration variables as well as on a proper preconditioning of each variable. These algorithms are studied and compared in terms of robustness, scalability, and efficiency on two real basin test cases.  相似文献   

Multi-stage metallogeny in the southwestern part of South China,and paleotectonic and climatic implications: A high precision geochronologic study     

《地学前缘(英文版)》2023,14(3):101536

The South China Block (SCB) is among the large-scale W-Sn mineralized regions of the globe. The Laojunshan W-Sn-dominant ore area (LOA) in the western part of the SCB preserves the records of the tectonic history of the Tethys realm extending through North Vietnam, and Yangtze to Cathaysia blocks, with coeval formation of giant metallic deposits. The prolonged tectonic activities and their control on the genesis and spatio-temporal distribution of giant metallic deposits in the LOA provide a window for a holistic understanding of the tectono-metallogenesis of the SCB. In this study, we present results from a multi-chronologic study to determine the timing of formation of the cassiterite-wolframite-scheelite mineralization. The results suggest three distinct tectono-metallogenic periods in the LOA during the geodynamic evolution of the surrounding tectonic units. The opening of the Proto-Tethys Ocean between the Yangtze-Indochina blocks and the westward Paleo-Pacific subduction beneath the Cathaysia block (420–380 Ma) jointly contributed to the Silurian to early Devonian intracontinental orogeny in the middle of the SCB that involved top-to-the-north thrusting along NE-striking shear zones. This event generated the Dulong-Song Chay granitoids, together with the formation of Xinzhai Sn deposit related to sheared mylonitic granites (ca. 419 Ma) and pegmatites (ca. 389 Ma), which include the early-stage Sn-sulfide skarn (ca. 418 Ma) and the late-stage Sn-bearing schist (ca. 389 Ma). During the Late Permian to Late Triassic (260–220 Ma), with the closure of the Proto-Tethys oceans in the west and ongoing Paleo-Pacific westward subduction in the east, the SCB and Indochina Block (IB) were amalgamated which also marks the time of formation of the Nanwenhe scheelite skarn deposit. The subducted Paleo-Tethys oceanic crust was likely entrained by the nearby rising Emeishan mantle plume (270–259 Ma), which formed the Maguan diabase (ca. 260 Ma) that shows significantly older Re-Os model age of ca. 268 Ma, suggesting that the Nanwenhe mineralization is potentially derived from ca. 260 Ma source. Furthermore, the intraplate shortening induced thin skinned crustal deformation and low grade metamorphism (ca. 230 Ma), with the main stage of scheelite-Sn-Mo mineralization (229.9, 229.8 and 219 Ma) and contemporary formation of the pegmatite (230.7 Ma). The Late Cretaceous involved two episodes of alternate extension and shortening, driven by the subduction polarity change from northwestward subduction of the Okhotomorsk block to northward subduction of the NeoTethys seafloor. The evolution of the LOA consists of the NW–SE transpression ending ca. 100 Ma, the WNW–ESE extension in the earlier episode lasting from 100 Ma to 86 Ma, the WNW–ESE transpression beginning at ca. 85 Ma and the NS extension in the later episode during the latest Cretaceous, which produced the extension-related three periods of Laojunshan granitic magmatism and coeval Sn-W mineralization, with ages in the range of 90–89 Ma, 87–85 Ma and 83–79 Ma. We also evaluate the implications of magmatic-metamorphic-metallogenic degassing on the regional paleoclimatic history.  相似文献   

Monazite behaviour and age significance in poly-metamorphic high-grade terrains: A case study from the western Musgrave Block, central Australia     

Nigel M. Kelly  Geoffrey L. Clarke  Simon L. Harley 《Lithos》2006,88(1-4):100-134

Integrated, in situ textural, chemical and electron microprobe age analysis of monazite grains in a migmatitic metapelitic gneiss from the western Musgrave Block, central Australia has identified evidence for multiple events of growth and recrystallisation during poly-metamorphism in the Mesoproterozoic. Garnet + sillimanite-bearing metapelite underwent partial melting and segregation to palaeosome and leucosome during metamorphism between 1330 and 1296 Ma, with monazite grains in leucosome recording crystallisation at 1300 Ma. Monazite breakdown during melting is inferred to have occurred in the palaeosome. During a subsequent granulite facies event at 1200 Ma, deformation and metamorphism of leucosome and palaeosome resulted in partial disturbance of ages and potential minor growth on 1300 Ma monazite in leucosome. Growth of new, high-Y (+HREE) monazite in palaeosome domains occurred during garnet breakdown in the presence of sillimanite to cordierite and spinel, as a result of post-peak isothermal decompression. Diffusive enrichment of resorbed garnet rims in Y + HREE suggests garnet breakdown occurred slower than volume diffusion of REE. Monazite in both palaeosome and leucosome were subsequently partially to penetratively recrystallised during a retrogression event that is suggested to have occurred at 1150–1130 Ma. The intensity of recrystallisation and disturbance of ages appears linked to proximity to retrogressed garnet porphyroblasts and their occurrence in the relatively reactive or ‘fertile’ local environments provided by the palaeosome/mesosome volumes, which caused localised changes in retrogressive fluids towards compositions more aggressive to monazite. Like reaction textures, it is apparent that domainal equilibrium and reaction may control or at least strongly influence monazite REE and U–Th–Pb chemistry and hence ages.  相似文献   

Assembly of Proterozoic Australia: implications of a revised pole for the ∼1070 Ma Alcurra Dyke Swarm, central Australia     

Phillip W. Schmidt  George E. Williams  Alfredo Camacho  James K. W. Lee 《Geophysical Journal International》2006,167(2):626-634

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滑坡稳定性分析与安全系数取值研究   总被引：5，自引：0，他引：5  

徐青  陈士军  陈胜宏 《中国地质灾害与防治学报》2006,17(3):58-62

在地质灾害中,滑坡灾害分布最广、发生频率最高、危害最大,是我国地质灾害防治的主要对象。滑坡研究的主要任务之一是稳定性分析。论文针对三板溪水电站进水口滑坡和水布垭水电站大岩淌滑坡,分别采用刚体极限平衡法、块体单元法、有限单元法对稳定安全系数和条间推力分布曲线进行分析和比较,研究各种方法的差异和计算精度,以及各种方法稳定安全系数的取值标准,希望为水利水电工程边坡设计规范有关有限单元法、块体单元法条目的编写和相应的允许安全系数取值标准的制定提供一定的参考。研究结果表明:①块体单元法计算的安全系数与刚体极限平衡法计算的安全系数可以采用相同的取值标准,而有限单元法计算的安全系数取值标准可适当降低;②块体单元法计算的条间水平推力、条间剪切力与刚体极限平衡法(尤其是Sarma法)计算的条间水平推力、条间剪切力非常相近,有限单元法计算的条间水平推力、条间剪切力较小;③分析方法、力学模型与参数取值应与安全系数取值标准相匹配。  相似文献   

苏皖地块－－特提斯演化阶段独立的构造单元   总被引：31，自引：1，他引：31       下载免费PDF全文

吴根耀  陈焕疆  马力  徐克定 《古地理学报》2002,4(2):77-87

基于苏皖地区的基底性质、晚元古代-中生代特征的沉积-火成建造、区域成矿和构造专属性，结合古地磁资料，提出了苏皖地块是特提斯演化阶段独立的构造单元的观点。它以苏鲁洋与华北克拉通间隔。震旦纪-早古生代的建造及变形特征与扬子克拉通有差异。石炭纪末和早二叠世的沉积和生物群表明它当时是古特提斯洋域里的一个中间地块，此时它已独立于扬子克拉通之外。三叠纪时苏鲁洋发生过大规模的消减但未闭合，因而苏皖地块的晚三叠世植物群与扬子克拉通有较明显区别。苏皖地块与华北克拉通（指胶辽地块）碰撞可能发生在早白垩世，该地区超高压变质岩的折返与之有关。之后，苏皖地块成为亚洲大陆雏形的一部分。  相似文献