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1.
Chris Yakymchuk Adrian Rehm Zhuoheng Liao John M. Cottle 《Journal of Metamorphic Geology》2019,37(6):839-862
Sapphirine–quartz granulites from the Cocachacra region of the Arequipa Massif in southern Peru record early Neoproterozoic ultrahigh‐temperature metamorphism. Phase equilibrium modelling and zircon petrochronology are used to quantify timing and pressure–temperature (P–T) conditions of metamorphism. Modelling of three magnetite‐bearing sapphirine–quartz samples indicates peak temperatures of >950°C at ~0.7 GPa and a clockwise P–T evolution. Elevated concentrations of Al in orthopyroxene are also consistent with ultrahigh‐temperature conditions. Neoblastic zircon records ages of c. 1.0–0.9 Ga that are interpreted to record protracted ultrahigh‐temperature metamorphism. Th/U ratios of zircon of up to 100 reflect U‐depleted whole‐rock compositions. Concentrations of heavy rare earth elements in zircon do not show systematic trends with U–Pb age but do correlate with variable whole‐rock compositions. Very large positive Ce anomalies in zircon from two samples probably relate to strongly oxidizing conditions during neoblastic zircon crystallization. Low concentrations of Ti‐in‐zircon (<10 ppm) are interpreted to result from reduced titania activities due to the strongly oxidized nature of the granulites and the sequestration of titanium‐rich minerals away from the reaction volume. Whole‐rock compositions and oxidation state have a strong influence on the trace element composition of metamorphic zircon, which has implications for interpreting the geological significance of ages retrieved from zircon in oxidized metamorphic rocks. 相似文献
2.
Vertical measurements of , and N2O concentrations, and uptake, and oxidation rates were measured at 5 sites in western Cook Strait, New Zealand, between 31 March and 3 April 1983. Nitrate increased with depth at all stations reaching a maximum of 10.5 μg-atom at the most strongly stratified station whereas was relatively constant with depth at all stations (~0.1 μg-atom ). The highest rates of oxidation generally occurred in the near surface waters and decreased with depth. N2O levels were near saturation with respect to the air above the sea surface and showed no obvious changes during 24 h incubation. oxidation by nitrifying bacteria may account for about 30% of the total utilization (i.e. bacterial+agal) and, assuming oxidation through to , may supply about 40% of the algal requirements of in the study area. These results suggest that bacterial nitrification is of potential importance to the nitrogen dynamics of the western Cook Strait, particularly with respect to the nitrogen demands of the phytoplankton. 相似文献
3.
Manoj K. Pandit Helga de Wall Narendra K. Chauhan 《Journal of Earth System Science》2008,117(3):201-209
A number of fine-grained sericite bearing pelitic, schistose lithologies occur along the Archean (Banded Gneiss Complex)-Proterozoic
(Aravalli Supergroup) contact (APC) in the Udaipur valley in NW Indian craton. These Al-rich lithologies (subsequently metamorphosed)
have been described as ‘paleosols’, developed over a 3.3 Ga old Archean gneissic basement and are overlain by Paleoproterozoic
Aravalli quartzite. The paleosol was developed between 2.5 and 2.1, coincident with the globally recognized Great Oxidation
Event (GOE). In previous studies these paleosol sections were interpreted to have developed under reducing environment, however,
the finding of a ‘ferricrete’ zone in the upper part of Tulsi Namla section (east of Udaipur) during the present study (in
addition to earlier reported lithologies) has led to an alternative suggestion of oxygen-rich conditions during paleosol development.
The Tulsi Namla paleosol section shows all the features characteristic of a complete paleosol section described from other
Archean cratons. The paleosol includes sericite schist with kyanite as the prevalent Al-silicate in the lower part of profile
while chloritoid and Fe-oxides typify the Fe-rich upper part. Alumina has remained immobile during the weathering process
while Fe and Mn show a decrease in the lower part of the section and an abrupt rise in the upper part, in the ferricrete zone.
The field and geochemical data indicate that the Tulsi Namla section is an in situ weathering profile and at least the upper part shows evidence of oxidizing conditions. 相似文献
4.
Correlations between heavy metals and organic carbon extracted by dry oxidation procedure in urban roadside soils 总被引:1,自引:0,他引:1
Xue Song Wang 《Environmental Geology》2008,54(2):269-273
The organic fraction in soils has a significant influence on heavy metal transport. In this study, the organic carbon content
was measured by dry oxidation procedure from 21 Xuzhou urban roadside soils to assess the relationships between the concentrations
of heavy metals (Pb, Cu, Zn, and Cr) and the amount of organic carbon. The anthropogenic heavy metals (e.g. Pb, Cu, Zn) were
strongly correlated with organic carbon (denoted by Corg−c) extracted by dry oxidation while natural heavy metal (e.g. Cr) showed no correlation to the Corg−c. The anthropogenic heavy metals were also strongly correlated with the amount of the total carbon. These results show that
the anthropogenic heavy metals are mainly enriched in the organic matter in the Xuzhou urban roadside soils. 相似文献
5.
绿片岩-低角闪岩相变质条件下磁铁铁矿与黄铁矿间的Fe同位素分馏 总被引:3,自引:0,他引:3
对辽宁省鞍山一本溪地区经历了绿片岩一低角闪岩相变质的新太古代条带状铁建造中磁铁矿和黄铁矿矿物对的Fe同位素分析结果显示:相对于标准IRMM-014,所有样品的磁铁矿和黄铁矿均显示Fe的重同位素富集;且黄铁矿的Fe同位素比值均大于磁铁矿的Fe同位素比值(ε57Fe黄铁矿ε57Fe磁铁矿),两种矿物的Fe同位素比值之差为△57Fe黄铁矿-磁铁矿=2.23~5.13.黄铁矿富集铁的重同位素表明矿物的Fe同位素组成并不代表其原始沉积的特征,而是在区域变质作用过程中Fe同位素发生了交换的结果.由同位素平衡判别图解可知,在绿片岩一低角闪岩相变质作用中,磁铁矿-黄铁矿间的Fe同位素基本达到了平衡,且在平衡条件下黄铁矿比磁铁矿更富集Fe的重同位素,二者之间的Fe同位素平衡分馏系数α黄铁矿-磁铁矿≈1.000 4‰±0.06‰(2σ).这一研究成果是对变质作用过程中Fe同位素的地球化学行为认识的重要进展. 相似文献
6.
Organic matter origin and distribution in suspended particulate materials and surficial sediments from the western Adriatic Sea (Italy) 总被引:5,自引:2,他引:5
T. Tesi S. Miserocchi M.A. Goi L. Langone A. Boldrin M. Turchetto 《Estuarine, Coastal and Shelf Science》2007,73(3-4):431-446
In this study, organic carbon (OC), total nitrogen (TN), stable carbon isotopic (δ13COC) and CuO reaction product compositions were used to identify the sources of organic matter (OM) and to quantify the relative importance of allochthonous and autochthonous contributions to the western Adriatic Sea, Italy. Suspended particulate material (195 samples) and surficial sediments (0–1 cm, 70 samples) from shallow cross-shelf transects were collected in February and May 2003, respectively. Vertical water column profiles were acquired along the same transects. Data include depth, potential temperature, salinity, density and chlorophyll fluorimetry.Along the western Adriatic shelf in the near-shore region, the phytoplankton growth was influenced by dynamics of the buoyant plumes from the Po and Appennine rivers. A small amount of very fine terrigenous material remained suspended within the coastal current and was exported southward along the shelf to the slope. High variability in the bulk composition was detected in the Po prodelta surficial sediments, whereas the western Adriatic shelf, although a larger area, exhibited a narrower range of values.A significant decoupling was observed between suspended particles in the water column and surficial deposits. The organic material collected in the water column was compositionally heterogeneous, with contributions from marine phytoplankton, riverine–estuarine phytoplankton and soil-derived OM. Frequent physical reworking of surficial sediments likely leads to the efficient oxidation of marine OC, resulting in the observed accumulation and preservation of refractory soil-derived OC delivered by the Po and Appennine rivers. 相似文献
7.
The products of 35S-sulphate reduction by sedimentary bacteria were measured at two sites in a salt marsh on the east coast of England. Non-acid-volatile products were measured, after acid-volatile sulphide was removed, by their reduction to sulphide by digestion with tin. The proportion of the sulphate reduced to tin-reducible products varied between 25% in a salt marsh pan and 61% in creek sediment, over a 0–25 cm depth profile. There were also variations with depth at each site in the proportions of sulphate reduced to tin-reducible products. Further examination revealed differences in the proportions of sulphate which were reduced to free sulphide, acid-volatile sulphide, sulphur or pyrite at the two sites. The data suggest that previous work which did not measure non-acid-volatile products underestimated sulphate reduction rates by three-fold in the creek site, but by only one third in the pan. 相似文献
8.
9.
10.
在氧化沉淀法去除铁的过程中,氧化反应分别在自然曝气、充气和除钙的条件下进行,对照结果进行分析,得出最佳的除铁配方,同时还着重对氧化反应速率及其影响因素(pH,Eh等)进行了探索性研究,为以后试验提供了一定的依据。 相似文献