Sediment–water interactions of natural oestrogens under estuarine conditions     

J. C. Bowman  J. L. Zhou  J. W. Readman 《Marine Chemistry》2002,77(4)

The natural human female hormones oestrone and 17β-oestradiol have been implicated in the disruption of endocrine systems in some wildlife adjacent to sewage effluents. The sorption behaviour of these two compounds under estuarine conditions was studied by spiking either 2.55 μg of oestrone or 2.65 μg of 17β-oestradiol in kinetic experiments. In equilibrium experiments, 3 ng of oestrone or 3.2 ng of 17β-oestradiol was added in each of the centrifuge tubes. Sorption onto sediment particles was relatively slow, with sorption equilibrium being reached in about 70 and 170 h for oestrone and 17β-oestradiol, respectively. The effects of a variety of environmental parameters on sorption were studied including salinity, sediment concentration (SC), the presence of a third phase, particle size and, also, surfactant concentrations. Results show that although salinity did not induce any statistically significant effect on the sorption of 17β-oestradiol, it did statistically enhance the sorption of oestrone, and a salting constant of 0.3 l mol⁻¹ was derived. The partition coefficient for both compounds decreased with increasing sediment concentration, a phenomenon that has been widely reported and attributed to the presence of colloids (which could enhance dissolved concentrations). In this paper, the true partition coefficients for sediment particles (K_p^true) and colloidal particles (K_c^true) have been calculated, and a K_p^true value of 141 and 102 ml g⁻¹ was obtained for oestrone and 17β-oestradiol, respectively. In addition, K_c^true values for oestrone (222×10² ml g⁻¹) and 17β-oestradiol (135×10² ml g⁻¹) were two orders of magnitude higher than their respective K_p^true values, suggesting that the colloidal particles are significantly stronger sorbents for natural oestrogens than sediment particles. Particles of different sizes were found to have different partition coefficients due to the strong relationships between partition coefficients for the two compounds and particulate organic carbon (POC) contents and specific surface areas (SSAs). The presence of a surfactant was shown to reduce the partition coefficients for the two compounds, although its concentrations being used were higher than those normally found in the natural environment.  相似文献   

胃肠酸度下中药及补铁制剂中铁活性的影响研究     

刘淑娟  王达成  杨沁羽 《华东地质学院学报》2006,29(2):159-163

在人体胃肠液的酸度条件下,采用正辛醇-水分配体系模拟药物在人体肠胃中的分配情况,研究了中药和补铁制剂中铁的形态及其在人体内的吸收情况,并探讨了中药不同比例的配伍、胃肠酸度及还原性物质的存在对水溶态铁和醇溶态铁的影响。结果表明,药物溶液中的铁形态与药物本身特性和配伍情况有关,酸度及配伍对药物中铁的溶出率和溶液中铁的形态有较大影响,人体对铁的吸收与胃肠酸度和还原性物质的存在有关。  相似文献   

碲的泡塑预分离M17树脂富集原子荧光测定法   总被引：7，自引：0，他引：7  

杨理勤 《黄金地质》1997,3(1):67-71

采用王水溶样，泡沫塑料预分离金等干扰组分，以Ｍ１７树脂富集Ｔｅ并使之与大部分共存的干扰元素分离，建立了原子荧光含金地质样品中碲的方法，用地矿部标准参考样品和含金地质试样分析考察，结果满意。方法检测下限为０．００９×１０＾－６。  相似文献   

中国省域尺度17部门资本存量的时空特征分析     

刘丽  李宁  张正涛  冯介玲  陈曦  白扣  黄承芳 《地理科学进展》2019,38(4):546-555

随着灾害强度、频率以及承灾体暴露的增加,自然灾害造成的损失日益严重。资本存量作为承灾体的经济暴露指标之一,是灾害损失评估的前提和基础。针对目前中国缺乏省域尺度长时间序列的经济部门分类的资本存量数据基础,论文通过永续盘存法,建立了2003—2015年中国大陆31省17部门的资本存量数据库,并分析其时空特征。结果显示：① 全国总资本存量与灾害直接损失的年际变化均呈增加趋势。省域尺度上,通过相关性分析显示,在99%置信度水平上,两者呈显著正相关(r=0.3)。② 时间上,各省17部门资本存量基本也呈增加趋势,但增速不同。在各部门增速最快的省份中,黑龙江省的居民服务、修理和其他服务业增速最快,增长约454.3倍;其次是青海省的租赁和商务服务业(398.3倍)、江苏省的金融业(295.1倍)、安徽省的科学研究和技术服务业(125.1倍)等。③ 空间上,2015年各省17部门资本存量最多的前4个部门分别是房地产业,工业,交通运输、仓储和邮政业,水利、环境和公共设施管理业,占比均在60%以上;且这4个部门资本存量暴露最多的省份是江苏省和广东省。该结果有助于从时空角度了解各省各部门资本存量暴露情况,为各省灾害风险管理者的防灾减灾工作提供重要的参考价值。  相似文献   

程序化设计的简并引物克隆半滑舌鳎CYP17基因   总被引：7，自引：0，他引：7  

陈彩芳  温海深  何峰  董双林 《中国海洋大学学报(自然科学版)》2009,39(6)

采用1种新的简并引物设计方法--CODEHOP法来克隆半滑舌鳎CYP17基因.该法结合NCBI、Blastp、BlockMaker、CODEHOP等生物信息学资源和DNAMAN、Oligo6.0等生物软件,程序性设计半滑舌鳎CYP17基因的CODEHOP引物,从半滑舌鳎卵巢组织中成功克隆了CYP17基因,该基因片段与其它物种的CYP17家族具有较高的同源性,经鉴定,该基因属于整个脊椎动物的CYP17基因群,尤其是鱼类亚群.实验结果表明,程序性设计的简并引物较传统简并引物特异性更高,假阳性率少,更有利于实验成功.  相似文献   

大黄鱼白细胞介素17受体E-like的分子特征及进化分析          下载免费PDF全文

丁扬  敖敬群  艾春香  陈新华 《应用海洋学学报》2016,35(1):107-115

白细胞介素17受体(Interleukin 17 receptor,IL-17R)家族与IL-17细胞因子家族介导的各类反应有着密切联系.IL-17RE-like(IL-17REL)是一类最新发现的IL-17受体,其结构与IL-17RE相似,但尚未发现其配体.本研究克隆得到大黄鱼(Larimichthys crocea)IL-17REL(Lyc IL-17REL)的全长c DNA,其开放阅读框全长1 659个核苷酸,推断可编码一个由552个氨基酸组成的蛋白,含有信号肽、胞外段、跨膜区和胞内段.与其他物种的IL-17REL相似,Lyc IL-17REL蛋白的胞外段具有一个保守的FN I-like结构域,而胞内段缺少IL-17受体家族保守的SEFIR(SEF and IL-17R)结构域.多序列比对分析表明Lyc IL-17REL与日本河豚(Takifugu rubripes)IL-17REL的氨基酸序列同源性最高,序列一致性可达57.0%.系统进化分析表明,脊椎动物的IL-17受体家族可分为2类,IL-17RA/RB/RD为一类,IL-17RC/RE/REL为一类.其中鱼类及高等脊椎动物的IL-17REL与IL-17RE亲缘关系最近,并且推测二者可能是由同一基因从硬骨鱼类之前的物种中分化而来.组织分布表明Lyc IL-17REL在所有被检测的组织中为组成型表达,在黏膜相关组织如小肠和鳃中的表达量最高.大黄鱼受嗜水气单胞菌(Aeromonas hydrophila)诱导刺激后,Lyc IL-17REL在其头肾及鳃中的基因转录水平均显著上调.这表明Lyc IL-17REL可能在细菌感染引起的免疫反应中起着重要作用.  相似文献   

Soldier crab (Dotilla myctiroides) distribution,food resources and subsequent role in organic matter fate in Ao Tang Khen,Phuket, Thailand     

Kimberly K. Takagi  Phaothep Cherdsukjai  Izumi Mimura  Yuka Yano  Kanjana Adulyanukosol  Makoto Tsuchiya 《Estuarine, Coastal and Shelf Science》2010

This study aimed to elucidate Dotilla myctiroides (H. Milne-Edwards) food resources and how the soldier crab influences the organic matter composition on the intertidal flat. A preliminary assessment of D. myctiroides size, sex, and population distribution was conducted to clarify the characteristics of the inhabiting population. Overall, D. myctiroides size and abundance was normal across the tidal flat area. Comparison of different sediment types from the soldier crab habitat (surface sediments, igloos, burrow lining, burrow pellets, feeding pellets, and feces) using the fatty acid (FA) analysis technique revealed D. myctiroides removes organic matter via the significantly lower contributions of polyunsaturated FAs, essential FAs, and dinoflagellates in the feeding pellets. Dotilla myctiroides tissue analysis of the hepatopancreas and hindgut in individuals that had been starved for 24 h confirmed not only the consumption of dinoflagellates, but diatoms and macroalgae as well. In addition, the FA metabolism within the digestive system implied the ability of the soldier crab to synthesize highly unsaturated FAs (HUFAs) such as 20:4n–6, 20:5n–3 and 22:6n–3.  相似文献   

M17树脂对岩石中痕量硒碲的分离富集研究及应用     

林猷璧  朱玉伦 《岩矿测试》1993,12(2):81-84

M_(17)树脂在>6mol/L的HCl介质中能同时吸附Se和Te,Se和Te可用水和丙酮分别洗脱,也可用丙酮同时洗脱。从而建立了两个新的Se、Te分离富集体系,使原子荧光测定达到纳克量级。  相似文献   

M17树脂分离富集原子荧光测定岩矿中痕量碲   总被引：4，自引：1，他引：4  

林猷璧  朱玉伦 《岩矿测试》1991,10(4):283-286

本文研究了不同种类树脂对Te的吸附能力,提出了在3mol/L HCl介质中,用M_(17)二甲胺树脂吸附,然后用水洗脱的新途径,使Te有效且无污染地得到分离和富集,实现了原子荧光测定地质试样中ppb级痕量Te。经地矿部标准参考样GSR7-12考察,分析结果与推荐值相符。  相似文献   

Preparation and After-Treatment of BaMgAl10 O17 ：Mn^2＋     

王永钱  张锦华宋羽 袁曦明 《中国地质大学学报(英文版)》2006,17(3):272-275

INTRODUCTION The properties of phosphor usedin a plasma dis-play panel (PDP) affect the performance of the PDP(Okazaki et al .,2000 ; Rao and Devine ,2000) . Theluminescent properties of the phosphor are decided bythe morphology ,particle size and size distribution ofthe powder ,sothe requirements for the powder mor-phology are high in a color PDP which belongs to ahigh resolution display apparatus (I m et al .,2005 ;Yang et al ., 2005) . Studies have shown that withsmall particle si…  相似文献