Origin of Fe-Ti Oxide Ores in Mafic Intrusions: Evidence from the Panzhihua Intrusion, SW China   总被引：12，自引：0，他引：12  

Pang  Kwan-Nang; Zhou  Mei-Fu; Lindsley  Donald; Zhao  Donggao; Malpas  John 《Journal of Petrology》2008,49(2):295-313

Economic concentrations of Fe–Ti oxides occur as massive,conformable lenses or layers in the lower part of the Panzhihuaintrusion, Emeishan Large Igneous Province, SW China. Mineralchemistry, textures and QUILF equilibria indicate that oxidesin rocks of the intrusion were subjected to extensive subsolidusre-equilibration and exsolution. The primary oxide, reconstructedfrom compositions of titanomagnetite in the ores and associatedintergrowths, is an aluminous titanomagnetite (Usp₄₀) with 40wt % FeO, 34 wt % Fe₂O₃, 16·5 wt % TiO₂, 5·3 wt% Al₂O₃, 3·5 wt % MgO and 0·5 wt % MnO. This compositionis similar to the bulk composition of the oxide ore, as inferredfrom whole-rock data. This similarity strongly suggests thatthe ores formed from accumulation of titanomagnetite crystals,not from immiscible oxide melt as proposed in earlier studies.The occurrence of oxide ores in the lower parts of the Panzhihuaintrusion is best explained by settling and sorting of densetitanomagnetite in the ferrogabbroic parental magma. This magmamust have crystallized Fe–Ti oxides relatively early andabundantly, and is likely to have been enriched in Fe and Tibut poor in SiO₂. These features are consistent with fractionationof mantle-derived melts under relatively high pressures (10kbar), followed by emplacement of the residual magma at 5 kbar.This study provides definitive field and geochemical evidencethat Fe–Ti oxide ores can form by accumulation in ferrogabbro.We suggest that many other massive Fe–Ti oxide depositsmay have formed in a similar fashion and that high concentrationsof phosphorus or carbon, or periodic fluctuation of fO₂ in themagma, are of secondary importance in ore formation. KEY WORDS: ELIP; Fe–Ti oxide ore; layered intrusion; Panzhihua; QUILF  相似文献   

洛川黄土-红粘土序列铁氧化物组成及其古气候指示   总被引：2，自引：0，他引：2  

谢巧勤  陈天虎  孙玉兵  李晓萱  徐晓春 《矿物学报》2008,28(4)

对洛川黄土、古土壤和红粘土中磁性矿物组成、成因和相关系进行了研究。结果表明:黄土磁性矿物以风尘磁铁矿为主,少量的成土赤铁矿和成土磁赤铁矿;古土壤磁性矿物以成土磁赤铁矿为主,成土赤铁矿次之,少量的风尘磁铁矿和赤铁矿;红粘土磁性矿物以成土赤铁矿为主,风尘磁铁矿和成土磁赤铁矿次之,少量风尘赤铁矿。黄土、古土壤和红粘土磁性矿物组成差异,反映了其形成期不同的古气候特性以及不同气候条件下生物地球化学作用强度的差异。干冷的冰期,黄土弱成土作用形成了以粗颗粒的风尘磁铁矿核 赤铁矿边的磁化率载体。间冰期的温暖湿润的古气候最有利于生物活动,强烈生物活动导致古土壤中大量纳米超细磁赤铁矿/磁铁矿产生,形成以磁赤铁矿为主,风尘磁铁矿核 赤铁矿边为辅的磁化率载体。红粘土成壤期,强降雨强蒸发的长干短湿的高温炎热的古气候使得红粘土化学风化强烈,生物地球化学活动较弱,形成以磁铁矿核 赤铁矿边和磁赤铁矿核 赤铁矿边的磁化率载体。黄土、古土壤和红粘土磁性矿物组成、磁性矿物相关系是其形成期独特的古气候指示。  相似文献   

膜生物反应器中膜污染机理及其防治     

宋志伟  杨帆  任南琪 《吉林大学学报(地球科学版)》2008,38(4)

通过向一体式膜生物反应器中分别投加聚合铝和粉煤灰改变料液性质,来预防膜污染和提高膜生物反应器对总磷的去除效率,并通过X射线衍射和红外光谱实验分析活性污泥性质的变化,利用扫描电镜分析中空纤维膜表观结构的变化情况,探讨防治膜污染的机理.实验结果表明:聚合铝的投加改变了活性污泥的性质和生物膜的表观结构,可有效地减缓膜污染,且除磷效率达85%以上;而投加粉煤灰并没有明显效果.  相似文献   

氧化锰矿物的生物成因及其性质的研究进展   总被引：5，自引：0，他引：5  

刘凡  冯雄汉  陈秀华  邱国红  谭文峰  贺纪正 《地学前缘》2008,15(6):66

土壤中的氧化锰矿物是原生矿物风化和成土过程的产物,是最具反应活性的一类矿物,决定着环境中许多物质的形态、迁移和转化,在元素生物地球化学循环中起着重要的作用,其形成机制和环境效应备受关注。已有的研究表明,环境中氧化锰的形成与微生物作用紧密相关,微生物作用可使自然环境中的Mn(Ⅱ)氧化速率提高105倍。参与Mn(Ⅱ)氧化的微生物在环境中广泛存在,已知的典型锰氧化细菌分布在变形菌门、放线菌门或厚壁菌门,它们均通过胞外聚合物中的多铜氧化酶来催化氧化Mn(Ⅱ)。细菌氧化Mn(II)成Mn(Ⅳ)是酶催化的两个连续的快速单电子传递过程,Mn(Ⅲ)在溶液中以与酶结合的瞬时中间态出现。生物形成氧化锰的最初形态为层状锰矿物,与δ-MnO2或酸性水钠锰矿很类似,且结晶弱,粒径小,锰氧化度高,结构中的八面体空穴多,因而比化学形成的氧化锰具有更强的吸附、氧化等表面活性。环境中Mn(Ⅱ)微生物氧化及形成的Mn(Ⅲ)中间体与碳、氮、硫等生命元素的地球化学循环的关系令人关注。  相似文献   

Laboratory study of the rates and products of the phototransformations of naphthalene adsorbed on samples of titanium dioxide,ferric oxide,muscovite, and fly ash     

Chantal Guillard  Hervé Delprat  Can Hoang-van  Pierre Pichat 《Journal of Atmospheric Chemistry》1993,16(1):47-59

The photodegradation of naphthalene (NPH), chosen as a model of polynuclear aromatic pollutants, has been studied in the presence of a layer of four water-insoluble inorganic solids which can be found in the troposphere (TiO₂, Fe₂O₃, muscovite, and a fly ash sample). Direct photolysis of NPH is negligible at >340 nm. Dark adsorption of NPH on TiO₂ (mainly anatase, nonporous, 50 m² g^–1) at 293 K corresponds to a surface coverage ofca. 50% at equilibrium. Under these conditions (saturated surface), the stationary-state photocatalytic degradation reaches 0.4 molecule nm^–2 h^–1 (>340 nm, radiant fluxca. 22 mW cm^–2). Dioxygen is required and its partial pressure in air is such that the degradation is zero order in O₂. Water vapor markedly increases the rate. The other particulates have also an effect, less important than that of TiO₂, however quite noticeable with respect to surface area unit for the fly ash sample which contains 3.2% Fe₂O₃. Apart from 1,4-naphthoquinone, which is the main intermediate product in all cases, 2-naphthol, phthalide, phthaldialdehyde, phthalic acid, acetophenone, benzaldehyde, benzoic acid are also formed on dry TiO₂. Depending on their volatility, these compounds are transferred to the gas phase or remain principally adsorbed on the solid particles where they are further transformed. For instance, phthalic acid (or anhydride) and benzoic acid are generated from 1,4-naphthoquinone. Degradation mechanisms are briefly discussed.  相似文献   

Kinetics of redox cycling of iron coupled with fulvic acid     

Yiwei Deng  Werner Stumm 《Aquatic Sciences - Research Across Boundaries》1993,55(2):103-111

The kinetics of conversion of iron(III) (hydr)oxides to ferrous iron mediated by fulvic acid have been investigated in order to improve the understanding of the redox cycling of iron at the oxic-anoxic boundary in natural waters. Under the conditions similar to natural waters, fulvic acid is able to reduce the iron(III) (hydr)oxide. The kinetics of the reaction depend on the reactivity of iron(III) (hydr)oxides and the reducing power of the fulvic acid. The rate of reaction is 60 nm/h obtained under following conditions: total concentration of Fe(III) 1.0 × 10^–4 M, pH 7.5, fulvic acid 5 mg/L. The rate is considered as a net result of reduction and oxidation in the > Fe^III-OH/Fe(II) wheel coupled with fulvic acid. In a real natural water system, reductants other than fulvic acid may be of importance. The results obtained in the laboratory, however, provide evidence that the Fe(OH)₃(s)/Fe(II) redox couple is able to act as an electron-transfer mediator for the oxidation of natural organic substances, such as fulvic acid by molecular oxygen either in the absence of microorganisms or as a supplement to microbial activity.  相似文献   

钾霞石制备体系碱性滤液的利用技术     

路华龙  霍光祥  段永华  勾明雷  刘军娜  刘晨 《岩石矿物学杂志》2024,43(1):125-130

为处理钾长石水热制备钾霞石所产生的碱性滤液,本文采用水热法,考察了氢氧化铝溶解时间、晶化时间、晶化温度、水碱比对钾霞石产率和白度的影响,并对合成钾霞石物相进行了表征。结果表明,合成钾霞石的最佳条件为,氢氧化铝溶解时间为1.5 h,晶化时间为4 h,晶化温度280℃,水碱比为1.8。XRD结果表明,产物为钾霞石粉体。傅里叶变换红外光谱表明,Al(OH)₃中的Al在水热条件下进入到Si—O骨架中形成了Si—O—Al官能团,从而印证了钾霞石的合成。差热分析结果表明,合成钾霞石具有良好的热稳定性。氮气吸附结果表明,合成钾霞石比表面积为5.18 m²/g,平均孔径为32.98 nm。实现了钾长石水热制备钾霞石所剩碱性滤液的资源化利用,并为钾长石水热制备钾霞石提供了一种母液循环的思路,使水热制备钾霞石工业化成为一种可能。  相似文献   

A multivariate statistical and geostatistical study on the geochemistry of allochtonous karst bauxite deposits in Hungary     

Bárdossy  George  Kovács  Ó. 《Natural Resources Research》1995,4(2):138-153

A geochemical evaluation of the Szc-Halimba-Kisld area, Hungary, covering an area of more than 200 km² is presented using different statistical and geostatistical methods. The study area is a representative example of allochtonous karst bauxite accumulation. The three groups of deposits studied here have been explored and mined since 1950. Several thousand boreholes have been drilled, and bauxite cores were analyzed for the five main chemical components. A total of 80,000 pleces of analytical data were processed, followed by a geological examination of borehole logs and of mining excavations.The quantitative geochemical evaluation of the data set led to both geochemical and practical results: The geochemical behavior of the allochtonous, clastic karst bauxite deposits differs essentially from that of the autochtonous and parautochtonous ones, as well as that of the lateritic bauxite deposits. The deposits of the study area can be split into several subsequent geochemical-sedimentological units, each representing an event of bauxite transport and accumulation. Clear regional patterns can be revealed in the composition of these units. The geostatistically measured chemical variability of the geochemical units is rather different, the lowest units showing the smallest variability. The interrelations of the main chemical components are weaker and more irregular in the studied deposits than in the autochtonous lateritic bauxite deposits. Additional local genetic features, such as transport routes, can be delineated by the methods applied. Within each deposit, local changes of chemical composition and of its variability can be determined more precisely. These results can be used in bauxite prospecting and exploration, because areas of high or low bauxite quality can be predicted.  相似文献   

Speciation of adsorbed arsenate on the surface of hydrous iron oxide     

Yongfeng JIA Xin WANG George Demopoulos 《中国地球化学学报》2006,25(B08):35-35

Adsorption of arsenate on hydrous iron oxide is an important process controlling geochemical cycling of arsenic in environment as well as the fate of arsenic-bearing mining wastes. The widely accepted view on the mechanism of adsorption is that arsenate is adsorbed via bidentate binuclear inner-sphere complexation. In this study, we characterized the arsenate-hydrous iron oxide sorption solids synthesized at pH=3-8 using Fourier transformed infrared spectroscopy （FTIR） and X-ray diffraction （XRD）. It has been determined that poorly crystalline ferric arsenate developed on the surface of iron oxide when arsenate was sorbed at acidic pH, while at alkaline pH the adsorption of arsenate was via bidentate complexation.  相似文献   

Brick tea and its health impact     

Hairong LI Qinbin LIU Wuyi WANG Xuehui LIU Hailong LI Shuhai LI Xiaoyu ZHAO Lizhen WANG 《中国地球化学学报》2006,25(B08):73-74

Tea bush is one of the plants cultivated in acidic soil, and is a typical hyper-accumulator of F and Al. Brick tea is a kind of brick-formed tea compressed using the older and coarse leaves and branches of tea trees. Brick tea mixed with milk is drunk as a daily indispensable beverage for Mongols, Ewenki, and other minority nationalities in the pastoral and semi-pastoral areas of Northwest China. It is reported that drinking brick tea can result in dental and skeletal fluorosis due to the high F content in it. Because Alzheimer＇s disease （AD） is related with Al in human brain, and Al has potential toxicities for skeletal and neural systems,  相似文献