闽南近海常见鲨鳐类肝油的四种理化常数和角鲨烯含量   总被引：8，自引：0，他引：8  

刘晓春  丘书院 《台湾海峡》1997,16(4):468-472

本文分析测定了闽南近海常见鲨鳐类肝油的理化常数和角鲨烯含量。尖头斜齿鲨肝油的碘值特别高，说明其中脂肪酸的不饱和程度很高；非皂化物含量很低，约占肝油重的38×10－3（m／m）；角鲨烯含量极微，在肝油中仅占84×10－5（m／m）。闽南近海常见鲨鳐类肝油的角鲨烯含量均很低，变化在（31～116）×10－5（m／m）之间。在相同的气相色谱条件下，小孔沙条鲨和狭纹虎鲨肝油中没有检测到角鲨烯。  相似文献   

无机碳与雨生红球藻(Haematococcus pluvialis)细胞调节物质   总被引：4，自引：0，他引：4  

刘建国  孙艳妮  殷明焱  刘伟  张展 《海洋与湖沼》2004,35(5):459-466

以单细胞雨生红球藻为材料，采用酸碱滴定和CO2加富通气培养微藻的方法，对旧液中HCO3^-和CO3^2-浓度变化以及对红球藻细胞生长的影响进行了研究。结果表明，旧液具有限制红球藻细胞生长和诱导细胞转化的作用。同时，旧液中无机碳离子浓度明显高于新液。培养液中富含CO3^2-时，各细胞数量与CO3^2-浓度呈正相关，相关系数为0．88。溶液中仅有HCO3^-时，各细胞数与HCO3^-浓度也呈正相关性。因此，排除了CO3^2-和HCO3^-作为旧液中的调节物质，限制红球藻细胞生长和诱导细胞转化的可能性。旧液乙酸乙酯提取物生物检测实验表明，在粗提取物中有降低细胞增长和诱导细胞转化的活性，表明调节物质能溶于有机相，也反过来证实无机碳离子不是旧液中的调节物质。DNA含量和倍性分析结果表明，红球藻游动细胞DNA复制可以加倍后不经过原生质分裂就可以再次进行，因此推测旧液中的调节物质对原生质分裂过程产生抑制作用，而不对DNA复制过程产生抑制作用。  相似文献   

Structural and nutritional heterogeneity of riparian vegetation in Patagonia (Argentina) in relation to seasonal grazing by sheep     

V.R. Utrilla  M.A. Brizuela  A.F. Cibils 《Journal of Arid Environments》2006,67(4):661-670

Riparian meadows of southern Patagonia are temporally and spatially heterogeneous habitats. They are thought to play a key role in regulating the dynamics of arid grazed steppes of the region. We conducted a 2-year study with sheep to determine the influence of two grazing conditions (deferment and spring grazing) on structural and nutritional parameters of three vegetation types apparently associated with a soil moisture gradient in a riparian meadow in southern Santa Cruz (Argentina). Spring deferment allowed forage accumulation in very moist and intermediate vegetation types by the beginning of the summer and had no detrimental impact on forage quality. Deferment had no effect on biomass accumulation of the drier vegetation type at our study site. Structural attributes of the vegetation appeared to affect spatial grazing patterns of sheep. Soil-related patchiness, rather than sheep grazing, appeared to control vegetation structure and nutritional value. The proportion of more mesic plant communities in riparian habitats of Patagonia could determine the outcome of plant–animal interactions in these systems. Practical recommendations of grazing capacity in paddocks, or more theoretical considerations of ecosystem dynamics of the Patagonian steppes need to explicitly consider the internal patchiness of riparian habitats.  相似文献   

原油在储层介质中的加水裂解生气模拟实验   总被引：5，自引：2，他引：5  

冯子辉  侯读杰等 《沉积学报》2002,20(3):505-509

采用高温高压热模拟实验方法,开展了原油在砂岩和火成岩储层介质中的加水裂解生气模拟实验研究.结果表明,原油开始大量裂解的温度是400℃,随模拟温度增加,甲烷相对含量增大,乙烷以上重烃气尤其是丙烷相对含量减小.其中砂岩的油水混合物裂解生气主要发生在450～500℃之间,生气窗范围小,对应的烃气产率高,火成岩的油水混合物裂解生气主要发生在450～600℃之间,生气窗范围大,对应的烃气产率小.模拟烃气的组分碳同位素分馏显著,随模拟温度增加呈变重趋势.在裂解生气过程中,水解加氢和催化作用对烃气的组成、产率和碳同位素分布有重要影响。  相似文献   

Unusual biomarker maturation ratio changes through the oil window, a consequence of varied thermal history     

Christopher P. N. Davies   《Organic Geochemistry》1997,27(7-8)

Saturated and aromatic biomarker ratios continue to change systematically through the oil window and into the gas-condensate window to high vitrinite reflectances (R_o = 1.16%) in mature marine and lacustrine Mesozoic clastic samples from a South African basin. Two of the ratios reverse above R_o = 0.9%. These unusual maturation effects result from isolated periods of high rates of maturation increase. The basin cooled regionally after the break-up of Gondwana but high heating rates prevailed during the late Cretaceous-early Tertiary, as Africa moved across a hotspot, and again in the late Tertiary as a result of a possible hotspot and hydrothermal event.  相似文献   

塔里木盆地油气资源的基本特征   总被引：3，自引：0，他引：3  

陈正辅 《海相油气地质》1997,2(1):15-20

塔里木盆地成油气地质历史条件复杂，盆地内海陆相油气、不同成藏期油气、不同成熟度以及不同保存条件的油气并存。具海相古生界及陆相中－新生界两大烃源岩系，前者以奥陶系和石炭系为最好源岩，后者以三叠系和侏罗系最佳。烃源对比结果比较全面地反映了这一特点。石炭系、三叠系、白垩系和中新统均为重要的储油层系，其储集岩类古生界主要为白云岩，次为石灰岩，中－新生界主要为砂岩。成藏类型可分为六种：古生古储、后生古储、后  相似文献   

基于五种油源的中重度风化溢油的常规鉴定指标的应用效果评估     

贺世杰  王传远  李延太  于洪军  韩彬 《海洋学报(英文版)》2016,35(4):1-8

本文利用采集于我国三大油田的五种原油样品开展了长达210天的溢油风化模拟实验,并依据相对偏差和重复性限数学分析法,进行溢油风化过程分析和诊断比值应用效果评估。研究结果表明:经过210天的风化,溢油鉴定诊断比值发生明显改变;其中来源于萜烷、甾烷和多环芳烃的诊断比值变化率要远低于正构烷烃,可用于中长期风化溢油鉴定。此外,研究发现,在这些有效诊断比值中有4个变化率较小,相对偏差低于5%,保持了较好的稳定性,更适合于重度风化溢油鉴定。  相似文献   

Effect of maturity on carbon isotope ratios of oils and condensates     

C.J. Clayton 《Organic Geochemistry》1991,17(6)

For modelling isotopic variations in oils it is convenient to differentiate the effects of oil generation ( 100–150°C) from the effects of oil to gas cracking ( 150–180°C). During generation, δ¹³C of kerogen may increase by up to 1% due to release of isotopically light oil and gas, although most kerogens show little or no chan δ¹³C of the generated oil increases by between 0 and 1% (av. 0.5%) due to mixing of isotopically heavy oil with an initial isotopically light unbound fraction, possibly of bacterial origin. The change occurs mostly over the first 20% of generation. During oil to gas cracking, kinetic isotope effects become important and the effect on δ¹³C of the remaining oil can be modelled as a Rayleigh process. δ¹³C increases by 1.5% by 50% cracking. Insufficient data are available to calibrate the effects at higher levels of cracking, and modelling these variations is hindered by a lack of understanding of the mechanism of pyrobitumen formation. However, increases greater than about 4% are unlikely to be observed. With increasing maturity, the low molecular weight fractions become isotopically heavy faster than the high molecular weight fractions. As a result, any separation of the low molecular weight fraction into a gas phase (“condensate formation”) will produce an isotopic difference between oil and condensate that depends on maturity. In the early stages of generation the condensate may be up to 1% lighter than the remaining oil. With increasing maturity, this difference at first decreases and then increases in the opposite sense. By half way through oil to gas cracking the condensate may be 1.5% heavier than the residual liquid. More subtle rearrangement reactions may result in small, but significant, changes to the shape of the isotope “type-curves” when different oil fractions are compared.  相似文献   

Petroleum isoprenoid hydrocarbons derived from catagenetic degradation of archaebacterial lipids     

J. Albaigés  J. Borbón  W. Walker 《Organic Geochemistry》1985,8(4):293-297

The three GC coeluting C₄₀ bis-phytanes with head-to-tail, tail-to-tail and head-to-head linkages considered to be archaebacterial markers, have been recognized in petroleum by enhanced mass-fragmentography. Supporting evidence has been obtained by the simultaneous occurrence of two C₂₁–C₂₄ series of isoprenoid and quasi-isoprenoid hydrocarbons that are supposedly formed during the catagenetic degradation of the isomeric C₄₀ isoprenoids. The C₂₁–C₂₄ quasi-isoprenoid hydrocarbons have been identified conclusively for the first time by comparison with authentic standards.  相似文献   

温度对复分解法制硝酸钾生产过程的影响          下载免费PDF全文

赵启文 《盐湖研究》2001,9(3):43-45

探讨以硝酸铵和氯化钾为原料、复分解法制硝酸钾工艺中 ,配料、硝酸钾结晶、氯化铵结晶等处操作温度对产量、质量、操作时间等的影响  相似文献