氢化物发生-原子荧光光谱法直接测定地球化学样品中痕量碲   总被引：2，自引：1，他引：1  

林光西 《岩矿测试》2008,27(2):151-152

采用硝酸-氢氟酸-高氯酸溶解样品,以Fe3+作减缓剂,不需分离富集,用氢化物发生-原子荧光光谱法直接测定地球化学样品中痕量碲。对测定介质、KBH4浓度、铁盐的作用等条件进行试验。方法检出限为0.0031μg/g,精密度(RSD,n=11)<6.10%。方法用于国家一级地球化学标准物质中痕量碲的测定,结果与标准值一致。  相似文献   

碱消解-高效液相色谱-电感耦合等离子体质谱法测定生物样品中的甲基汞和乙基汞   总被引：7，自引：2，他引：5  

杨红霞  刘崴  李冰 《岩矿测试》2008,27(6):405-408

建立了碱消解-高效液相色谱-电感耦合等离子体质谱联用系统测定生物样品中甲基汞(MeHg)与乙基汞(EtHg)的分析方法。为提高灵敏度,选用微流量的PFA雾化器,在优化的检测条件下,MeHg及EtHg检出限可达到0.036μg/L和0.03μg/L;线性范围达到4个数量级,两条工作曲线线性相关系数为1。对1.78μg/L MeHg、1.65μg/L EtHg的混合标准溶液重复测定7次,色谱峰面积的相对标准偏差(RSD)分别为1.79%和1.44%。对标准物质BCR 464(金枪鱼)的分析结果表明,测定值与标准值基本吻合,但略低于标准值;甲基汞和乙基汞的加标回收率分别为85.9%和84.5%。高效液相色谱与质谱联用技术的高灵敏度和低检出限能够满足生物样品中汞形态定量分析的要求。  相似文献   

橄榄岩—熔体相互作用过程中Re-Os体系的变化趋势: 对华北新生代地幔橄榄岩Re-Os年龄含义的启示   总被引：1，自引：0，他引：1  

张宏福 《岩石学报》2008,24(11):2457-2467

橄榄岩的Re-Os同位素体系作为探讨岩石圈地幔形成年龄的重要手段已受到人们越来越多的重视。然而,Re-Os体系是否会受到橄榄岩的低温蚀变如蛇纹石化和地幔交代作用或橄榄岩—熔体相互作用的影响并不十分清楚。本文在总结国际上典型造山带橄榄岩剖面研究和地幔橄榄岩捕虏体研究的基础上,发现橄榄岩的Re-Os同位素体系基本不受蛇纹石化等低温蚀变作用的影响; 但橄榄岩—熔体相互作用会造成橄榄岩的Re-Os体系的变化即Re或Os的带入。当熔体/岩石比例较小时(≤1),橄榄岩—熔体相互作用会造成橄榄岩的Re含量显著增加,而放射成因的Os同位素即¹⁸⁷Os增量有限。但当熔体/岩石比例很大时(≥1),会造成¹⁸⁷Os同位素显著增加。同时,橄榄岩的Re含量与中等程度不相容主、微量元素如Al、Ti、Yb的正相关关系可以通过橄榄岩的两阶段演化模式来解释,即早期的部分熔融残留和后期的橄榄岩—熔体相互作用共同影响的结果。橄榄岩的Re含量与Cr含量的正相关关系进一步说明了这一问题。上述结果对华北东部岩石圈地幔的演化过程有重要的启示作用。因为华北东部古生代时期的确存在太古宙岩石圈地幔,然而新生代时期地幔橄榄岩捕虏体普遍具有元古宙而非太古宙的事实证明橄榄岩—熔体的相互作用的确广泛存在,从而造成岩石圈地幔橄榄岩变年轻。因此,新生代地幔捕虏体的Re-Os同位素年龄并不是岩石圈地幔的形成年龄,而是混合作用的结果。汉诺坝地幔橄榄岩的Re含量和Sr、Nd同位素组成符合橄榄岩—多元熔体相互作用的混合趋势,其橄榄岩的全岩Al₂O₃含量和橄榄石Fo的反相关性能够通过橄榄岩—熔体相互作用来解释。  相似文献   

Wave Loads and Protective Techniques of An On-Shore Wave Power Device     

You Yage YuZhi Associated Professor  Guangzhou Institute of Energy Conversion  Chinese Academy of Sciences  Guangzhou . Professor  Guangzhou Institute of Energy Conversion  Chinese Academy of Sciences  Guangzhou 《中国海洋工程》1995,(4)

In this paper, the extreme wave loads on an on-shore wave power device are investigated. First, boundary element method is applied to solve the three dimensional potential problem based on the small amplitude wave assumption. Then the motion of the Oscillating Water Column (OWC) inside the device and its laods on the device are calculated in time domain. Several protective techniques often applied are simulated by changing the constraint of the upper end of the chamber of the device. Numerical results are used to judge the effectiveness of these techniques. The investigation shows that damping can not effectively restrain the motion of OWC when the period of incident wave is long, which may cause dangerous loads on the structure. The shut chamber can effectively restrain the motion of OWC, but alternatively cause high pressure in the chamber. A Contracting opening with a Taper (CT) can exhaust a great amount of kinetic energy of OWC, and significantly decrease the loads. It is a promising protective tec  相似文献   

A community-wide intercomparison exercise for the determination of dissolved iron in seawater     

Andrew R. Bowie  Eric P. Achterberg  Peter L. Croot  Hein J.W. de Baar  Patrick Laan  James W. Moffett  Simon Ussher  Paul J. Worsfold 《Marine Chemistry》2006

The first large-scale international intercomparison of analytical methods for the determination of dissolved iron in seawater was carried out between October 2000 and December 2002. The exercise was conducted as a rigorously “blind” comparison of 7 analytical techniques by 24 international laboratories. The comparison was based on a large volume (700 L), filtered surface seawater sample collected from the South Atlantic Ocean (the “IRONAGES” sample), which was acidified, mixed and bottled at sea. Two 1-L sample bottles were sent to each participant. Integrity and blindness were achieved by having the experiment designed and carried out by a small team, and overseen by an independent data manager. Storage, homogeneity and time-series stability experiments conducted over 2.5 years showed that inter-bottle variability of the IRONAGES sample was good (< 7%), although there was a decrease in iron concentration in the bottles over time (0.8–0.5 nM) before a stable value was observed. This raises questions over the suitability of sample acidification and storage.  相似文献   

Kohonen网络与BP网络的集成应用研究     

丁香乾  曹均阔  贺英 《中国海洋大学学报(自然科学版)》2003,33(4):615-620

本文介绍了 Kohonen神经网络对输入数据进行聚类方法在卷烟配方中的应用 ,提出了从核心样本动态搜索 BP网络训练样本的新探索 ,摒弃了过去 BP算法中训练样本固定不变 ,互不相交的方法 ,实现了 BP网络和 Kohonen网络动态无缝集成。  相似文献   

Sample Disturbance in Soft and Sensitive Clays: Analysis and Assessment     

K. Nagendra Prasad  S. Triveni  T. Schanz  Late T. S. Nagaraj 《Marine Georesources & Geotechnology》2007,25(3):181-197

Despite the sophisticated methods employed to obtain high quality samples, they are prone to disturbance, due to stress release, let apart, due to sampling tools and techniques adopted. Critical reappraisal of different methods suggest that any method of sample quality assessment involving strength and deformation parameters would enable easier implementation and correct other engineering parameters for estimated sample disturbance. In this technical paper, sample disturbance index, using merely the slopes of compression paths, (representing mechanical response), in the pre- and post-yield stress regimes under odeometric loading conditions is proposed. This method is based on single oedometer test results on samples of unknown degrees of disturbance during sampling and handling. The unique feature of this approach is that the ideal rigid plastic material behavior is taken as reference. This eliminates the need for any additional experimental data or any calculations from the relationships formulated with any set of assumptions.  相似文献   

海桑属红树植物遗传多样性和引种关系研究   总被引：8，自引：2，他引：8  

周涵韬  林鹏 《海洋学报》2002,24(5):98-106

以海南东寨港红树林自然保护区内无瓣海桑(Sonneratia apetala)、海南海桑(S.hainanensis)、拟海桑(S.paracaseolaris)、杯萼海桑(S.abla)、大叶海桑(S.ovata)、海桑(S.caseolaris)等6种海桑属红树植物为材料,对15个有效引物进行RAPD分析,共扩增出512条带,其中多态性条带为297,占总扩增条带的58.01%.Nei指数法分析和UPGMA统计分析表明,6种海桑属红树植物分为A,B,C3个组,平均遗传距离为0.38.A组包括无瓣海桑、海南海桑、大叶海桑、怀萼海桑,其中无瓣海桑、海南海桑、大叶海桑处于同一个亚组.B组包括拟海桑.C组包括海桑.对海南和福建无瓣海桑种群进行RAPD分析.对Shannon表型多样性指数统计结果表明,福建种群为0.669,海南种群为0.671,各种群遗传变异较大,这与无瓣海桑种群广泛的适应性相一致.对种群间的Shannon表型多样性指数分析表明,种群内的遗传变异占整个遗传变异的93.3%,而种群间的遗传变异仅占6.7%.这表明无瓣海桑种群的大部分遗传变异存在于种群内,而种群间的遗传变异较小.由此可见,无瓣海桑基因组丰富的多样性,是使其由海南成功引种到福建的重要因素.  相似文献   

离子色谱分析在黄土和粉尘研究中的应用   总被引：1，自引：0，他引：1  

王丹  屈文军  张小曳  严立文  曹国良 《海洋地质与第四纪地质》2005,25(1):113-118

黄土中存在着大量的碱金属及碱土金属，以往的测试方法多为原子吸收和ICP—MS，离子色谱法在测试黄土样品的碱金属和碱土金属元素含量中应用不多。将黄土地质标准样品进行消解后用离子色谱进行测试，测试效果良好，重复测试的相对标准偏差小于5％，与推荐值的相对误差小于5％，准确度和精密度符舍相关的质量控制要求。本实验方法测试的离子含量都在仪器响应呈线性的最佳测试范围之内，标准曲线经回归后相关系数均达到0．9999。黄土样品的分析结果与粉尘气溶胶样品的离子分析结果对比表明，此方法对于探讨粉尘起源以及沙尘暴天气的研究具有重要意义。  相似文献   

Optimum Sample Size to Detect Perturbation Effects: The Importance of Statistical Power Analysis – A Critique     

Marco Ortiz 《Marine Ecology》2002,23(1):1-9

Abstract. The current article describes statistical power analysis as an efficient strategy for the estimation of the optimum sample size. The principle aim is constructively to criticise and enrich the results presented by Mouillot et al. (1999) , who estimate the optimum sample size for evaluating possible perturbations. The authors did not make any reference to statistical power analysis, even though their objective clearly went beyond a simple stock evaluation to assess management strategies in a particular marine ecosystem. Surprisingly, they proposed (a priori) an ANOVA design to test a hypothesis considering both space and temporal scales. However, the authors did not cover important topics related with power analysis and the precautionary principle, both used into environment impact assessment programmes for marine ecosystems. Based on their results and on statistical power analysis, it is demonstrated that the variability (dispersion statistics), a key factor they used to estimate the sample size, is less relevant than the magnitude of perturbation (effect size). Therefore, a greater effort must be devoted to estimate the effect size of a particular phenomenon rather than a desired variability.  相似文献