Levels and distribution of tris-(2,3-dibromopropyl) isocyanurate and hexabromocyclododecanes in surface sediments from the Yellow River Delta wetland of China     

Ling Wang  Mengyuan Zhang  Yinghua Lou  Runhui Ke  Minggang Zheng 《Marine pollution bulletin》2017,114(1):577-582

The levels and distribution of tris-(2,3-dibromopropyl) isocyanurate (TBC) and hexabromocyclododecanes (HBCDs) of surface sediments in the Yellow River Delta wetland had been investigated. The concentrations of TBC and ∑ HBCDs ranged from 0.20 to 29.03 ng·g^? 1 dw and below limits of detections (LODs) to 20.25 ng·g^? 1 dw. The average composition profile of three HBCDs isomers were 10.1%, 6.1% and 83.8% for α-, β- and γ-HBCD, respectively. Moreover, correlation analysis indicated there are similar sources among three isomers and positive correlations between total organic carbon (TOC) content and concentrations of TBC and HBCDs. The mass inventory of TBC,α-, β-, γ-HBCD, ΣHBCDs in surface sediments of Yellow River Delta wetland were estimated about 725.50, 72.76, 44.29, 548.34, 665.39 kg. Therefore, further investigations on potential human health and environmental risk assessments of TBC and HBCDs were needed.  相似文献   

六溴环十二烷环境研究进展          下载免费PDF全文

卜德志  孙霞  劳齐斌  矫立萍  陈立奇 《海洋开发与管理》2022,39(1):65-76

极地区域由于其独特的地理位置和自然条件,是对全球气候变化和环境污染响应和反馈最为敏感的区域之一,在全球气候变化和环境污染研究中占据重要地位。HBCDs作为一种新型持久性有机污染物,近几年受到国际社会的广泛关注。文章对HBCDs特性及近几年来极地、中低纬度区域HBCDs研究进行了综述,对比分析了环境中大气、水体、土壤、沉积物、植被和生物等多介质中HBCDs赋存水平,探讨了其异构体在多介质中的浓度分配差异,并对其可能原因给出解释,论证了HBCDs污染防治及其进一步环境行为研究对人类健康及生态环境安全的重要意义。  相似文献   

莱州湾河流表层沉积物中六溴环十二烷的含量水平、分布及组成特征   总被引：1，自引：0，他引：1  

刘艺凯  王景芝  唐建辉  于志强  张干 《地球化学》2014,(1):55-63

从莱州湾附近河流采集了36个表层沉积物样品,采用高效液相色谱耦合三重四极杆串联质谱的分析方法对沉积物中的六溴环十二烷（HBCDsl3种异构体进行了测定,目的是表征研究区域内HBCDs的污染水平和组成特征,并探讨其分布、来源及影响因素。结果表明,莱州湾河流沉积物中ZHBCDs的含量范围为0．03～20．17ng／gdw（均值是2．14ng／gdw）：较国内外其他河流,该研究区域HBCDs含量水平较低。HBCDs异构体组成各不相同,除1个站位外,其他站位样品中7-HBCD占主导地位（52．3％～97．3％,均值72．4％）,但是在农业区a-HBCD相对丰度较高。对HBCDs的分布特征及来源分析得出,含量较高的站点多集中在工业区,呈现出明显的点源特征：而远离工业区的采样点,HBCDs可能主要来自大气的传输和沉降,且HBCDs的含量与TOC含量呈现出较好的相关性,表明TOC是非工业区分布的一个控制因素。  相似文献   

环境中溴系阻燃剂六溴环十二烷的水平及分析进展   总被引：2，自引：0，他引：2  

焦杏春  路国慧  王晓春  杨永亮 《岩矿测试》2012,31(2):210-217

六溴环十二烷(HBCDs)是一种添加型溴系阻燃剂,被广泛应用于建筑隔热材料、纺织用品及少量电子产品中。2006年欧盟、国际公约等组织相继停止生产和使用多溴联苯醚后,HBCDs也曾在某些用途中作为替代品使用。在各环境介质中,空气和水体是HBCDs的主要释放空间。点源附近的环境介质中通常能够检测出较高浓度的HBCDs,远高于没有明显点源的地区。工业合成的HBCDs以γ-HBCD异构体为主,大多数生物体内的HBCDs以α-HBCD所占比例最大,可能与化合物结构、环境条件及生物代谢过程等均有关。气相色谱-质谱分析技术对HBCDs有较高的检测灵敏度,但由于HBCDs存在热重排、热降解等现象,使得化合物的异构体分析受限。液相色谱-质谱分析技术弥补了上述缺陷,不但可以区分HBCDs化合物的对映与非对映异构体结构,还可以借助串联质谱(MS/MS)联用技术降低化合物的检出限。文章综述了环境中HBCDs的水平及分析进展,认为在HBCDs的立体结构以及各异构体之间的转化过程和转化条件等方面有很大的探索空间,指出在环境背景区开展HBCDs的环境行为、演变趋势、控制措施及替代技术研究,是今后应该深入研究的领域。  相似文献   

Organohalogen contaminants in striped dolphins (Stenella coeruleoalba) from Japan: Present contamination status, body distribution and temporal trends (1978-2003)     

Tomohiko Isobe  Karri Ramu  Yuko Tajima  Masao Amano  Shin Takahashi 《Marine pollution bulletin》2009,58(3):396-401

Organohalogen contaminants including PCBs, DDTs, CHLs, HCHs, HCB, PBDEs and HBCDs were determined in striped dolphins (Stenella coeruleoalba) found stranded at Gogo-shima (n = 6, 2003) and collected from Taiji (n = 15, 1978-1992) in Japan. All target compounds were significantly detected in all the specimens, indicating ubiquitous contamination of oceanic cetaceans in northwest Pacific Ocean. Examination of body distribution of organohalogens in the six specimens from Gogo-shima showed no significant difference in concentrations among the analyzed tissues, except for brain, which had lower levels possibly due to the existence of blood-brain barrier. For evaluating temporal trends, archived blubber samples of adult male stripped dolphins collected in 1978, 1979, 1986 and 1992 were analyzed. Concentrations of PCBs, DDTs and HCHs did not change significantly during 1978-2003. In contrast, remarkable increasing trends of PBDEs and HBCDs were observed, suggesting growing consumption in Japan and surrounding countries in recent years.  相似文献